The invention relates to a method for manufacturing a thermoelectric module having a high-insulation
thermal coupling surface, low
thermal resistance and no
brazing layer. The method comprises the following steps: manufacturing an insulated frame which is embedded with at least two
metal electric-connection terminals by an injection molding method; preparing thermoelectric elements; placing the thermoelectric elements in through holes of the insulated frame; respectively spraying
metal coating on the upper ends and the lower ends of the thermoelectric elements;
grinding the sprayed surfaces; and covering an
alumina film layer on the grounded surfaces respectively, wherein the insulated frame is provided with a plurality of through holes in which thermoelectric elements are placed; grooves of which the number corresponds to that of the
metal electric-connection terminals are formed in side frames of the insulated frame and are communicated with different through holes; the first end parts of the metal electric-connection terminals are respectively arranged in the grooves, while the second end parts are positioned outside the side frames of the insulated frame. The thermoelectric module manufactured by the manufacturing method has the high-insulation
thermal coupling surface, the
low resistance and no
brazing layer, and has the characteristics of improvement on the reliability of the electric connection between the thermoelectric elements and an external
system, simplification of operation steps, reduction of material cost, excellent performance, and suitability for large-scale generalization and application.