Method for preparing laser thermal composite induction nanoparticle reinforcement laminated film

A technology of nano-particles and enhanced compounding, applied in the coating process of metal materials, coatings, etc., can solve the problems of low interface bonding strength, the size of workpieces polluting the environment, and weak coating interface bonding, etc., to improve the properties and distribution of surface stress , the effect of homogenizing the distribution of nanoparticles and refining the microstructure

Inactive Publication Date: 2013-05-15
JIANGSU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this method has a small impact force and a low strain rate, which makes the interface bonding of the coating relatively weak. It is not suitable for preparing thick coatings, and the efficiency is low, and it is difficult to handle parts with complex shapes.
Electroless deposition methods such as electroless plating, electroplating, etc. can also prepare nano-coatings, but they have disadvantages such as low interface bonding strength, polluting the environment, and limited workpiece size.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0021] Example 1:

[0022] 1) Select SiC powder with an average size of 10nm for surface treatment;

[0023] 2) Select the ZL104 aluminum alloy substrate to be processed, and polish and polish the surface, and then perform ultrasonic cleaning in alcohol;

[0024] 3) Prepare the nano SiC powder selected in step 1) into an alcohol suspension, then disperse it ultrasonically, and then dip it on the surface of the ZL104 aluminum alloy treated in step 2) at a speed of 5 mm / s, and leave it to dry. ;

[0025] 4) Use nanosecond pulse laser to irradiate the surface of the ZL104 aluminum alloy substrate pre-coated with nano-SiC particles to melt, and the irradiated laser energy density is 0.6 J / cm 2 , The laser pulse width is 10 ns, the spot diameter is 3 mm, so that the nano SiC particles are immersed in the molten pool, and after cooling and solidification, they are half embedded on the surface of the ZL104 aluminum alloy substrate;

[0026] 5) Cover the surface of the ZL104 aluminum alloy su

Example Embodiment

[0031] Example 2:

[0032] 1) Select Al with an average size of 200nm for surface treatment 2 O 3 powder;

[0033] 2) Select the AZ91 Mg alloy substrate to be processed, and polish and polish its surface, and then perform ultrasonic cleaning in alcohol;

[0034] 3) Change the nano Al selected in step 1) 2 O 3 The powder is formulated into an alcohol suspension, then ultrasonically dispersed, and then dip-coated on the surface of the AZ91 Mg alloy treated in step 2) at a speed of 1 mm / s, and left to dry;

[0035] 4) Pre-coated nano-Al with nanosecond pulse laser irradiation 2 O 3 The surface of the granular AZ91 Mg alloy matrix is ​​melted, and the laser energy density is 0.1 J / cm 2 , The laser pulse width is 5 ns, the spot diameter is 10 mm, so that nano Al 2 O 3 The particles are immersed in the molten pool, and half embedded in the surface of the AZ91 Mg alloy matrix after cooling and solidification;

[0036] 5) Use aluminum foil as the absorption layer to cover the nano Al obtained

Example Embodiment

[0041] Example 3:

[0042] 1) Select nano TiN powder with an average size of 80nm for surface treatment;

[0043] 2) Select the aluminum bronze alloy substrate to be processed, and polish and polish its surface, and then perform ultrasonic cleaning in alcohol;

[0044] 3) Prepare the nano TiN powder selected in step 1) into an alcohol suspension, then disperse it ultrasonically, and then dip it on the surface of the aluminum bronze alloy treated in step 2) at a speed of 10 mm / s, and leave it to dry. ;

[0045] 4) Use nanosecond pulse laser to irradiate the surface of aluminum bronze alloy substrate pre-coated with nano-TiN particles to melt, and the laser energy density is 1 J / cm 2 , The laser pulse width is 15 ns, the spot diameter is 6 mm, so that the nano-TiN particles are immersed in the molten pool, and after cooling and solidification, they are half embedded in the surface of the aluminum bronze alloy substrate;

[0046] 5) Use black paint as the absorption layer to cover the su

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Abstract

The invention discloses a method for preparing a laser thermal composite induction nanoparticle reinforcement laminated film, and the method relates to the technical field of material surfaces. The surface of a metal matrix coated with a ceramic nanoparticle layer is irradiated by laser to a melting state, and ceramic nanoparticles are soaked in a molten bath and cooled to be in a semi-embedded state; then, the surface of the metal matrix with semi-embedded nanoparticles is impacted through high-pressure impact wave force effect which is generated by laser induction, so that the nanoparticles are completely embedded into the surface layer of the matrix; and the steps are repeated so as to embed multiple layers of ceramic nanoparticles, and a uniform nanoparticle reinforcement laminated film with large thickness is obtained. The nanoparticle reinforcement laminated film obtained by the method is form in interface bonding and has less defects and a uniform component structure, and the surface performance of a metal material can be obviously improved. The method is simple in process, low in cost, easy in realizing automation and suitable for large-scale mass production.

Description

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Claims

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Application Information

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Owner JIANGSU UNIV
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