White polyester film and method for manufacturing same, solar cell back sheet, and solar cell module

a technology of white polyester film and solar cell, which is applied in the direction of photovoltaic energy generation, electrical equipment, semiconductor devices, etc., can solve the problems of reducing the adhesion, cleaving and peeling of polyester films, and difficult to obtain sufficient adhesion, etc., to achieve excellent adhesion, excellent weather resistance, and high power generation efficiency

Inactive Publication Date: 2017-12-28
FUJIFILM CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The present invention provides a white polyester film that is resistant to weather and has good adhesion to other resin layers. This film is useful for manufacturing solar cell modules that can generate high power for a long period of time. The invention also provides a solar cell back sheet that further contributes to the high power generation efficiency of the solar cell module.

Problems solved by technology

However, in a case in which white particles are added to polyester films, it is likely that the polyester films are cleaved and peeled off and the adhesiveness degrades.
In addition, in the case of transparent polyester films not including white particles, sufficient adhesiveness can be obtained by trying to find appropriate formulations of, mainly, coated layers; however, in white polyester films including white particles, it is difficult to obtain sufficient adhesiveness only by improving coated layers.
In addition, for example, in a case in which heat fixation temperatures after stretching are increased in manufacturing steps, the orientations of resins are relaxed, and the cleavage strengths of films are improved; however, in a case in which heat fixation temperatures are too high, the degradation of weather resistance attributed to the relaxation of the orientations is accompanied, and thus it is difficult to satisfy both weather resistance and adhesiveness.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0273]1>

[0274]As described below, terephthalic acid and ethylene glycol were directly reacted with each other so as to distill water away and were esterified, and a polyester resin (Ti catalyst-based PET) was obtained using a direct esterification method in which polycondensation was carried out at a reduced pressure and a continuous polymerization device.

[0275](1) Esterification Reaction

[0276]In a first esterification reaction tank, highly pure terephthalic acid (4.7 ton) and ethylene glycol (1.8 ton) were mixed together for 90 minutes so as to form a slurry, and the slurry was continuously supplied to the first esterification reaction tank at a flow rate of 3,800 kg / h. Furthermore, an ethylene glycol solution of a citric acid chelate titanium complex (VERTEC AC-420, manufactured by Johnson Matthey) in which citric acid coordinated Ti metal was continuously supplied, and a reaction was caused under stirring at an inner temperature of the reaction tank of 250° C. for an average resi...

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Abstract

Provided are a white polyester film including a polyester and white particles, in which, at an equivalent of a thickness of 250 μm, a machine stretching direction tear strength FMD is 2.5 to 6.0 N, a transverse stretching direction tear strength FTD is 2.0 to 5.0 N, a ratio of the machine stretching direction tear strength FMD to the transverse stretching direction tear strength FTD is 1.05 to 4.00, and a concentration of terminal carboxyl groups is 5 to 25 equivalents / ton, a method for manufacturing the same, a solar cell back sheet and a solar cell module in which the same white polyester film is used.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS[0001]This application is a continuation application of International Application No. PCT / JP2016 / 058021, filed Mar. 14, 2016, the disclosure of which is incorporated herein by reference in its entirety. Further, this application claims priority from Japanese Patent Application No. 2015-074615, filed Mar. 31, 2015, the disclosure of which is incorporated herein by reference in its entirety.BACKGROUND OF THE INVENTION1. Field of the Invention[0002]The present disclosure relates to a white polyester film and a method for manufacturing the same, a solar cell back sheet, and a solar cell module.2. Description of the Related Art[0003]Recently, solar cells have been attracting attention as next-generation sustainable energy sources.[0004]Solar cell modules are constituted of members such as a solar cell element, a sealing material that surrounds (seals) the solar cell element, a transparent front substrate disposed on a light-receiving surface side of...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): B29C55/12C08J5/18B29C48/305B29C48/92C08L67/02H01L31/049
CPCB29C55/12C08J5/18C08L67/02H01L31/049B29C55/005B29K2067/00B29K2105/16C08J2367/02Y02E10/50H01L31/0481
Inventor HARADA, KEINAKAI, SHINICHI
Owner FUJIFILM CORP
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