Preparation method of bionic carbon negative electrode material used as potassium ion battery negative electrode, and product

A negative electrode material and battery negative electrode technology, applied in the field of biomimetic carbon and its preparation, can solve the problems of insufficient rate performance and fast charge/discharge characteristics, and achieve excellent electrochemical performance, high reversible capacity, and excellent rate performance.

Inactive Publication Date: 2021-03-02
福建海峡石墨烯产业技术研究院有限公司
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Problems solved by technology

However, their rate capability and fast charging/discharging characteristics are still insufficient for practical battery applications, thus it is necessary to continue to study advanced carbon-based anodes for potassium-ion batteries

Method used

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  • Preparation method of bionic carbon negative electrode material used as potassium ion battery negative electrode, and product
  • Preparation method of bionic carbon negative electrode material used as potassium ion battery negative electrode, and product
  • Preparation method of bionic carbon negative electrode material used as potassium ion battery negative electrode, and product

Examples

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Example Embodiment

[0041]Example 1

[0042]Such asfigure 1 As shown, first of all, a nitrogen-carbon compound (C3N4) Intermediate: Put 15mg of melamine precursor in a porcelain boat and put it in a muffle tube furnace at 2℃min-1The heating rate is heated to 550°C and kept at a constant temperature for 5 hours, and then naturally cooled to room temperature to obtain C3N4;

[0043]Secondly, cobalt (Co) catalyst catalyzes high-temperature carbonization treatment: Use an agate mortar to remove C3N4Grind into fine powder, then mix with metal Co at a mass ratio of 1:1, and then mix thoroughly in an agate mortar; put it in a porcelain boat after mixing evenly, and heat it at 2℃ in a tube furnace with an argon atmosphere min-1The rate of heating up to 800 ℃, and constant temperature heating treatment at this temperature for 2h, and then natural cooling to room temperature;

[0044]Finally, acid treatment to remove the metal catalyst; repeated washing with 2mol / L hydrochloric acid (HCl) solution to remove Co, and then r

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Abstract

The invention provides a preparation method of a bionic carbon negative electrode material used as a potassium ion battery negative electrode, and a product. The preparation method of the bionic carbon negative electrode material comprises the following steps: preparing a nitrogen-carbon compound (C3N4) intermediate; then catalyzing with a metal catalyst, and carbonizing at a high temperature of 700-900 DEG C; and finally, carrying out acid treatment to remove the metal catalyst, washing, and drying in a vacuum drying oven at 50-80 DEG C for 12-18 hours to obtain the biomimetic carbon negativeelectrode material similar to a biological cell structure. The negative electrode of the potassium ion battery is the biomimetic carbon negative electrode material prepared by the method, the potassium ion battery uses Prussian blue as a positive electrode, uses 4mol L<-1> of potassium bis(fluorosulfonyl) amide as an electrolyte, and uses 1, 2-dimethoxyethane as a solvent. The biomimetic carbon provided by the invention has excellent electrochemical properties such as high reversible capacity, excellent rate capability, excellent cycle performance and the like as a negative electrode materialof a potassium ion battery.

Description

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Claims

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Application Information

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Owner 福建海峡石墨烯产业技术研究院有限公司
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