UV photocuring product

A light-curing, product technology, used in organic chemistry, coatings, fire-retardant coatings, etc., can solve the problems of large moisture influence, limited curing depth, slow polymerization speed, etc.

Active Publication Date: 2018-04-24
成都迪泰化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, it also has disadvantages such as being greatly affected by moisture, slow polymerization speed, few types of oligomers and reactive diluents, high price, and difficult to adjust the properties of polymerization products, which limits its practical application

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Selection of cationic photoinitiators and free radical photoinitiators, substrate wetting agents, defoamers, leveling agents, and hydroxyl-containing acrylate reactive monomers:

[0024] Cationic photoinitiator UVI 6976 (Dow Chemical, triarylsulfonium salt),

[0025] Free radical photoinitiator Irgacure 907 (Ciba, α-aminoketone derivative) / BMS (double bond, 4-p-tolylmercaptobenzophenone),

[0026] Substrate wetting agent HANSA1065 (BEZEMA), defoamer TEGO 920 (EVONIC), leveling agent EFKA3600 (BASF), hydroxypropyl methacrylate, pentaerythritol triacrylate.

[0027] Synthesis of acrylate photosensitive prepolymers containing aminoalkoxy groups:

[0028] Add hydroxypropyl acrylate and hexamethoxymethyl melamine to the reactor, the molar ratio is 3.05:1, add polymerization inhibitor p-hydroxyanisole and catalyst p-toluenesulfonic acid, the consumption is 0.1% of the total weight of reactants , reacted at 105°C, turned on the cooling water of the horizontal condenser, and b

Embodiment 2

[0037] Embodiment 2: A kind of UV light curing product that can realize ultra-fast UV curing under normal temperature:

[0038] Cationic photoinitiator and free radical photoinitiator, UV special color paste, matting agent, filler, substrate wetting agent, wetting and dispersing agent, defoamer, leveling agent, paint tank internal stabilizer, hydroxyl-containing acrylic acid Selection of ester reactive monomers:

[0039] Cationic photoinitiator UVI 6992 (Dow Chemical, triarylsulfonium salt),

[0040] Free radical photoinitiator Irgacure 819 (Ciba, acyl phosphine oxide) / 369 (Jiu Ri, α-amino ketone derivative), UV special color paste (B7 carbon black, W28 titanium white, R254 positive red, Y139 orange, Y154 Golden, B15:3 Phthalocyanine Blue, Iron Oxide Yellow, Iron Oxide Red, G7 Phthalocyanine Green, V23 Permanent Violet, O73 Fresh Orange, etc.),

[0041] Matting agent GRACE Rad 2105, substrate wetting agent HANSA1065 (BEZEMA), wetting and dispersing agent BYK168, defoamer TEGO

Embodiment 3

[0051] Selection of cationic photoinitiators and free radical photoinitiators, pigments and fillers, substrate wetting agents, wetting and dispersing agents, defoamers, leveling agents, and hydroxyl-containing acrylate active monomers:

[0052] Cationic photoinitiator Irgacure 261 (CIBA, ferrocene salt),

[0053] Free radical photoinitiator Irgacure 907 (Ciba, α-amino ketone derivative) / ITX (double bond, thioxanthone),

[0054] Pigments (titanium dioxide, carbon black, positive red, orange, golden, phthalocyanine blue, phthalocyanine green, bright orange, permanent violet, etc.),

[0055] Filler (calcium carbonate, talcum powder, barium white, fumed silicon, etc.), substrate wetting agent HANSA1065 (BEZEMA), wetting and dispersing agent lubrizol36000 ((LUBRIZOL) \ defoamer TEGO 920 (EVONIC), leveling agent EFKA3600 ( BASF), hydroxyethyl methacrylate, dipentaerythritol pentaacrylate.

[0056] Synthesis of acrylate photosensitive prepolymers containing aminoalkoxy groups:

[0

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Abstract

A UV photocuring product comprises an initiator and a photosensitive prepolymer and/or an active monomer thereof. The initiator comprises a radical initiator and a positive ion initiator capable of photolyzing and producing superacid; after absorbing light energy, the positive ion initiator can jump to an excited state, molecules produce photolysis reaction to generate superacid, after the photosensitive prepolymer and/or the active monomer thereof can be catalyzed and promoted at the normal temperature to initiate free radical photopolymerization by high-energy UV ultraviolet radiation, polycondensation is carried out to continue to crosslink, and thus, the curing degree is improved; and the positive ion initiator comprises an acrylate photosensitive prepolymer containing aminoalkoxy andan acrylate photosensitive prepolymer containing active hydroxyls, and the active monomer of the acrylate photosensitive prepolymer containing aminoalkoxy is selected from hydroxyl-containing (methyl)acrylate or vinyl active monomer.

Description

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Claims

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Application Information

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Owner 成都迪泰化工有限公司
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