Method for making adhesive film

A manufacturing method and technology for bonding films, which are applied in the direction of film/sheet-like adhesives, adhesives, etc., can solve the problems of reduced workability, inability to stabilize co-extrusion molding, and inability to increase the mixing ratio of tackifying resin, etc. Stable quality and good forming workability

Inactive Publication Date: 2013-08-21
NITTO DENKO CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in such a method, when a surface protection film with high adhesive force is produced according to the type and use of the adherend, even if it is necessary to increase the amount of tackifying resin added to the adhesive layer, due to the use of EVA As the matrix resin of the masterbatch, the proportion of the tackifying resin in the masterbatch cannot be increased
In such a method, for example, when the compounding ratio of the tackifying resin is 15% by weight or more, the particles are blocked, the workability is reduced, and stable coextrusion molding becomes impossible.

Method used

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  • Method for making adhesive film

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0058] [Example 1]

[0059] As the thermoplastic resin in the base layer forming material, low-density polyethylene (Nippon Polyethylene Corporation, NOVATEC LD LF547) was used, and as the polyolefin resin in the adhesive layer forming material, polypropylene (Japan POLYCHEM ( Co., Ltd., trade name "NOVATEC PPFX3", melting temperature 139°C, MFR8.0 (according to JIS-K6921-2)), as the thermoplastic elastomer in the adhesive layer forming material, styrene-butadiene- A hydrogenated styrene block copolymer (SEBS, manufactured by Shell Chemical Co., Ltd., trade name "KRATON G1657"). As a tackifying resin in the adhesive layer forming material, a hydrogenated terpene resin (manufactured by Yasuhara Chemical Co., Ltd., Trade name "Clearon P125").

[0060] First, the polyolefin-based resin and the hydrogenated terpene-based resin were melt-mixed according to the mixing ratio shown in Table 1 to prepare pre-kneaded pellets. Then, the pre-kneaded pellets and SEBS were dry-blended in the mixi

Example Embodiment

[0061] [Example 2]

[0062] As the thermoplastic elastomer in the adhesive layer forming material, a hydrogenated styrene-isoprene-styrene block copolymer (SEPS, manufactured by Kuraray Co., Ltd., trade name "Septon 2043") was used instead of SEBS, according to the table The mixing ratio shown in 1 is that polypropylene and hydrogenated terpene-based resin are melt-mixed to produce pre-kneaded pellets, and the pre-kneaded pellets and SEPS are dry-blended according to the mixing ratio shown in Table 1. In addition, with Example 1 was implemented in the same manner, and an adhesive film (2) having a base layer (thickness 100 μm) and an adhesive layer (thickness 15 μm) was produced.

Example Embodiment

[0063] [Example 3]

[0064] As the polyolefin resin in the adhesive layer forming material, low-density polyethylene (melting temperature 110°C, MFR2.0 (according to JIS-K6922-2)) is used instead of polypropylene as the thermoplastic elasticity in the adhesive layer forming material Body, using hydrogenated styrene-isoprene-styrene block copolymer (SEPS, manufactured by Kuraray, trade name "Septon 2043") instead of SEBS as the tackifying resin in the adhesive layer forming material, Use hydrogenated aromatic petroleum resin (manufactured by Arakawa Chemical Industry Co., Ltd., trade name "ARCON P-125") instead of hydrogenated terpene resin, and compare low-density polyethylene with hydrogenated aromatic resin according to the mixing ratio shown in Table 1. The petroleum resin was melt-mixed to prepare pre-kneaded pellets, and the pre-kneaded pellets and SEPS were dry-blended according to the mixing ratio shown in Table 1. Except for this, the same procedure as in Example 1 was carri

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Abstract

The invention provides a method for making an adhesive film having a substrate layer and an adhesive layer through co-extruding a substrate layer forming material and an adhesive layer forming material containing a thermoplastic elastomer and a tackifying resin. The method allows the adhesive film having a good making shaping operability and a stable quality to be made when the content of the tackifying resin in the adhesive layer is high. The invention also provides the adhesive film obtained through the making method. The invention further provides a master batch for the formation of the adhesive layer of the adhesive film used in the making method. The adhesive film having the substrate layer and the adhesive layer through co-extruding the substrate layer forming material including a thermoplastic resin as a main component and the adhesive layer forming material containing the thermoplastic elastomer and the tackifying resin through the adhesive film making method, the adhesive layer forming material contains a polyolefin series resin having a melting temperature (Tm) of 100-180DEG C solved through a differential scanning calorimetry (DSC), and the content proportion of the tackifying resin in the adhesive layer is below 40wt%.

Description

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Claims

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Application Information

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Owner NITTO DENKO CORP
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