The invention discloses a molten iron jar melting agent and a preparation method and application of the molten iron jar melting agent. The molten iron jar melting agent is composed of, by weight, 0 to 100% of jet coal, 0 to 100% of anthracite, 0 to 100% of industrial salt and 0 to 100% of aluminum powder, wherein the sum of the weight percents of the components is 100%. The preparation method specifically includes the steps of A pretreatment and B preparation, wherein in the pretreatment process, materials are prepared according to a formula of the molten iron jar melting agent, the anthracite and the jet coal are smashed for use, and the industrial salt and the aluminum powder are purchased for use; in the preparation process, the smashed anthracite, the smashed jet coal, the industrial salt and the aluminum powder are weighed according to the proportion of the formula and then mixed and stirred evenly, so that a target object is obtained. The molten iron jar melting agent is placed in a molten iron jar before iron is placed in a blast furnace and 200 kg to 500 kg of the molten iron jar melting agent is added each time. The anthracite, the jet coal, the industrial salt and the aluminum powder are reasonably combined, so that the polymer effect is generated, the effect that one plus one is larger than two is achieved, an intense combustion reaction is generated after the agent is added to the surface of molten iron, and the reaction is complete.