Pulse laser deposition based preparation method of phase change film

一种脉冲激光沉积、薄膜的技术,应用在离子注入镀覆、金属材料涂层工艺、涂层等方向,能够解决高光波传输损耗等问题

Active Publication Date: 2022-01-25
SHANGHAI JIAOTONG UNIV PINGHU INTELLIGENT OPTOELECTRONICS RES INST
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Problems solved by technology

However, other than that when Ge 2 Sb 2 Te 5 When applied to integrated photonics devices, the extinction coefficients of amorphous and crystalline states at 1550nm are as high as 0.12 and 1.49, respectively (Stegmaier M, CarlosR, Bhaskaran H, et al.NonvolatileAll-Optical 1×2Switch for Chipscale PhotonicNetworks[ J].Advanced Optical Materials,2016,5(1):1600346.), resulting in high optical wave transmission loss in the optical waveguide device made of this material in the important communication band

Method used

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Embodiment Construction

[0038] The present invention will be further described below in conjunction with the accompanying drawings and specific embodiments, so that those skilled in the art can better understand the present invention and implement it, but the examples given are not intended to limit the present invention.

[0039] Ge based on pulsed laser deposition (PLD) in preferred embodiments of the present invention 2 Sb 2 Se 4 Te 1 The preparation method of the thin film is based on the pulsed laser deposition equipment, including the following steps: under vacuum conditions, the laser is used to irradiate the rotating target for pre-targeting, and then deposit Ge on the rotating silicon substrate. 2 Sb 2 Se 4 Te 1 film. refer to figure 1 , the pulsed laser deposition equipment is equipped with a rotating target 1, a rotating silicon substrate 2, a vacuum pump 3, a laser window 5 and other structures, and 4 is incident laser light.

[0040] In some embodiments, deposited Ge 2 Sb 2 Se ...

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Abstract

The invention discloses a pulse laser deposition based preparation method of a phase change film. The method is based on pulse laser deposition equipment, and comprises the following steps that under a vacuum condition, lasers are used for irradiating a rotary target material to carry out pre-targeting, and then a Ge2Sb2Se4Te1 film is deposited on a rotary silicon substrate. According to the method, the novel phase change material Ge2Sb2Se4Te1 is prepared through pulsed laser deposition, it is guaranteed that all elements in the alloy film are in a quite ideal component ratio, the refractive index change condition of the Ge2Sb2Se4Te1 in the gradual phase change process is achieved through annealing at the specific temperature and the specific time, the goodness value FOM is equal to 5.2 at the position of 1550 nm, the goodness value is the ratio of the change of the refractive index to the change of the extinction coefficient before and after phase change, and the phase change performance of the phase change material is reflected. For the novel phase change material Ge2Sb2Se4Te1 prepared based on pulsed laser deposition, the morphology change before and after phase change and the lattice structure under the crystalline state condition are researched, the change condition of the chemical attitude of the elements before and after phase change is analyzed, and the phase change mechanism of Ge2Sb2Se4Te1 is disclosed.

Description

technical field [0001] The invention relates to the technical field of thin film deposition, in particular to a preparation method of a phase change thin film based on pulsed laser deposition. Background technique [0002] Optical phase change materials (OPCM) are a group of unique materials, because of the huge contrast of optical properties before and after the phase change (crystalline state and amorphous state), in the fields of optical switches, image displays, optical storage and all-optical computers has been widely used. Chalcogenide phase change materials Phase change materials mainly include monobasic (Te-based, Sb-based), binary (SbTe-based, GeTe-based) and ternary-based (GeSbTe-based), Ge 2 Sb 2 Te 5 It has attracted widespread attention because of its nanosecond phase transition and the huge difference in optical constants (Δn>2.5) before and after the phase transition. With the increasing demand for chalcogenide phase change materials in the fields of op...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C14/28C23C14/06
CPCC23C14/28C23C14/0623
Inventor 郑分刚汪成根袁伟张桂菊
Owner SHANGHAI JIAOTONG UNIV PINGHU INTELLIGENT OPTOELECTRONICS RES INST
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