The invention discloses a hydrophobicity regulation and control method of an alkaline
polyelectrolyte fuel
cell catalyst layer. The method comprises the following steps of firstly, synthesizing a series of
fluorine-containing alkaline polyelectrolytes, and dissolving and dispersing the
fluorine-containing alkaline polyelectrolytes in an
organic solvent (such as
dimethyl sulfoxide) to prepare a
polymer solution with a certain concentration; then adding the
hydrophobic polymer solution and the common
polymer solution into the catalyst dispersion solution according to different volume ratios (thehydrophobic
polymer solution can be completely used), and carrying out uniform
ultrasonic dispersion to prepare catalyst ink; finally, spraying uniformly dispersed catalyst ink on the alkaline membrane, removing the
solvent by heating in the spraying process, and placing the alkaline membrane with the catalyst layer between the gas
diffusion layers to form a membrane
electrode. The method is characterized in that the hydrophilicity and hydrophobicity of the catalyst layer can be adjusted by adding the
hydrophobic polymer solution in proportion, the hydrophobic
polyelectrolyte is located in athree-
phase reaction interface, and the hydrophilicity and hydrophobicity of reaction active sites of the catalyst layer can be accurately adjusted and controlled without introducing the extra
electrode components.