Lithium battery carbon cathode capable of preventing over-discharging

A technology of over-discharge and carbon negative electrode, which is applied in the field of lithium battery carbon negative electrode, can solve the problems of low capacity, aggravated over-discharge, difficulty, etc., and achieve the effect of avoiding dissolution and precipitation, and improving storage life and service life

Inactive Publication Date: 2014-06-04
SICHUAN JIANXING LITHIUM BATTERY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The consistency of a single battery is affected by the manufacturing level, and it is difficult to achieve complete consistency in capacity, voltage, internal resistance, and self-discharge
Therefore, batteries with low capacity, low voltage, high internal resistance, and high self-discharge will be given priority; at the same time, inconsistent cycle attenuation of different batteries will also aggravate the over-discharge phenomenon

Method used

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  • Lithium battery carbon cathode capable of preventing over-discharging
  • Lithium battery carbon cathode capable of preventing over-discharging
  • Lithium battery carbon cathode capable of preventing over-discharging

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0035] Embodiment one

[0036] Mix graphite, lithium titanate, Super P, CMC, and SBR according to the mass ratio of 90:5:2:1.0:2.0, dissolve in deionized water, stir evenly to make negative electrode slurry, and then use 90g / m on one side 2 coated on both sides of the copper foil, dried in vacuum at 85 degrees Celsius for 10 hours, then rolled and cut to form a carbon negative electrode.

Example Embodiment

[0037] Embodiment two

[0038] Mix mesophase carbon microspheres, lithium titanate, Super P, CMC, and SBR according to the mass ratio of 90:5:2:1.0:2.0, dissolve them in deionized water, stir evenly to make negative electrode slurry, and then Surface 90g / m 2 coated on both sides of the copper foil, dried in vacuum at 85 degrees Celsius for 10 hours, then rolled and cut to form a carbon negative electrode.

Example Embodiment

[0051] Embodiment three

[0052] The lithium battery carbon negative electrode of the discharge of the present embodiment includes a current collector, and the two sides of the current collector are coated with a vacuum-dried negative electrode slurry layer, and the negative electrode slurry layer is composed of the following components by weight: 85 parts of carbon active material , 1 part of lithium titanate, 0.5 part of conductive agent and 0.5 part of binder.

[0053] The carbon active material is one or a combination of graphite, mesocarbon microspheres, soft carbon, and hard carbon.

[0054]The conductive agent is one or a combination of nano-carbon powder (Super P), carbon nanotube (CNT), vapor-phase deposited carbon fiber (VGCF), and graphene.

[0055] The binder is one or a combination of styrene-butadiene rubber (SBR), sodium carboxyhydroxy cellulose (CMC), and polyvinylidene fluoride (PVDF).

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Abstract

The invention discloses a lithium battery carbon cathode capable of preventing over-discharging, which is used for solving the problems that the electric potential is rapidly raised when the capacity of an existing carbon cathode is used up, and cathode current collector copper is dissolved and is separated out on the surface of an anode. The lithium battery carbon cathode comprises a current collector, wherein the two sides of the current collector are coated with cathode slurry layers which are dried in vacuum; each cathode slurry layer is formed by mixing a carbon active material, an over-discharging function additive, a conductive agent and a bonding agent; the over-discharging function additive is lithium titanate. With the adoption of the lithium battery carbon cathode, a carbon cathode battery also has one part of capacity after being discharged to lower limit voltage, so that the dissolving and the separation of the current collector copper, caused by over-discharging, can be avoided, and the storage life and the service life of the battery are prolonged.

Description

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Claims

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Application Information

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Owner SICHUAN JIANXING LITHIUM BATTERY
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