56 results about "Ferric" patented technology

The invention relates to a surface coating modified lithium ion battery cathode material and a preparation method thereof. The surface coating modified lithium ion battery cathode material has a general chemical formula of LiNi<1-a-b>CoaAlbO2/M, wherein a is more than 0.1 and less than 0.3, b is more than 0.01 and less than 0.2, and M refers to a coating layer. The material is coated by adopting a dry method; the coating layer refers to one or a mixture of two of lithium iron phosphate and lithium ferric manganese phosphate; and the mass ratio of the coating layer to LiNi<1-a-b>CoaAlbO2 is (0.01-0.2):1. The surface coating modified lithium ion battery cathode material and the preparation method thereof disclosed by the invention have the advantages that the stability of the cathode material is improved, and the safety performance of the material is improved; and moreover, in the dry-method coating process, waste liquor is not produced, high-temperature sintering is not needed, and the energy consumption and cost can be reduced.

The invention discloses a phenol ortho-methylation catalyst and a preparation method thereof. The catalyst is an alkaline Fe/Mg compound oxide, wherein, the mol ratio of Fe to Mg is 1: (0.1-2). The preparation method comprises the following steps: mixing and dissolving soluble malysite and soluble magnesium salts into alcohols solvent according to a required proportion to prepare a solution A; adding polyethyleneglycol (PEG) into strong aqua ammonia to prepare a solution B; slowly mixing the solution A and the solution B in a cocurrent flow mode under the condition of normal temperature and ultrasound, and then going on with the ultrasound for 30 minutes; filtering, washing, drying and baking the obtained precipitation; porphyrizing the baked solid and repulverizing the solid into 10-20 mesh finely ground particles after tabletting; the finely ground particles are the catalyst. The catalyst has the advantages of high activity at low temperature, simple preparation, innocuity, good stability, high selectivity of ortho position, particularly high selectivity of orthocresol and few by-products.

The invention provides a synergetic metal recycling method for nickel and cobalt containing waste batteries and copper containing electronic waste. The preliminarily smashed and metal element enriched waste batteries and the copper containing electronic waste are mixed, and a slag former and a reducing agent in a certain ratio are blended for an oxidative reducing reaction; relatively active metal iron, aluminum and the like in the reaction process form oxide to enter an upper layer slag phase; metal cobalt and nickel enter copper liquid on the bottom layer, and therefore the metal phase and a slag phase are separated, and metal containing copper, cobalt and nickel is obtained; and copper, cobalt, nickel and other high-purity metal are recycled through electrorefining. The method is short in flow, high-temperature thermometallurgy is adopted for synergetically recycling the valuable metal in the batteries and the electronic waste, and the problems that traditional waste battery wet recycling efficiency is low, the environment is polluted, a large amount of lixivium needs to be used, and a large amount of acid and alkaline is consumed are avoided; and an efficient novel recycling way is provided for waste ternary battery and electronic waste resource recycling, and good industrial application prospects are achieved.

The invention relates to a control method of inclusions in a thick steel plate used for high heat input welding, which is characterized by adding a deoxidizing agent during steel liquid pouring, wherein the components and adding order of the deoxidizing agent are as follows: Mn and Si, Al, Ti, Ca and Mg; the Mg content is 0.0005-0.007%, when Mg is added for deoxidizing, the oxygen content in steel liquid needs to be adjusted and precisely controlled through adding Fe2O3 powder to a casting ingot mold, and the adding amount of the Fe2O3 powder is such that the oxygen content in the steel liquid is maintained at 0.001-0.008%; the Al content in steel is lower than 0.006%; the ratio of the inclusions with size smaller than 3mu m in the steel liquid is not lower than 80%, and the surface density of the inclusions is not smaller than 300 inclusions/mm<2>; the main components in the center of the inclusions are MgO or MgO and Ti2O3, and the main component on the external surface of the inclusions is MnS. The inclusions formed by using the method provided by the invention can favorably inhibit the growth of austenite crystal in a welding heat-affected zone and promote the growth of intracrystalline ferrite, thus improving the high heat input welding performance of the thick plate.

The invention relates to a micro-electrolytic filler containing a catalyst, which comprises ferrum and carbon and is added with a catalyst. The mass percents of ferrum, carbon and catalyst in the filler are 45-55%, 40-50% and 1-5%, respectively. The catalyst is one or more of the following elements: copper, vanadium, molybdenum and antimony. The invention has the advantages that, firstly, the COD de-electrolyzing rate in wastewater which has large concentration of organic matters, high poisonousness and high chromaticity and is hard to treat biochemically is improved by 10-20%, the COD removing rate is about 35-60%, the chromaticity can be removed by 60-90% and meanwhile the B/C value is improved by 0.1-0.3 and biodegradability of the wastewater is improved; secondly, the cylindrical cellular structure of the filler is beneficial to ensure adequate contract reaction of the filler and water to reduce the flowing resistance of the water; and thirdly, the carbon bed is not easy to passivate and harden and be blocked by iron mud, and the amount of sludge is reduced.

Hydrofluoroolefins and hydrochlorofluoroolefins contaminated with acid and/or iron compounds are purified and stabilized by contacting the haloolefin with a solid adsorbent such as alumina and then combining the purified haloolefin with one or more stabilizers such as an epoxide. The purified, stabilized haloolefins thus obtained are useful in a wide variety of end-use applications, including, for example, as refrigerants, propellants, foaming agents, fire suppression or extinguishing agents, and solvents.

The invention relates to a titanium-carbide-based steel-bonded cemented carbide material which is characterized in that titanium carbide (TiC) is adopted as a hard base of the material, and alloy tool steel is adopted as a binding phase. The volume percentage of the titanium carbide is 35-45%, and the mass percentage of the alloy tool steel is 55-65%. A total mass of the titanium carbide and the alloy tool steel is 100%. The alloy tool steel is composed of chromium, molybdenum, aluminum, nickel, titanium, and iron. According to the invention, the alloy material is prepared with an advanced low-pressure hot-isostatic-pressing sintering technology. The production process is simplified, production efficiency is improved, and energy consumption is greatly saved.

The invention relates to a technology for extracting zinc, lead and silver step by step by processing zinc-leached residues by a full wet process, and belongs to the technical field of zinc-leached residue recycle. The technology comprises the following steps of: preparing sulfuric acid into an appropriate concentration, and performing two-stage acid leaching in an appropriate liquid-solid ratio and at a high temperature to obtain slurry; filtering and separating the slurry to obtain lead-silver residues and a zinc-containing solution; oxidizing, neutralizing and deironing the zinc-containing solution, and depositing zinc by using sodium sulphide; and eluting the lead-silver residues, blending with caustic lye at an appropriate concentration to obtain slurry at a certain concentration, reacting at a certain temperature and in a certain solid-liquid ratio, and filtering and separating to obtain a filter cake and a filtrate, wherein the filtrate is directly added with sodium sulphide for lead deposition and the filter cake returns to a silver cyaniding leaching process. The technology is short in process, simple in operation, low in cost and mild and loose in reaction conditions; an acid solution and an alkali solution at high concentrations are not required; requirements on equipment are low; the extraction rate of metal is higher than that in the conventional method; no additional waste solid, waste liquid and waste gas are discharged; the recycle of the eluate and the filtrate is realized; and environment pollution is avoided from the source.

The invention discloses a copper and iron compound honeycomb coating type denitrification catalyst as well as a preparation method and application thereof. The catalyst provided by the invention takesa copper-based molecular sieve prepared through an ion exchange method or an immersion method as an active component, ferric polysilicate is added as a co-catalysis component, a honeycomb cordieriteceramic block is used as a carrier and an aluminum sol is used as as a binder. The catalyst prepared by the invention is prepared through a vacuum coating method; the preparation method is simple to operate, holes are not liable to block in a coating process and large-scale production is easy to realize; a coating has a large capacity and the coating fastness of active components is high; a good cooperative catalysis effect is formed between duplex metal including copper and iron, the denitrification activity of the catalyst is improved and the anti-H2O performance and anti-SO2 performance ofthe catalyst are also improved. The catalyst provided by the invention has a denitrification efficiency of 90 percent or more in a range of 220 to 510 DEG C and has a good application prospect in a stationary source denitrification direction.

The invention relates to composite reinforced multinutrition rice and a process thereof, belonging to the field of grain processing. The invention can be popularized and applied to the nutrition reinforcing process of other grains. In the invention, the composite reinforced multinutrition rice is processed by reinforcing five nutrients of folic acid, sodium ferric ethylene diamine tetraacetic acid, L-lysine hydrochloride, zinc gluconate and calcium lactate in rice by the steps of ultrasonic soaked adsorption, steaming gelatinization and microwave drying. The reinforced rice disclosed by the invention is rich in multiple nutrients and has short production cycle, high processing efficiency and high product quality; and appearance and other items of quality indexes meet the requirement.

The invention relates to a high-temperature iron-based zeolite molecular sieve honeycomb type denitration catalyst and a preparation method thereof, and belongs to the technical field of atmospheric pollution treatment technologies and environmentally friendly catalyzing materials. The preparation method comprises the following steps: mixing ferrous salts with ferrite; synthesizing a zeolite molecular sieve, natural zeolite molecular sieve powder, attapulgite clay or kaolin, glass fibers, an organic binding agent, wood pulp or sesbania cannabina powder, stearic acid and glycerinum; and carrying out mixing, ageing, extrusion forming, drying and roasting to obtain the iron-based zeolite molecular sieve honeycomb type denitration catalyst. According to the catalyst, the zeolite molecular sieve and natural raw mineral materials which have excellent thermal stability are used as carriers, and the running stability, the sintering resistance and the mechanical strength of the catalyst in a high-temperature environment are improved. The obtained honeycomb type denitration catalyst has good water resistance and sulfur poisoning resistance, and the conversion ratio of oxynitride is greater than 90% under the conditions that the temperature is in the high-temperature range of 400-600 DEG C and the air speed is 10,000 h<-1>.

A nano-class magnetic particle-palygorskite composition, which can be magnetically controlled and used for cleaning raw materials, water, air, sewage, etc and preparing target medicines, is composed of palygorskite crystals and magnetic nanoparticles carried by said palygorskite crystal. It is prepared from palygorskite clay through suspending in water, adding Fe salt solution, hydrolytic reaction, dewatering, washing, and reductive calcining.

An iron removing flux for Mg alloy contains magnesium chloride, potassium chloride, sodium chloride, calcium chloride, calcium fluoride and Ti (or Mn) compound. Its advantages are high effect on removing iron and other impurities from Mg alloy, high activity and low cost.

The invention relates to a method for preparing a ferric vanadate-graphene negative electrode composite material. The method comprises the following steps: dispersing sheet layers of graphene, forming ferric vanadate on the surface of graphene, growing and performing after-treatment on the ferric vanadate attached to the surface of graphene. According to the method disclosed by the invention, the sheet layers of graphene are dispersed, so that the ferric vanadate is uniformly attached to the surface of the graphene. Therefore, the ferric vanadate-graphene negative electrode composite material is uniform in texture and high in dispersity, the performance is greatly improved, and hydrogen peroxide is added into graphene turbid liquid, so that reaction is carried out on the surface of the uniformly dispersed graphene, functional groups are generated, a negative ion state is formed, ferrous iron ions are easily adsorbed, the reaction rate is accelerated, the adsorption rate is increased, and the ions react with vanadate on the graphene surface so as to form uniform particles. The ferric vanadate-graphene negative electrode composite material disclosed by the invention has low discharge voltage and extremely high discharge capacity, the raw materials are wide in source, and the cost is reduced.

The invention relates to a method for processing red mud by utilizing iron pyrites, comprising the following steps of: uniformly mixing air-dried red mud and the iron pyrites according to a certain proportion; and then heating under the condition of oxygen isolation so as to transform Fe2O3 contained in the red mud into magnetic Fe3O4. The red mud processed by utilizing the method disclosed by the invention is not only neutralized in alkalinity, but also has iron oxide content being less than 2 percent and can be used as a fire-resistant raw material; in addition, the iron oxide obtained through magnetic separation can be used as an iron smelting raw material.

The present invention relates to a preparation method of low-temperature light radiation, which is used for preparing a ferroelectric film of bismuth titanate doped with rare earth. The method solves the problems of the ferroelectric film of bismuth titanate prepared with the existing methods, such as the poor anti-fatigue properties, the small value of remanent polarization, the low reliability of storage, and the excessively high temperature of crystallization in the crystallization process and so on. The preparation method comprises the following two steps: preparing precursory sol of bismuth titanate doped with rare earth and molding the precursory sol. The ferroelectric film prepared in the method has excellent anti-fatigue properties, higher intensity of polarization, higher reliability of storage, and lower temperature of crystallization. The preparation method has the advantages of simple process, simple equipment, short preparation cycle, cheap raw materials that can be purchased in the market, and low cost.

A NiCuSiFe alloy prepared from Ni and Cu contained waste through resmelting contains Ni (25-60 wt%), Cu (25-60), Si (8-15), impurity (less than or equal to 0.2) and Fe (the rest), and can also be used as additive for smelting refractory steel, high-weatherability steel and other alloy steel. Its advantages are low smelting point, high dispersity and deoxidizing effect in molten steel and low cost.

The invention belongs to the field of sludge treatment and particularly relates to a sludge solidifier and a preparation method of the solidifier. The sludge solidifier mainly comprises magnesia, modified kieselguhr, wood ceramic, poly-ferric sulfate, tea saponin, vanillin and sodium silicate. The prepared sludge solidifier has the advantages that the sludge solidifier is simple to operate, has good dehydration, and microorganism and heavy metal removal effects, improves the quality of sludge filtrate, and reduces environmental pollution; the sludge solidifier is low in cost and environment-friendly, and is convenient for large-scale popularization and application.

The invention provides a ductile cast iron material, a composition containing the same and a production method of a bearing saddle and ductile cast iron. The ductile cast iron material comprises the following components in percentage by weight: 3.35-3.81% of C, 2.35-2.75% of Si, 0.35-0.85% of Mn, 0.30-0.56% of Cu, P not more than 0.05%, S not more than 0.05%, and the balance of iron and inevitable impurities. The yield strength, the tensile strength and the elongation of the ductile cast iron produced by the ductile cast iron material with the components can reach standard requirements of the bearing saddle on the tensile strength, the yield strength and the elongation, so that the ductile cast iron can be used for producing the bearing saddle.

The invention relates to the field of liquid dairy product, in particular to a milk oligopeptide added liquid milk and a preparation method thereof. The milk oligopeptide added liquid milk, based on 1000 parts by weight, comprises 942-996 parts of milk, 0-50 parts of white granulated sugar, 3-5 parts of milk oligopeptide, 0.1-1.5 parts of thickening agent and 0.9-1.5 parts of emulsifying agent combination, wherein the emulsifying agent comprises 0.8-1.1 parts by weight of sucrose fatty acid ester with HLB value being 15 and HLB of total emulsifying agent being 9-11. The invention surmounts the technical difficulty that a quantity of milk scale is produced when adding high protein substance in superhigh temperature liquid milk, adds variety of liquid dairy products which are suitable for puerperae, rich in protein and Fe, and has high absorptivity and good mouth feel, and innovates the product structure and formula composition of original compound liquid milk, thus new product varieties appear on market.

The invention relates to the technical field of inorganic materials, and discloses a preparation method for a ferrous carbonate/graphene composite material. The preparation method comprises the steps of: I. mixing graphene materials, water-soluble ferrite, urea and water to form a suspension, wherein the mass ratio of the graphene materials to the water-soluble ferrite is (0.02-0.2):1, and the amount-of-substance concentration ratio of the urea to the water-soluble ferrite is (20-100):1; II. putting the suspension into a reaction kettle, controlling the temperature to be 100-180DEG C, and carrying out hydrothermal reaction for 4-12h to obtain the ferrous carbonate/graphene composite material. The invention further provides a lithium ion battery prepared by taking the ferrous carbonate/graphene composite material as a negative electrode material. By being synthesized through low-temperature hydrothermal reaction, the ferrous carbonate/graphene composite material is high in specific capacity and good in cycling performance, and has excellent development prospects after being applied to the negative electrode materials of the lithium ion battery.

The invention discloses a boron-phosphorus alloy cast iron used for the cylinder body of an air compressor and a manufacturing process thereof. : Fe 94; C 3-4; Si 2-3; Mn 0.5-1.0; P 0.1-0.5; S 0.05-0.1; B 0.03-0.05. The manufacturing process of the present invention is: raw and auxiliary materials-pig iron, scrap steel-electric furnace smelting-tapping inoculation, inoculation with flow-filtering casting-finished cylinder body. The invention is suitable for making cylinder blocks of air compressors.

The invention relates to a method for the melting purification of magnesia by using a waste magnesium product. The adopted technical scheme is that the method comprises the following steps of: manually picking out and removing impurities visible to the naked eye from various purchased waste magnesium products; crushing and grinding the waste magnesium products subjected to the impurity removal into powder of below 800 meshes and removing iron with an iron removing device; removing carbon from the powder subjected to the iron removal by the water floatation method; loading the powder subjected to the carbon removal by the water floatation method into a kiln bogie, conveying the kiln bogie loaded with the powder to a tunnel kiln or a shuttle kiln, closing the kiln door, stirring the powder at the temperature of 550 to 650 DEG C and blowing in oxygen for 2 to 4 hours; uniformly mixing the powder subjected to the carbon removal with light burnt magnesium powder in a weight ratio of 1:2-4 and performing compression molding and drying; conveying the dried blank to a high-temperature electric arc furnace for melting at the temperature of 2,500 to 3,500 DEG C for 6 to 8 hours; and cooling, crushing and selecting the products. The method has the advantages of saving resource, protecting environment and saving energy.

The invention discloses a method for preparing lithium manganate by a wet-doping method. By the wet-doping method, manganese chloride solution, ammonium bicarbonate solution and lanthanum nitrate solution are reacted in aqueous solution. Lanthanum hydroxide and manganese carbonate are generated in a coprecipitation way. Manganic manganous oxide-doped crystals are obtained after high-temperature calcination, crushing and grading. Lithium carbonate and the manganic manganous oxide-doped crystals are mixed according to the molar ratio of lithium to manganese, and the molar ratio is 1.15:2. After being mixed effectively and uniformly, the above mixture is put into a kiln to be sintered at a high temperature. After cooling, crushing, grading, sieving and deironing of the sintered materials, spinel-shaped and lanthanum-doped lithium manganate is obtained. The method can combine materials and doping elements tightly. During the high-temperature calcination reaction, the doping elements can be inserted into crystal structures to be doped completely and fused with the doped crystals together. The doping of lanthanum element can raise the average oxidation state of manganese ions, inhibit Jahn-Teller effect effectively, reduce the capacity fading and raise the cycle performance.

The invention relates to a high-temperature-resistant high-performance rare earth permanent magnet material. The high-temperature-resistant high-performance rare earth permanent magnet material is prepared from, by weight, 20-35% of rare earth elements, 0.8-1.5% of boron, 0.02-0.2% of molybdenum, 0.5-5% of silicon, 0.1-3% of vanadium, 0.02-0.5% of calcium, 0.02-0.5% of zirconium, 0.02-0.5% of chromium, 0.5-5% of nickel and the balance iron and inevitable impurities. The rare earth permanent magnet material has high high-temperature resistance and excellent mechanical performance and is low in cost and high in stability, a preparation method is simple, and large-scale industrial production can be easily achieved.