An object of the invention is to provide a laminate which is good in adhesiveness between a substrate and a thin film laminated thereon by a dry film-forming method such as a chemical
vapor growth method or a
vacuum evaporation method even if the substrate is a
polymer substrate made of a nonpolar
polymer; and a process for producing the same. In order to attain the above-mentioned object, the invention provides a laminate comprising a
polymer substrate, a primer layer comprising a cyclized rubber which is a
conjugated diene polymer cyclized product or a derivative thereof, the layer being formed on the surface of the
polymer substrate, and a thin film laminated on the surface of the primer layer by a dry film-forming method; and a process for producing the same. The present invention also provides a laminate comprising a
polymer substrate in which a cyclized rubber which is a
conjugated diene polymer cyclized product or a derivative thereof is incorporated into a polymer-molding material, and a thin film laminated on the surface of the
polymer substrate by a dry film-forming process; and a process for producing the same.