Aqueous acrylic resin which can degrade formaldehyde by using visible light and preparation method of aqueous acrylic resin

[0031] A water-based acrylic resin that degrades formaldehyde with visible light is made of methyl methacrylate, butyl acrylate, methacrylic acid, divinylbenzene and black phosphorus modified nano-titanium dioxide, and its specific component formula is as follows:

[0032]

[0033]

[0034] The preparation method of the water-based acrylic resin of the visible light degradation formaldehyde, its steps are as follows:

[0035] a. Preparation of black phosphorus modified nano-titanium dioxide; mixing the prepared nano-titanium dioxide and the stripped black phosphorus to make a visible light catalyst;

[0036]b. Take methyl methacrylate, butyl acrylate, methacrylic acid, divinylbenzene, and black phosphorus modified nano-titanium dioxide and mix them to make mixed monomers according to the above mass percentage ratio; The initiator and the emulsifier accounting for 41% of the total mass of the emulsifier were dissolved in deionized water accounting for 21% of the total mass o

[0042] A water-based acrylic resin for visible light degradation of formaldehyde, made of methyl methacrylate, butyl acrylate, acrylic acid, divinylbenzene and black phosphorus modified nano-titanium dioxide, its specific component formula is as follows:

[0043]

[0044] The preparation method of the water-based acrylic resin of the visible light degradation formaldehyde, its steps are as follows:

[0045] a. Preparation of black phosphorus modified nano-titanium dioxide: the prepared nano-titanium dioxide and the exfoliated BP are mixed to make a visible light catalyst;

[0046] b. Weigh methyl methacrylate, butyl acrylate, acrylic acid, divinylbenzene, and black phosphorus modified nano-titanium dioxide according to the above mass percentage ratio to make mixed monomers; The emulsifier and the emulsifier accounting for 59% of the total mass of the emulsifier were dissolved in deionized water accounting for 39% of the total mass of water to prepare the first solution. Accor

[0052] A water-based acrylic resin for degrading formaldehyde by visible light, made of ethyl methacrylate, amyl acrylate, methacrylic acid, divinylbenzene and silicon dioxide-modified nano-titanium dioxide, and its specific component formula is as follows:

[0053]

[0054]

[0055] The preparation method of the water-based acrylic resin of the visible light degradation formaldehyde, its steps are as follows:

[0056] a. Preparation of silica-modified nano-titanium dioxide: mixing the prepared nano-titanium dioxide and nano-silicon dioxide to make a visible light catalyst;

[0057] b. Ethyl methacrylate, pentyl acrylate, methacrylic acid, divinylbenzene, and silica-modified nano-titanium dioxide are mixed to form a mixed monomer according to the above-mentioned mass percentage ratio; 45% of the initiator and 50% of the total mass of the emulsifier were dissolved in 30% of the total mass of deionized water to prepare a first solution. According to the FOX formula, the mixe