Waste PET composite material

A composite material and mixed material technology, which is applied in the field of plastic material recycling, can solve the problems of poor impact performance of waste PET, and achieve the effects of improving toughness, saving resources and energy, and reducing pollution emissions.

Active Publication Date: 2019-04-19
CHINESE RES ACAD OF ENVIRONMENTAL SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patents describes how waste plastics are used for making composites that have both good mechanical properties (rigorence), resistance against environmental stress cracking, durability, flexibility, etc.) and reduced harmful chemical substances released from them when they were discarded after being processed. By modifying these polymeric compounds instead of just containing certain types or grades of polyethylene naphthalate (PEN), we aimed towards improving their overall effectiveness without compromising any beneficial qualities such as impact strength. Overall, this innovative approach allows us to create more efficient and effective ways to dispose of wasted products while reducing negative health hazards associated therewith.

Problems solved by technology

This patents discusses how much wasted or damaged PET can cause environmental pollution if left untrusted for decades due to their lack of useful properties such as being bulky, strong against bending, resistant to heat damage from sunlight exposure, easy-to-break openings that allow harmful gases into the environment during manufacturing processes, and having low thermal conductivity compared to other polymers commonly found in packaging applications like vinyl chloride copolymer rubbers. Therefore, there has been an increasing demand on efficient reuse methods of these types of waste products without causing negative effects upon our natural ecosystem.

Method used

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  • Waste PET composite material
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Examples

Experimental program
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Effect test

Embodiment 1

[0035] A waste PET composite material, raw materials include: waste PET with a crushing particle size of 1-10 cm, waste resin powder of 40-100 mesh, silane coupling agent and polyolefin elastomer (POE), the preparation process is as follows:

[0036] 1) Mix the silane coupling agent and waste resin powder at a mass ratio of 1 to 10:100, and dry to obtain silanized waste resin powder;

[0037] 2) Weigh the waste PET and dry it, and mix the waste PET with the silanized waste resin powder and polyolefin elastomer obtained in step 1) to obtain a mixture, wherein the mass ratio of PET to waste resin powder is 5-9:1 -5, the amount of polyolefin elastomer added accounts for 1% to 20% of the mass of the mixture;

[0038] 3) The mixture is extruded and granulated through a twin-screw extruder. The temperature of the barrel of the extruder is 235-260°C, the temperature of the die head is 240-265°C, the speed of the main engine is 150-180r / min, and the feeding speed is about 10-25 r / mi

Embodiment 2

[0049] Improvements were made on the basis of Example 1, wherein the mass ratio of waste resin powder: POE: waste PET was limited to 1:1:8, and composite material 1 was obtained. After testing, the impact strength of composite material 1 increased by 3.4% compared with waste PET, see image 3 . Its elongation at break, flexural strength, tensile strength see Figure 4 , 5 6.

Embodiment 3

[0051] Improvements were made on the basis of Example 2, wherein the mass ratio of waste resin powder: POE: waste PET was limited to 1:1.5:7.5, and composite material 2 was obtained. After testing, the impact strength of composite material 2 increased by 14% compared with waste PET, see image 3 . After testing, the elongation at break, bending strength, and tensile strength of this embodiment are also within reasonable ranges, and this embodiment is the most preferred embodiment after comprehensive evaluation. Its elongation at break, flexural strength, tensile strength see Figure 4 , 5 6.

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Abstract

The invention discloses a waste PET composite material. A silane coupling agent can be mixed with waste PET and a polyolefin elastomer after being mixed and dried with waste resin powder with a mass ratio of 1-10 : 100, so that a mixture can be obtained, wherein the mass ratio of the waste PET to the waste resin powder is 5-9 : 1-5, and the addition amount of the polyolefin elastomer accounts for1-20% of the mass of the mixture; and extrusion granulation of the mixture can be realized through a twin-screw extruder. Through a modification technology to develop the composite material, the comprehensive utilization of the waste PET and waste resin can be realized, and the disadvantage of poor PET impact property can be overcome.

Description

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Claims

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Application Information

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Owner CHINESE RES ACAD OF ENVIRONMENTAL SCI
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