The invention relates to an inorganic
electrochromism ion transport layer and
assembly composite film system preparation method, which is characterized in that a WO3-based film, an AlPO4-based film, a NiO-based film and a TCO layer are sequentially prepared on a glass substrate / TCO layer through a chemical
liquid phase method or a magnetron
sputtering method, the WO3-based film, the NiO-based film and the TCO layer are prepared through the magnetron
sputtering method, and the WO3-based film, the AlPO4-based film, the NiO-based film and the TCO layer are arranged on the glass substrate / TCO layer. The
ion transmission layer AlPO4-based thin film is prepared by adopting a magnetron
sputtering method or a chemical
liquid phase deposition method. The invention has the advantages that: a novel
solid electrolyte material, namely an AlPO4-based material, is adopted as the
ion transmission layer; and the AlPO4-based ion
transport layer can be prepared by adopting a chemical
liquid phase deposition method. Compared with a
radio frequency mode needed by magnetron sputtering, the liquid
phase method is lower in cost and higher in efficiency. Meanwhile, the AlPO4-based ion
transport layer prepared by the liquid
phase method enables the
film structure to be loose and the ion mobility to be higher due to the characteristics of the preparation method, and the finally prepared
assembly has higher color changing efficiency.