Conductive polymers having highly enhanced solubility in organic solvent and synthesizing process thereof

[0144] Embodiment 1: the preparation of high conductivity polyaniline (HCPANI)

[0145] In this example the emeraldine base form (EB) of high conductivity polyaniline (HCPANI) was prepared. 100 ml of distilled and purified aniline was slowly added dropwise to 6 liters of 1 mol / liter hydrochloric acid, and then the obtained solution was mixed with 4 liters of isopropanol. The temperature of the mixed solution was kept at -15°C. Ammonium persulfate ((NH 4 ) 2 S 2 o 8 ) 56 g was dissolved in 2 liters of 1 mol / liter of hydrochloric acid to form a solution, and then this solution was slowly added dropwise to the above-mentioned mixed solution under stirring to initiate polymerization, and the time for dropping was 40 minutes. After 3 hours, the polymerization was complete and a precipitate formed. The obtained precipitate was filtered with filter paper, and then washed with 1 liter of 1 mol / liter ammonium hydroxide (NH 4 OH) solution for washing. The precipitate was move

[0149] Except that the polymerization reaction temperature was about -25°C, other steps and conditions were the same as in Example 1. The polymerization reaction is carried out for 4-6 hours. It was determined by infrared spectroscopy and NMR analysis (results not shown) that the synthesized substance was emeraldine base polyaniline.

[0151] Except that the time for adding the free radical initiator ammonium persulfate was 3 hours, other steps and conditions were the same as in Example 1. The polymerization reaction is carried out for 3 to 8 hours. It was determined by infrared spectroscopy and NMR analysis (results not shown) that the synthesized substance was emeraldine base polyaniline.