Preparation method of charcoal-based heat conduction rubber

A heat-conducting rubber and bio-char technology, which is applied in the field of preparation of bio-char-based heat-conducting rubber, can solve the problems of decreased mechanical properties of rubber products, low bonding degree, poor compatibility between bio-char and rubber, etc., and achieve surface activity and increased roughness , modified filling effect, good thermal conductivity and mechanical properties

Inactive Publication Date: 2016-10-12
宁波金特信钢铁科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The technical problem mainly solved by the present invention: aiming at the current biochar used as a filler to produce heat-conducting rubber, due to the poor compatibility of biochar and rubber, the low d

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0019] Example 1

[0020] Weigh 1 kg of bamboo strips and grind and degum them in a corundum mortar for 1 hour, and then rinse the ground bamboo strips with 0.5mol / L hydrochloric acid for 2 hours and then dry them, and pickling the dried bamboos according to the solid-liquid ratio of 1:5 Mix the flakes with 1mol / L sodium hydroxide solution, shake and soak overnight on a shaker; after the end of immersion, the filter residue is obtained by centrifugal separation and placed in a Buchner funnel, filtered and washed with deionized water for 3 times, and the filter residue is naturally dried , Then put the dried filter residue into a carbonization furnace, heat it to 300°C under the protection of argon, heat it up to 300°C for 2 hours, and then grind it through a 100-mesh sieve to obtain bamboo-based biochar powder; weigh 100g peach gum and 500mL distilled water and mix Then put it into a beaker, move the beaker into a 60°C water bath and stir for 20 minutes to obtain a modified peac

Example Embodiment

[0022] Example 2

[0023] Weigh 2kg of bamboo strips and grind and degum them in a corundum mortar for 2h, and then rinse the ground bamboo strips with 0.5mol / L hydrochloric acid for 3h and then dry them. According to the solid-liquid ratio of 1:5, pickling the dried bamboo Mix the flakes with 1mol / L sodium hydroxide solution, shake and soak overnight on a shaker; after the end of immersion, the filter residue is obtained by centrifugal separation and placed in a Buchner funnel, washed with deionized water for 4 times, and the filter residue is naturally dried , Then put the dried filter residue into the carbonization furnace, heat it to 350°C under the protection of argon, and keep it carbonized for 3 hours, then grind through a 100-mesh sieve to obtain bamboo-based biochar powder; weigh 150g peach gum and 550mL distilled water and mix Then put it into a beaker, move the beaker into a 65°C water bath and stir for 25 minutes to obtain a modified peach gum solution. Mix the bambo

Example Embodiment

[0025] Example 3

[0026] Weigh 2kg of bamboo strips and grind and degum them in a corundum mortar for 2h, and then rinse the ground bamboo strips with 0.5mol / L hydrochloric acid for 3h and then dry them. According to the solid-liquid ratio of 1:5, pickling the dried bamboo Mix the flakes with 1mol / L sodium hydroxide solution, shake and soak overnight on a shaker; after the end of immersion, the filter residue is obtained by centrifugal separation and placed in a Buchner funnel, washed with deionized water for 5 times, and the filter residue is naturally dried , Then put the dried filter residue into a carbonization furnace, heat it to 400°C under the protection of argon, and keep it carbonized for 3 hours, then grind it through a 100-mesh sieve to obtain bamboo-based biochar powder; weigh 200g peach gum and 600mL distilled water and mix Then put it into a beaker, move the beaker into a 70°C water bath and stir for 30 minutes to obtain a modified peach gum solution. Mix the bamb

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Abstract

The invention relates to a preparation method of biochar-based heat-conducting rubber, and belongs to the technical field of rubber preparation. In the method, bamboo strips are used as raw materials, which are subjected to acid washing, alkali foaming, carbonization, compound modification by natural resin and vegetable oil under the action of microorganisms, and finally kneading with raw rubber to obtain thermally conductive rubber. The present invention modifies the surface of biochar by natural resin and vegetable oil, adheres a large number of natural resin particles and hydrophobic groups on its surface, increases the surface activity and roughness of biochar, enhances the binding effect of biochar and rubber, and reinforces natural resin. It can be cured and cross-linked to form a network structure, and at the same time, it can interpenetrate and penetrate with the network formed by the vulcanization of the rubber compound to form supplementary cross-linking, form more effective heat conduction network chains, improve the thermal conductivity of rubber, and at the same time, it can also modify the filling effect of biochar. , to improve the mechanical properties of the compound, it has both excellent thermal conductivity and excellent mechanical properties.

Description

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Claims

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Application Information

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Owner 宁波金特信钢铁科技有限公司
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