System and method for treating copper-containing molten iron

A technology of molten iron and iron particles, which is applied in transportation and packaging, improvement of process efficiency, metal processing equipment, etc., can solve the problems of difficult large-scale industrial application, inability to further develop, and difficult gas pollution to the environment, and achieves reduction of raw material costs, Low production cost and the effect of improving purity

Pending Publication Date: 2017-06-13
JIANGSU PROVINCE METALLURGICAL DESIGN INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Most of these methods cannot be further developed due to low copper removal ability or too harsh conditions.
For example, when the melting separation method is used, it is only suitable for processing small pieces of scrap steel containing a large amount of exposed copper; if the gasification separation method is u

Method used

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  • System and method for treating copper-containing molten iron
  • System and method for treating copper-containing molten iron
  • System and method for treating copper-containing molten iron

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0074] Send the copper-containing molten iron at 1450 degrees Celsius to the atomization granulation device for atomization and granulation to obtain copper-containing fine iron particles with a particle size of less than 74 microns, accounting for 86%. Among them, TFe in the copper-containing molten iron contains 95wt%, Cu Containing 1.0wt%; Then the above-mentioned copper-containing fine iron particles, ammonia and carbon dioxide are sent to the stirring leaching tank to carry out ammonia leaching reaction, the ammonia leaching conditions are: the ammonia water mass concentration is 1%, the carbon dioxide mass concentration (in the form of (NH 4 ) 2 CO 3 ) is 2%, the liquid-solid ratio is 10:1, the ammonia immersion temperature is 40 degrees centigrade, and the time is 2h. After the reaction finishes, carry out solid-liquid separation to obtain iron powder and copper-containing ammonia immersion solution. TFe contains 95.5% of the iron powder. wt%, Cu contains 0.05wt%, iron po

Embodiment 2

[0076] Send the copper-containing molten iron at 1500 degrees Celsius to the atomization granulation device for atomization granulation, and obtain copper-containing fine iron particles with a particle size of less than 74 microns, accounting for 90%. Among them, the copper-containing molten iron contains 96wt% TFe and Cu 0.8wt%; then the above-mentioned copper-containing fine iron particles, ammonia and carbon dioxide are sent to the stirring leaching tank to carry out ammonia leaching reaction, and the ammonia leaching conditions are: the ammonia water mass concentration is 3%, and the carbon dioxide mass concentration (in the form of (NH 4 ) 2 CO 3 ) is 4%, the liquid-solid ratio is 6:1, the ammonia immersion temperature is 45 degrees centigrade, and the time is 1h. After the reaction finishes, carry out solid-liquid separation to obtain iron powder and copper-containing ammonia immersion solution. In the iron powder, TFe contains 97.2 wt%, Cu contains 0.04wt%, iron powder ca

Embodiment 3

[0078] Send the copper-containing hot metal at 1525 degrees Celsius to the atomization granulation device for atomization and granulation, and obtain copper-containing fine iron particles with a particle size of less than 74 microns, accounting for 95%. 0.6wt%; then the above-mentioned copper-containing fine iron particles, ammoniacal liquor and carbon dioxide are sent to the stirring leaching tank to carry out ammonia leaching reaction, and the ammonia leaching condition is: the ammoniacal liquor mass concentration is 6%, and the carbon dioxide mass concentration (with (NH 4 ) 2 CO 3 ) is 5%, the liquid-solid ratio is 3:1, the ammonia immersion temperature is 50 degrees Celsius, and the time is 30min. After the reaction is over, solid-liquid separation is carried out to obtain iron powder and copper-containing ammonia immersion solution. TFe content in iron powder is 98.2 wt%, Cu contains 0.03wt%, iron powder can be used as the steelmaking raw material of high-quality carbon st

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Abstract

The invention provides a system and a method for treating copper-containing molten iron. The system comprises an atomizing granulating device, an ammonia leaching device and an ammonia evaporating device, wherein the atomizing granulating device is provided with a copper-containing molten iron inlet and a copper-containing fine iron particle outlet; the ammonia leaching device is provided with a copper-containing fine iron particle inlet, an ammonia water inlet, a carbon dioxide inlet, an iron powder outlet and a copper-containing ammonia leaching liquid outlet; the copper-containing fine iron particle inlet is connected with the copper-containing fine iron particle outlet; the ammonia evaporating device is provided with a copper-containing ammonia leaching liquid inlet, an air inlet, a carbon dioxide outlet, an ammonia gas outlet and a copper oxide outlet; the copper-containing ammonia leaching liquid inlet is connected with the copper-containing ammonia leaching liquid outlet; and the carbon dioxide outlet is connected with the carbon dioxide inlet. According to the system, copper and iron in the copper-containing iron powder are separated through ammonia leaching, and copper is recovered by an ammonia evaporating method, so that the purity of the metal iron powder is improved, the recovery rate of copper is not less than 98.5 percent, the TFe content of the iron powder is not less than 95.5 percent by weight, and the Cu content is not more than 0.05 percent by weight.

Description

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Claims

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Application Information

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Owner JIANGSU PROVINCE METALLURGICAL DESIGN INST
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