Rapid formation and capacity grading method for soft package battery using high-voltage electrolyte

A soft-pack battery and electrolyte technology, which is applied in the field of lithium-ion batteries, can solve problems such as the impurity in the battery is not easy to decompose, the electrolyte is easy to decompose to produce gas, and the SEI film is not dense, so as to shorten the production cycle, reduce production costs, and reduce The effect of labor intensity

Inactive Publication Date: 2020-07-24
新乡华锐锂电新能源股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Aiming at the deficiencies of the prior art, the present invention provides a rapid composition and volumetric method using a high-voltage electrolyte pouch battery, which not only solves the problem that the electrolyte of the high-voltage battery is easy to decompose and prod

Method used

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  • Rapid formation and capacity grading method for soft package battery using high-voltage electrolyte
  • Rapid formation and capacity grading method for soft package battery using high-voltage electrolyte
  • Rapid formation and capacity grading method for soft package battery using high-voltage electrolyte

Examples

Experimental program
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Effect test

Example Embodiment

[0029] Example one:

[0030] 1: The electrolyte used in this high-voltage soft pack battery contains 1.5% of the film-forming agent hexafluoroisopropanol and 1.5% of the stabilizer hexamethyldisilazane;

[0031] 2: In an environment where the dew point is less than -45°C, the electrolyte with the above characteristics is injected and sealed, and then aged at a temperature of 60°C for 96h;

[0032] 3: After taking it out and cooling it to room temperature, it is air-sealed according to the conventional process;

[0033] 4: At a pressure of 2.0Kg / cm2 and a temperature of 38°C, the chemical conversion is performed first. The chemical conversion process is: the current of the first step of constant current charging is 0.01C, and the protection termination voltage is 3.5V; the second step of constant current charging current 0.1C, the protection termination voltage is 4.1V; the current of the third step of constant current charging is 0.3C, and the protection termination voltage is 5.0V;

[

Example Embodiment

[0036] Embodiment two:

[0037] 1: The electrolyte used in this high-voltage soft-pack battery contains 3% film-forming agent hexafluoroisopropanol and 2.5% stabilizer hexamethyldisilazane;

[0038] 2: In an environment where the dew point is less than -45°C, the electrolyte with the above characteristics is injected and sealed, and then aged at a temperature of 60°C for 108 hours;

[0039] 3: After taking it out and cooling it to room temperature, it is air-sealed according to the conventional process;

[0040] 4: At a pressure of 2.5Kg / cm2 and a temperature of 45°C, the chemical conversion is carried out first. The chemical conversion process is: the current of the first step constant current charging is 0.01C, and the protection termination voltage is 3.5V; the second step of constant current charging current 0.1C, the protection termination voltage is 4.1V; the current of the third step of constant current charging is 0.3C, and the protection termination voltage is 5.0V;

[0041] 5:

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Abstract

The invention relates to the technical field of lithium ion batteries, and discloses a rapid formation and capacity grading method for a soft package battery using high-voltage electrolyte. The methodcomprises the steps of (1) injecting electrolyte applied to the high-voltage soft package battery under the environment that the dew point is less than -45 DEG C, sealing the edges, and aging for 96to 120 hours at the temperature of 60 to 80 DEG C; 2) taking out the aged electrolyte subjected to edge sealing, cooling to room temperature, and carrying out air exhaust sealing according to a conventional process; and 3) carrying out formation and capacity grading treatment on the electrolyte subjected to air extraction and sealing. The aging time and the formation current of the electrolyte canbe actually adjusted according to the capacity of a single body and the precision of a test cabinet, but cannot be lower than the minimum value. By adopting the customized high-voltage electrolyte, experimental verification shows that the formation effect is good, the conventional performance is qualified, and the high-temperature performance is superior to the performance of conventional electrolyte and a conventional formation capacity grading battery..

Description

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Claims

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Application Information

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Owner 新乡华锐锂电新能源股份有限公司
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