106 results about "Analytical chemistry" patented technology

The invention relates to an infrared spectrum enhancement and detection method and an infrared spectrum enhancement and detection device based on a graphene nano antenna. The device comprises a light source, a collimating lens, a one-point detector and an MEMS (micro-electromechanical system) grating light modulator based on the three-dimensional graphene nano antenna. Infrared light emitted from the light source is irradiated to the MEMS grating light modulator based on the three-dimensional graphene nano antenna through the collimating lens, an interference signal of the MEMS grating light modulator can be detected by the one-point detector, a detection signal is demodulated through Fourier transform, a spectrum is reproduced, and trace molecules are detected according to obtained spectrum information; the device has the advantages of good stability, high response speed, high sensitivity, dynamic tunable broadband, high enhancement factor and the like, can be expected to greatly increase the variety of substances detected by an infrared spectroscopic analysis technology and improve the detection sensitivity of the infrared spectroscopic analysis technology, and has a huge development space and a wide application prospect.

A method for analyzing formation fluid in a subterranean formation is disclosed, wherein the method includes the steps of: adding a scavenger compound to an analytical reagent to form a reagent solution; collecting an amount of formation fluid into a formation tester, wherein the formation tester includes at least one fluids analyzer comprising at least one probe, at least one flow line, at least one reagent container, and at least one spectral analyzer, wherein the fluids analyzer is configured such that the collected formation fluid is fed through the at least one flow line to the at least one spectral analyzer; mixing an amount of the collected formation fluid with an amount of the reagent solution to form a mixture; and analyzing the mixture downhole.

The invention discloses an on-line detection instrument for hydrogen fluoride gas. The on-line detection instrument comprises a detection system and a central processing system, wherein the detection system comprises a sampling device and an HF (Hydrogen Fluoride) gas sensor which is connected with the central processing system; the sampling device comprises a gas detection chamber; the gas detection chamber is provided with a gas inlet and a gas outlet which are connected with a GIS (Geographic Information System) high-pressure gas chamber; the HF gas sensor is fixed on the gas detection chamber; a testing end of the HF gas sensor is positioned inside the gas detection chamber; gas from the GIS high-pressure gas chamber enters the gas detection chamber; the HF gas sensor is used for detecting the concentration of the HF gas in the gas, and used for transmitting detection information to the central processing system to be processed so as to obtain the content of the HF gas. The invention further discloses a method for quantitatively detecting the hydrogen fluoride gas by using the detection instrument. By utilizing the detection instrument and the method, the content of the hydrogen fluoride gas can be rapidly and accurately detected in real time, and SF6 inside SF6 electric equipment is not lost.

There is provided a liquid processing method for performing a liquid process on a front surface of a substrate by using a processing solution and then performing a rinse process on the front surface of the substrate by using a rinse solution having a temperature lower than a temperature of the processing solution. The liquid processing method includes performing an intermediate process between the liquid process and the rinse process, for adjusting a temperature of the front surface of the substrate to a temperature higher than the temperature of the rinse solution and lower than the temperature of the processing solution.

The invention discloses Mn<4+> doped fluoroaluminate red fluorescent powder as well as a preparation method and an application thereof. The method comprises steps as follows: hydrofluoric acid and water are added to a polytetrafluoroethylene container, K2MnF6 is added and stirred to be dissolved, and then KF is added; after KF is dissolved, K3AlF6 is added and continuously stirred to be completely dissolved, and then the mixture is continuously stirred for 30 min; the mixture is left to stand after stirring is stopped, suction filtration is performed, a filter cake is dried under the vacuum condition at the temperature of 70 DEG C, and the Mn<4+> doped fluoroaluminate red fluorescent powder is obtained. Compared with the prior art, the K3AlF6:Mn<4+> red fluorescent powder is synthesized in a hydrofluoric acid aqueous solution, and the diluted aqueous solution has a function of purifying the K3AlF6 phase; excessive KF.2H2O is added, so that the K3AlF6 phase is crystallized and separated to be purified in the aqueous solution; the obtained fluorescent powder has a narrow emission spectrum range, and the reabsorption phenomenon is effectively avoided; the phase of the synthesized fluorescent powder is pure, and the light emitting efficiency and collection rate are high; the color gamut range of a white light LED device packaged by the fluorescent powder is wide.

The invention discloses a high-salinity-resistant nucleic acid sensor for copper and application thereof. The sensor comprises a molecular recognition element, a signal multiplication element and a signal conversion element, wherein the molecular recognition element comprises copper ion deoxyribozyme; the copper ion deoxyribozyme consists of a substrate chain and an enzyme chain; the signal multiplication element comprises an isothermal amplification system; the isothermal amplification system comprises an amplification template; the signal conversion element comprises hemin and a color developing agent. The sensor provided by the invention is used for specifically recognizing a copper ion; the primary enlargement and conversion of a signal are carried out through an isothermal index multiplication reaction; a G-four-chain body structure with activity is formed under the induction of the hemin; the color developing agent is catalyzed to develop a color, thus, secondary multiplication and conversion are generated; the signal is converted into a visual signal, and the qualitative and quantitative detection in a high-salinity environment can be carried out.

The invention belongs to the field of protein analysis, and relates to a new method for enrichment of a glycosylated peptide through a magnetic nanometer material modified by aminoxy, in particular to a method for solid-phase enrichment and mass spectrographic analysis of a glycosylated peptide fragment. The method comprises the following steps: firstly, using sodium periodate NaIO4 to oxidize a hydroxyl group on a glycopeptide to change the hydroxyl group to an aldehyde group; secondly, placing the magnetic nanometer material Fe3O4@ONH2 modified by aminoxy to an oxidized glycopeptide solution, and fixing the glycopeptide to the magnetic nanometer material through reaction of an aminoxy group and the aldehyde group obtained after a sugar chain in the glycopeptides is oxidized; thirdly, cleaning to remove non-glycopeptide which does not react with the nanometer material; finally, dissociating the captured glycopeptide from the material by use of sugar chain enzyme, and realizing mass spectrographic analysis of the glycosylated peptide. The method is simple in step, convenient to operate, high in speed and efficient, and can realize highly-sensitive and highly-selective mass spectrometric analysis of the glycosylated peptide.

The inorganic scintillator of the invention is an inorganic scintillator capable of producing scintillation by radiation, which is a crystal comprising a metal oxide containing Lu, Gd, Ce and Si and belonging to space group C2/c monoclinic crystals, and which satisfies the condition specified by the following inequality (1A), wherein A_Lu represents the number of Lu atoms in the crystal and A_Gd represents the number of Gd atoms in the crystal.

{A_Lu/(A_Lu+A_Gd)}<0.50  (1A)

The invention relates to rare earth ion liquid as well as a preparation method and application thereof in o detection of ferric ions. According to the invention, the rare earth ion liquid [C4mim] [Dy(NO3)4] is used as a fluorescence probe, a rare earth ion liquid aqueous solution with fixed concentration is prepared to be used as standard detection liquid, and whether water contains ferric ions or not can be judged by observing whether the ionic liquid fluorescence light cancels or not under 325nm excitation wavelength. By adopting the rare earth ion liquid, the ferric ions can be exclusively recognized, interference of other heavy metal ions is avoided, the detection method is simple and fast, a detection reagent is short in synthesis period and high in yield, and when being applied to actual production, the ion liquid is an environment-friendly solvent and has a wide application prospect.

The invention discloses an inorganic sensitive layer based surface enhanced Raman spectrum detection technology and material preparation thereof. According to the detection technology, a surface enhanced Raman spectrum material based on an inorganic sensitive layer is used as an active substrate of a surface enhanced Raman scattering, and is exposed in the small molecule atmosphere; a new solid substance formed by specific reaction of the inorganic sensitive layer and small molecules to be detected by a Raman spectrometer is detected, and the type of the small molecules is obtained according to the Raman spectrum of the new solid substance; according to the preparation method, a colloid electrostatic self-assembly method, a thiourea-induced isotropic shell growth method, a metal halogenation method and a physical deposition method are used for a precious metal nanoparticle colloidal solution, a metal salt solution and a thiourea solution to prepare the material in which precious metalnanoparticles are coated with a metal oxide layer, or the precious metal nanoparticles are coated with a metal sulfide layer, or the precious metal nanoparticles are coated with a metal halide layer.The technology can be used for real-time online detection of hydrogen sulfide, carbon disulfide, hydrogen chloride, mustard gas, nitrogen dioxide and the like.

The invention discloses a preparation method of a flexible electrode membrane based on polyacrylamide hydrogel. The preparation method comprises the following steps: 1) weighing the following raw materials: polyacrylamide powder, sodium chloride powder and water according to corresponding mass percentages; 2) dissolving the sodium chloride powder in water to obtain a sodium chloride solution, adding the polyacrylamide powder, and performing stirring until a gel-like flexible gel is formed; and 3) standing the flexible gel in step 2) at normal temperature, and stretching the flexible gel untilcomplete transparence to obtain the flexible electrode membrane based on the polyacrylamide hydrogel. The preparation method has the advantages of high efficiency, low preparation cost, environmentalprotection, safety, good stability, and high conductivity of the prepared flexible electrode membrane.

The invention discloses synthesis of a probe detecting a copper ion (Cu<2+>) and a nickel ion (Ni<2+>) by a colorimetric method, and an application in detection of Cu<2+> and Ni<2+> in a water sample.A structural formula of the molecular probe is as follows as shown in the specification. The molecular probe can give different complex reactions with Cu<2+> and Ni<2+> in an aqueous solution to showdifferent colors so as to achieve the purpose of simultaneously detecting Cu<2+> and Ni<2+> by colorimetry; a detection solution is changed to bright red from yellow after complexing of the probe andCu<2+>; the detection solution is changed to purple after complexing of the probe and Ni<2+>; a color change is obvious; a detection speed is high; and the differentiation is easy. High-sensitivity detection of Cu<2+> and Ni<2+> can be achieved in combination with ultraviolet spectrophotometry; the probe can directly detect a micro level of Cu<2+> and Ni<2+> in the water; and the limits of detection are as low as 2.1nM and 1.2nM respectively. When a pH (potential of hydrogen) is 4-10, the probe can highly sensitively detect Cu<2+> and Ni<2+> in the water sample, is simple to operate and goodin selectivity and has a higher application value in the fields of environmental science, analysis, detection and the like.

The present invention discloses a choline particle and a preparation method and an application thereof. The preparation method comprises the following preparation steps: step one, crushing choline topass a 20-100 mesh sieve; step two: dissolving a first binder in water to obtain a binder solution; and step three: after mixing the choline processed in the step one with a second binder, putting themixture into a granulator, and adding the binder solution obtained in the step two for granulation to obtain the choline particle. The binder is dissolved in water, then the choline is granulated, the prepared granule is uniform and moderate in size, good in fluidity, and not easy to absorb moisture; and a prepared pressed tablet is smooth on surface, small in difference in tablet weight, good inhardness (good in friability), and good in disintegration.

The invention discloses a method for rapid determination of isothiazolinone compounds in a water-based adhesive for cigarettes. The method comprises the following steps: adding an extraction agent into the water-based adhesive for cigarettes, wherein a volume mass ratio of the extraction agent to a water-based adhesive sample is 5-40 mL: 0.3 g; then carrying out ultrasonic extraction for 5 to 45 min so as to obtain extract liquor; subjecting the obtained extract liquor to centrifugation, taking supernatant and introducing nitrogen into the supernatant so as to obtain concentrated supernatant; allowing the concentrated supernatant to pass through a filter membrane so as to obtain a to-be-detected solution; and carrying out quantitative analysis on the isothiazolinone compounds in the to-be-detected solution by using ultrahigh performance liquid chromatography-diode array. The method provided by the invention can carry out simultaneous analysis and detection on at least three isothiazolinone compounds in the water-based adhesive for cigarettes; the method is simple in treatment and fast in analysis speed; detection results are good in repeatability and high in sensitivity; and the method is applicable to determination of three isothiazolinone compounds in the water-based adhesive for cigarettes or in other complex matrixes.

The invention discloses a kit for detecting the content of a KAPPA light chain.The kit comprises a reagent R1, a reagent R2 and a KAPPA light chain calibration material, wherein the reagent R1 comprises a first buffer solution, a first electrolyte, a surface active agent, a first stabilizer, a macromolecule accelerant and a first preservative, the reagent R2 comprises a second buffer solution, an anti-human KAPPA light chain antibody, a second electrolyte, a second stabilizer and a second preservative, and the C1 inhibitor calibration material comprises a third buffer solution, a third stabilizer, a third preservative, an antioxidant and a KAPPA light chain antigen.The invention further discloses the application of the kit for detecting the content of the KAPPA light chain and a method for detecting the content of the KAPPA light chain using the kit.By the adoption of the kit and the detection method, the content of the KAPPA light chain can be detected easily and quickly.

A monitor for monitoring the concentration of oxygen in a fuel or in an ullage over a fuel comprises (i) a sensing element comprising a luminescent substance comprising a luminophore and a support in which the luminophore is covalently bound to the support, (ii) a light source arranged to irradiate the sensing element with light, and (iii) a photosensor arranged to detect light emitted from the luminescent substance. The luminescent substance may be, for example, a platinum porphyrin covalently bound to silica.

Disclosed is a method for calculating a ratio of glycosylated hemoglobin with high accuracy by electrochemically detecting the concentration of fructosyl valine or fructosyl valyl-histidine in a sample. Also disclosed is an apparatus for assaying glucose and glycosylated hemoglobin simultaneously. Further disclosed are a method and an apparatus for removing hydrogen peroxide in a sample.

Described herein are methods for making and using magnetic ionic liquid that have at least one cationic component and at least one anionic component, where at least one of the cationic components or the anionic components is a paramagnetic component. The magnetic ionic liquids are capable of manipulation by an external magnetic field.

The invention discloses a white spirit sample testing system and method based on near infrared spectroscopy, and relates to the technical field of liquid sample testing, solves the problem of difficulty in batch testing due to low accuracy and high cost of existing liqueur sample grade testing, and adopts the technical scheme that the liqueur sample grade testing device comprises a light source unit, a prism unit, a sample disc unit, a light splitting unit, a detection unit and a control terminal; the signal output end of the control terminal is connected with the signal input ends of the prism unit, the sample disc unit and the light splitting unit; the signal output end of the detection unit is connected with the signal input end of the control terminal; the control terminal comprises adisplay unit, a database, a data processing unit and a control unit; spectrum data of a white spirit sample are obtained by utilizing a near infrared spectrum technology, and the liqueur grade is rapidly judged by pattern recognition software, so that not only are the judgment speed and accuracy of the liqueur grade improved, but also the test cost is reduced, and basic conditions are provided forbatch test of the liqueur samples.

The invention discloses a crystal material. The chemical formula is Mg11(HPO3)8(OH)6, the reflectivity in an ultraviolet-visible-near infrared band of 0.2-2.5 microns is 88% or above, and simultaneously the emissivity in a far infrared band of 2.5-25 microns is 0.90 or above. The invention also discloses a preparation method of the crystal material. The preparation method comprises the following steps: on the basis of raw materials of magnesium acetate tetrahydrate and phosphorous acid, simultaneously adding a cyclohexylamine template agent, and preparing the Mg11(HPO3)8(OH)6 crystal powder bya hydrothermal synthesis method. According to the crystal material provided by the invention, comprehensive performance of reflection and radiation can be well combined, the actual cooling effect is2-10 DEG C better than the common heat reflecting material titanium dioxide in the market, and the crystal material can be well applied to the field of heat reflection infrared radiation.