Active carbon material derived based on green soy bean shells as well as preparation method and application of active carbon material

A technology of activated carbon and edamame shell, applied in the field of materials, achieves the effects of high yield, mild working conditions and simple operation

Pending Publication Date: 2021-07-30
SOUTHWEST UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

There are few reports on the preparation of carbon material electro

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0036] Embodiment 1, the preparation of activated carbon material derived from edamame hulls

[0037] The preparation method of the activated carbon material derived from edamame hulls, the specific steps are as follows:

[0038](1) Put the edamame shell powder with a particle size of 60 mesh in a tube furnace, under the protection of argon, raise the temperature at a rate of 5 °C / min to 200 °C for 1 hour, and then continue to heat up at a rate of 5 °C / min to Insulate at 400°C for 1 hour, then raise the temperature at a rate of 5°C / min to 800°C for 3 hours, and finally cool to room temperature to obtain a crude carbon material precursor derived from edamame hulls;

[0039] (2) Soak the crude carbon material precursor prepared in step (1) with a hydrochloric acid solution with a mass fraction of 10% for 1 hour, repeatedly suction filter and wash, and dry at 80° C. for 10 hours to obtain a crude carbon material;

[0040] (3) The coarse carbon material prepared in step (2) is

Example Embodiment

[0042] Embodiment 2, the preparation of activated carbon material derived from edamame hulls

[0043] The preparation method of the activated carbon material derived from edamame hulls, the specific steps are as follows:

[0044] (1) Put the edamame shell powder with a particle size of 40 mesh in a tube furnace, under the protection of argon, raise the temperature at a rate of 2°C / min to 200°C for 1 hour, and then continue to heat up at a rate of 2°C / min to Insulate at 400°C for 1 hour, then raise the temperature at a rate of 2°C / min to 800°C for 3 hours, and finally cool to room temperature to prepare a crude carbon material precursor;

[0045] (2) Soak the coarse carbon material precursor prepared in step (1) with 15% acetic acid solution for 1 hour, repeatedly suction filter and wash, and dry at 80° C. for 10 hours to obtain a coarse carbon material;

[0046] (3) Mix the coarse carbon material prepared in step (2) with KOH at a mass ratio of 2:1, and after fully grindin

Example Embodiment

[0048] Embodiment 3, the preparation of activated carbon material derived from edamame hulls

[0049] The preparation method of the activated carbon material derived from edamame hulls, the specific steps are as follows:

[0050] (1) Put the edamame shell powder with a particle size of 30 mesh in a tube furnace, under the protection of argon, raise the temperature at a rate of 3°C / min to 200°C for 1 hour, and then continue to heat up at a rate of 3°C / min to Insulate at 400°C for 1 hour, then raise the temperature at a rate of 3°C / min to 800°C for 3 hours, and finally cool to room temperature to prepare a crude carbon material precursor;

[0051] (2) Soak the coarse carbon material precursor prepared in step (1) with 20% sulfuric acid solution for 1 hour, repeatedly suction filter and wash, and dry at 80° C. for 10 hours to obtain a coarse carbon material;

[0052] (3) The coarse carbon material prepared in step (2) is mixed with KOH at a mass ratio of 3:1, after being full

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PUM

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Abstract

The invention discloses an activated carbon material derived based on green soy bean hulls and a preparation method and application thereof.The activated carbon material is prepared by taking the green soy bean hulls as raw materials and KOH as an activating agent through the steps that the green soy bean hulls are calcined to obtain a crude carbon material, then the KOH and the crude carbon material are fully ground and evenly mixed according to the proportion, then secondary carbonization treatment is conducted, and finally the activated carbon material is prepared after impurity removal, suction filtration and drying. The method is low in cost, rich in raw material source, simple to operate, convenient to treat, mild in action condition, high in yield (15.6%) and suitable for large-scale industrial production. The prepared activated carbon material has a porous structure, is filled with uniformly distributed micropores and mesopores, shows excellent electrochemical energy storage performance when being used as a capacitor electrode material, is a good electrode material, is further researched and prepared into a supercapacitor, and has potential and wide application prospects in the field of electrochemical energy storage.

Description

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Claims

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Application Information

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Owner SOUTHWEST UNIVERSITY
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