The invention provides a method for analyzing the contents of fluorides in hazardous wastes. According to the method, a pretreated sample is completely combusted in an enclosed space by adoption of anoxygen bomb
combustion technology; one part of the
fluorine element in the
oxygen bomb is absorbed by absorption liquid in the
oxygen bomb and the other part is absorbed by absorption liquid in a gasabsorption
station through a gas form; the absorption liquid is combined to obtain
fluoride extracting solution; and the extracting solution is treated to obtain to-be-tested sample solution.
Fluorine ion series
standard solution is prepared; and a
standard curve is drawn for a negative logarithm (E(Mv)-log cF-(mg / L))of the concentration of
fluorine ions via a potential value E. An
ion chromatograph-
fluoride ion selective
electrode is utilized to measure the potential value of the to-be-tested sample solution; and the content of the fluorides is calculated via the
standard curve according tothe measured potential value. The method is relatively high in test result
correctness and is capable of greatly shortening the test time at the same time.