Preparation method of three-dimensional carbon nanotube adhesive tape flexible current collector

一种柔性集流体、碳纳米管的技术,应用在混合电容器集电器、混合/双电层电容器制造等方向,能够解决限制电活性材料接触面积、限制电活性材料电化学表面积、不利柔性超级电容器电化学性能等问题,达到提高电化学性能、避免集流体损坏、成本低的效果

Active Publication Date: 2022-02-08
SHANXI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the currently used current collectors are all two-dimensional planar current collectors, which greatly limits the contact area with the electroactive material, especially when the electroactive material is loaded on the current collector, the two-dimensional planar collector Fluids cannot lead to distributed loading of these electroactive materials, which severely limits the electrochemical surface area of ​​the electroactive materials and thus is not conducive to the enhancement of the electrochemical performance of the fabricated flexible supercapacitors.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] A preparation method of a three-dimensional carbon nanotube tape flexible current collector, comprising the following steps:

[0021] The carbon nanotube film pasted with scotch tape was used as the anode, and the platinum sheet was used as the cathode, respectively immersed in 1mol / L H 2 SO 4 In the electrolytic cell of the solution, and the anode and the cathode are respectively connected to the positive pole and the negative pole of the DC power supply. Next, the carbon nanotubes were dispersed by applying a constant voltage of 2V between the anode and the cathode, the treatment time was 1800s, and the treatment temperature was 35°C. Subsequently, the dispersed current collector is washed with deionized water, and dried at room temperature to obtain a three-dimensional carbon nanotube tape flexible current collector.

[0022] figure 1 It can be seen that through the dispersion treatment, the carbon nanotube tape flexible current collector changes from a two-dimens...

Embodiment 2

[0024] A preparation method of a three-dimensional carbon nanotube tape flexible current collector, comprising the following steps:

[0025] The carbon nanotube paper pasted with insulating tape is used as the anode, and the platinum sheet is used as the cathode, which are respectively immersed in the electrolytic cell filled with 3mol / L NaOH solution, and the anode and cathode are respectively connected to the positive and negative poles of the DC power supply. Next, the carbon nanotubes were dispersed by applying a constant voltage of 10V between the anode and the cathode. The treatment time was 30s, and the treatment temperature was 5°C. A three-dimensional carbon nanotube tape flexible current collector was obtained.

[0026] figure 2 It can be seen that through the dispersion treatment, the carbon nanotubes in the current collector change from a two-dimensional aggregated structure to a three-dimensional dispersed structure. This three-dimensional dispersion structure ...

Embodiment 3

[0028] A preparation method of a three-dimensional carbon nanotube tape flexible current collector, comprising the following steps:

[0029] The carbon nanotube paper pasted with scotch tape is used as the anode, the platinum sheet is used as the cathode, and the calomel electrode is used as the reference electrode, which are respectively immersed in the electrolytic cell filled with 2mol / L NaCl solution, and the anode and the cathode are respectively connected to the positive electrode and the positive electrode of the DC power supply. Negative connection. Next, by applying a current density of 1 mA / cm between the anode and cathode 2 A constant current was used to disperse the carbon nanotube film, the treatment time was 3600s, and the treatment temperature was 30°C. Subsequently, the dispersed current collector is washed with deionized water, and dried at room temperature to obtain a three-dimensional carbon nanotube tape flexible current collector. The carbon nanotubes in...

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Abstract

The invention relates to the field of preparation of flexible current collectors, in particular to a preparation method of a three-dimensional carbon nanotube adhesive tape flexible current collector, and aims to solve the problem that the electrochemical surface area of an electroactive material is limited. According to the invention, the cheap adhesive tape is used as a flexible support body and an adhesive, and the carbon nanotube material is pasted on the adhesive tape; and the three-dimensional carbon nanotube adhesive tape flexible current collector is placed in an electrolyte aqueous solution to be dispersed through a constant current method or a constant voltage method, and the three-dimensional carbon nanotube adhesive tape flexible current collector is prepared. Compared with the existing two-dimensional flexible current collector, the highly dispersed carbon nanotube flexible current collector with the three-dimensional structure can disperse and load the electroactive material, so that the electrochemical performance of the constructed electrode and device is remarkably improved.

Description

technical field [0001] The invention relates to the field of preparation of flexible current collectors, in particular to a method for preparing a three-dimensional carbon nanotube tape flexible current collector. Background technique [0002] In recent years, the rapid development of flexible and wearable electronics has promoted the development of flexible energy storage devices. Flexible supercapacitors have the potential to efficiently supply energy to flexible electronic devices under different deformation states and improve the wearing comfort of wearable devices due to their fast charge and discharge, high capacity, long cycle life, and excellent mechanical deformation properties. Huge potential. At present, further improving the electrochemical performance and mechanical flexibility of the prepared flexible supercapacitor is the main demand and challenge to promote its wide application in flexible and wearable electronic devices. The components of flexible supercap...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01G11/68H01G11/70H01G11/86
CPCH01G11/68H01G11/70H01G11/86
Inventor 周海涵刘宇芩马灿良
Owner SHANXI UNIV
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