Graphite anode plate anti-oxidation coating composition and application thereof

An anti-oxidation coating, graphite anode technology, applied in the direction of coating, electrodes, electrolysis components, etc., can solve the problem of large resistance at the connection between the graphite anode plate and the anode clamp, poor high temperature oxidation resistance of the graphite anode plate, and graphite anode plate. The conductive area becomes smaller and other problems, so as to reduce the number of replacements of the graphite anode plate, reduce the labor intensity of workers, and improve the performance of high temperature oxidation resistance.

Active Publication Date: 2021-07-30
包头市中鑫安泰磁业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0013] At present, there are problems: the service life of graphite anode plate in the electrolysis process of rare earth oxide molten salt is generally about 30 hours, and the service life is relatively low
The main reason is that the graphite anode plate exposed to the air has poor high temperature oxidation resistance, followed by the largest resistance and the highest temperature at the connection between

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0036] Example 1

[0037] First, the surface of the graphite anode plate is processed with a roller machine to form a 1-2 mm deep mesh groove, which is to prevent the coating from falling off. The mixture of fluorinated lanthanum, sodium silicate, zinc sodium phosphate, and water is used as an antioxidant coating material, and sodium silicate mainly function, and the oxidation of fluorinated lantomerium. The electrolyte in the fluoride and rare earth oxide molten salt electrolysis is the same material, and there is no problem that the product is contaminated. 3 kg of fluorinated lanthanum, 0.5 kg of sodium silicate, 0.2 kg of phosphate, 0.15 kg of 0.15 kg, uniformly coated on the graphite anode plate, the coating thickness 2-3mm, placed for 1-2 hours, then put it into the horse The furnace is baked, and the sintering temperature of 300-400 ° C is baked, and time is 1 hour. After the coating is sintered 300-400 ° C, the antioxidant coating material is sintered on the surface of the gr

Example Embodiment

[0039] Example 2

[0040]First, the surface of the graphite anode plate is processed with a roller machine to form a 1-2 mm deep mesh groove, which is to prevent the coating from falling off. 2 kg of fluoride, 1 kg of lanthanium oxide, 0.5 kg of sodium silicate, 0.2 kg of phosphate, and 0.15 kg of 0.15 kg, evenly coated on the graphite anode plate, the coating thickness of 2-3 mm, placed for 1-2 hours, Then put it into the muffle furnace for baking, baking the sintering temperature of 300-400 ° C, time 1 hour. After the coating is sintered 300-400 ° C, the antioxidant coating material is sintered on the surface of the graphite anode plate.

Example Embodiment

[0041] Example 3

[0042] First, the surface of the graphite anode plate is processed with a roller machine to form a 1-2 mm deep mesh groove, which is to prevent the coating from falling off.

[0043] 3 kg of cerium fluoride, 0.5 kg of sodium silicate, 0.2 kg of zinc phosphate, 0.15 kg of 0.2 kg, uniformly coated on the graphite anode plate, the coating thickness 2-3mm, placed for 1-2 hours, then put it into the horse The furnace is baked, and the sintering temperature of 300-400 ° C is baked, and time is 1 hour. After the coating is sintered 300-400 ° C, the antioxidant coating material is sintered on the surface of the graphite anode plate.

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Abstract

The invention relates to a graphite anode plate anti-oxidation coating composition. The anti-oxidation coating composition comprises a rare earth metal compound, sodium silicate and zinc phosphate, and the rare earth metal compound is fluoride or/and oxide of rare earth metal. Sodium silicate and zinc phosphate are compounded to stably bond fluoride and oxide of rare earth metal on the graphite anode plate, so that the high-temperature oxidation resistance of the graphite anode plate can be remarkably improved, contact between air and the graphite anode plate is effectively prevented, the speed of oxidation reaction between the surface of the graphite anode plate and the air is further reduced, the service life of the graphite anode plate is prolonged, the frequency of replacing the graphite anode plate is reduced, the labor intensity of workers is reduced, the production efficiency is improved, and the production cost is reduced.

Description

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Claims

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Application Information

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Owner 包头市中鑫安泰磁业有限公司
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