Method for preparing rare-earth-waste-residue coagulant

A technology of rare earth waste residue and coagulant, which is applied in the direction of flocculation/sedimentation water/sewage treatment, etc., which can solve the problems of application limitation and high production cost.

Inactive Publication Date: 2014-01-29
YANCHENG INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, although they have good coagulation effect, the high production cost limits their application

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1:①7,3mol/L100ml(12g);②100℃1h;③,;④,60℃2h,;⑤,182.1NTU,pH5.5,1000ml preparation 4ml, experiment ,3.2NTU, to 98.2%。 Embodiment 2:①7,4mol/L100ml(16g);②100℃2h;③,;④,70℃2h,;⑤,176.5NTU,pH5.5,1000ml preparation 4ml, experiment ,2.7NTU, to 98.5%。 Embodiment 3

[0004] Example 1: ① Take 7 grams of dried rare earth waste residue, put it into a flask and slowly add 100ml of 3mol / L sodium hydroxide solution (that is, contain 12g of sodium hydroxide); ② Boil at 100°C Heating for 1 hour; ③ After the reaction, the mother liquor was vacuum filtered, and the filtrate was used for subsequent concentration; ④ The filtrate was placed in a water bath, heated and matured at 60°C for 2 hours, and the transparent liquid obtained was the obtained mixture. coagulant; ⑤Taking a certain coking biochemical effluent as the treatment water quality, the measured turbidity is 182.1NTU, pH5.5, take 1000ml of it and put it into the prepared coagulant 4ml, carry out coagulation experiment, measure the turbidity of the effluent after precipitation The degree is 3.2NTU, and the turbidity removal rate reaches 98.2%. Example 2: ① Take 7 grams of dried rare earth, put it into a flask and slowly add 100ml of 4mol / L sodium hydroxide solution (that is, contain 16g of s...

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Abstract

The invention relates to a method for preparing a head-wrapped wet acid-method rare-earth-waste-residue coagulant for water treatment. The coagulant is mainly prepared through mixing head-wrapped wet acid-method rare-earth desulfurized waste residues and sodium hydroxide and reacting. The preparation of the coagulant belongs to solid waste utilization, the coagulation effect and flocculation performance of the coagulant are equivalent to those of an alkali-method rare-earth coagulant, however, the cost is reduced greatly; the effect on the removal of turbidity and chromaticity of biochemical effluent of coking is obviously better than those of other common coagulants. Thus, the coagulant is an expansion of rare-earth waste residues in the field of wastewater treatment.

Description

technical field [0001] The invention relates to a preparation method and specific steps of an alkaline rare earth waste slag coagulant for water treatment. Background technique [0002] In recent years, there have been more and more studies on the application of rare earths in the field of water treatment. For example, ZL 2009 1 0142775.1 and ZL 2011 1 0020432.5 disclosed that rare earth concentrates were mixed with hydrochloric acid and sodium hydroxide in corresponding proportions to prepare water treatment products. Rare earth coagulant. Because the reaction amount of rare earth in its preparation is very small, although the residue after the reaction can be reused, it will be affected. Therefore, although they have good coagulation effect, their application is limited due to the high production cost. During the Baotou wet-type acid rare earth extraction process, in order to eliminate the influence of sulfate ions on subsequent rare earth extractants, it is necessary to...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/52
Inventor 延克军甄树聪敬双怡暴苗苗周友新王利
Owner YANCHENG INST OF TECH
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