Localization coating for automobile tail gas purification catalyst, and preparation method thereof

A technology for purifying catalysts and automobile exhaust, which is applied in the field of automobile exhaust purification, can solve problems such as difficulty in popularization, and achieve the effect of reducing costs and improving durability

Active Publication Date: 2020-02-18
ZHEJIANG DA FENG AUTOMOBILE TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This technology divides up certain parts of an engine's air filter system (AFS) into two areas: one for better fuel economy and reduction of emissions; another part called the back quarter where there may be more than just three layers on top of it containing special materials like platinum or rhodium. These techniques help increase the effectiveness at starting engines by improving their ability to convert harmful gases such as carbon monoxide (CO), hydrocarbons (HC).

Problems solved by technology

This patented describes how vehicles emit large amounts of unhealthous materials like nitrogen oxide (NO) from their engines during operation due to factors like fuel quality concerns and increasingly stringent regulatory controls over recent years. These issues lead to concern about reducing these unwanted compounds entering our ozone layers and affecting human health. To address this issue, researchers developed new methods to reduce the amount of expensive platinum(Pt), rhodium (Rh)-based catalysis coatings applied onto diesel carriages.

Method used

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  • Localization coating for automobile tail gas purification catalyst, and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] A localized coating of an automobile exhaust purification catalyst, which is coated on the inner wall of the honeycomb ceramic carrier channel arranged at the outlet end of the automobile engine. Catalytic conversion of harmful substances such as CO, HC and NOx in the exhaust gas into CO 2 、H 2 O and N 2 and other harmless gases into the atmosphere.

[0037] In this embodiment, the honeycomb ceramic carrier includes a front half area and a second half area with a height ratio of 1:2, the coating of the first half area includes an inner coating, a middle coating, and an outer coating in sequence, and the coating of the second half area sequentially includes Internal and external coatings. The inner and outer coatings of the first half area have the same components as the inner and outer coatings of the second half area.

[0038] According to parts by mass, the components of the inner coating include 64.5 parts of rare earth composite oxide, 26 parts of modified alumina,

Embodiment 2

[0050] In this embodiment, the honeycomb ceramic carrier includes a front half area and a second half area with a height ratio of 1:1. The coating in the first half area includes an inner coating, a middle coating, and an outer coating in sequence, and the coating in the second half area also sequentially Including inner coating, middle coating and outer coating, but the coating coating parts of the first half area and the second half area are different.

[0051] According to parts by mass, the components of the inner coating include 45.95 parts of rare earth composite oxide, 45.95 parts of modified alumina, 8 parts of additives and 0.1 part of noble metal. Among them, the rare earth composite oxide includes Ce1, which is composed of 90% of a mixture of ceria and zirconia in a mass ratio of 1:1 and 10% of lanthanum oxide. Modified alumina includes 90% alumina and 10% lanthanum oxide. Pd is selected as the precious metal. The auxiliary agent is a mixture of pseudo-boehmite and B

Embodiment 3

[0064] In this embodiment, the honeycomb ceramic carrier includes a front half area and a second half area with a height ratio of 1:4, the coating of the first half area includes an inner coating, a middle coating and an outer coating in sequence, and the coating of the second half area includes Internal and external coatings. The inner and outer coatings of the first half area have the same components as the inner and outer coatings of the second half area.

[0065] According to parts by mass, the components of the inner coating include 74.2 parts of rare earth composite oxide, 14.8 parts of modified alumina, 10 parts of additives and 1 part of noble metal. Among them, the rare earth composite oxide includes Ce1, which consists of 97% of a mixture of cerium oxide and zirconia with a mass ratio of 2:1 and 3% of yttrium oxide. Modified alumina includes 99.9% alumina and 0.1% lanthanum oxide. Pd is selected as the precious metal. The auxiliary agent is an equal mass ratio mixtur

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Abstract

The invention relates to the technical field of automobile tail gas purification, in particular to a localization coating for an automobile tail gas purification catalyst, and a preparation method thereof. The coating is applied to the inner walls of channels of a honeycomb ceramic carrier arranged at a gas outlet end of an automobile engine, the honeycomb ceramic carrier comprises a front half region and a rear half region with a height ratio of 1:(1-4), a coating of the front half region sequentially comprises an inner coating, a middle coating and an outer coating, and a coating of the rearhalf region sequentially comprises an inner coating and an outer coating; and the components of the inner coating, the middle coating and the outer coating comprise a rare earth composite oxide, modified alumina, an additive and a noble metal. By partitioning the carrier into regions and coating different regions with coatings with different components, different thicknesses, and different noblemetal contents, a use amount of the noble metal on the entire honeycomb ceramic carrier can be reduced while the tail gas conversion efficiency is ensured, and thereby the cost of the automobile tailgas purification catalyst is reduced.

Description

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Claims

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Application Information

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Owner ZHEJIANG DA FENG AUTOMOBILE TECH
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