The invention belongs to the technical field of solar panels, and especially relates to a high-light-transmittance ultra-white figured glass and a preparation process thereof. The purpose of the invention is to solve the problem that an existing solar module is short in service life. The high-light-transmittance ultra-white figured glass comprises main materials and auxiliary materials, the main materials comprise SiO2, CaO and a mixture, the auxiliary materials comprise MgO, Al2O3, Fe2O3, Sb2O3, SO3 and CeO2, and the mixture is prepared by mixing Na2O and K2O. The use amount of antimony oxideand the use of cerium oxide are increased on the basis of the original raw materials of ultra-white glass, parts of ultraviolet rays are shielded after cerium oxide is added, a small amount of generated power is reduced, and the aging of the upper EVA and the lower EVA of a vacuum laminated battery piece of the solar module can be delayed, thereby the service life of the whole solar module can bewell prolonged; and the visible light transmittance is improved after antimony oxide is increased, so the defect that the transmittance of a solar spectrum curve is reduced due to the fact that cerium oxide is added in advance and then parts of ultraviolet rays are shielded is overcome.