Method for preparing composite type fracturing propping agent by utilizing gold ore tailings and zirconium oxide

A technology of zirconia fiber and fracturing proppant, which is applied in the fields of earth drilling, solid waste removal, mining fluid, etc., can solve the problems of poor mechanical properties and high brittleness of proppant, and achieve overcoming brittleness, improving chemical composition, The effect of improving overall performance

Inactive Publication Date: 2012-10-10
SHAANXI UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] At present, low-density, high-strength, low-brittleness and corrosion resistance have become the main research trend of proppant ceramsite. To achieve this goal, different high-temperature fluxes are introduced into the proppant formula and the way of ceramsite molding is optimized, which improves to a certain extent. The mechanical properties of the proppant improve the acid resistance and salt resistance of the material. However, it still cannot fundamentally solve the shortcomings of the poor mechanical properties (brittleness) of the ceramsite proppant

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] 1) Put the gold ore tailings and alumina powder into the ball mill for dry grinding, use alumina ball stone as the grinding medium, control the mass ratio of the ball and the raw material to 2:1, ball mill for 0.5h to 2h respectively, and then pass the 120 mesh sieve;

[0026] 2) Put 40% sieved gold mine tailings, 45% alumina powder and 15% high-temperature-resistant zirconia chopped fibers into the ball mill according to mass percentage, then add 10% gum aqueous solution to mix Evenly use alumina balls as the grinding medium, control the mass ratio of the grinding balls, the mixture and the aqueous gum solution to 2:1:0.3, grind for 0.5h to 3h to form a mixed slurry, and pass the slurry through a 300-mesh sieve;

[0027] Among them, alumina powder is α-alumina or corundum powder for industrial use, its corundum content is >98%, and its particle size is <10μm; high temperature resistant zirconia chopped fibers have a melting point greater than 1500°C-1700°C. High therm...

Embodiment 2

[0031] 1) Put the gold ore tailings and alumina powder into a ball mill for dry grinding, use alumina ball stone as the grinding medium, control the mass ratio of the ball and the raw material to 2.5:1, ball mill for 0.5h to 2h respectively, and then pass the 120 mesh sieve;

[0032] 2) Put 55% sieved gold mine tailings, 30% alumina powder and 15% high-temperature-resistant zirconia chopped fibers into the ball mill according to mass percentage, and then add 10% gum aqueous solution to mix Evenly use alumina balls as the grinding medium, control the mass ratio of the grinding balls, the mixture and the aqueous gum solution to 2.5:1:0.35, grind for 0.5h to 3h to form a mixed mud, and pass the mud through a 300-mesh sieve;

[0033] Among them, alumina powder is α-alumina or corundum powder for industrial use, its corundum content is >98%, and its particle size is <10μm; high temperature resistant zirconia chopped fibers have a melting point greater than 1500°C-1700°C. High ther...

Embodiment 3

[0037] 1) Put the gold ore tailings and alumina powder into a ball mill for dry grinding, use alumina ball stone as the grinding medium, control the mass ratio of the ball and the raw material to 3:1, ball mill for 0.5h to 2h and then pass the 120 mesh sieve;

[0038] 2) Put 50% sieved gold mine tailings, 40% alumina powder and 10% high-temperature-resistant zirconia chopped fibers into the ball mill according to mass percentage, and then add 10% gum aqueous solution to mix Evenly use alumina balls as the grinding medium, control the mass ratio of the grinding balls, the mixture and the aqueous gum solution to 3:1:0.38, grind for 0.5h to 3h to form a mixed slurry, and pass the slurry through a 300-mesh sieve;

[0039] Among them, alumina powder is α-alumina or corundum powder for industrial use, its corundum content is >98%, and its particle size is <10μm; high temperature resistant zirconia chopped fibers have a melting point greater than 1500°C-1700°C. High thermal stabilit...

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Abstract

The invention discloses a method for preparing a composite type fracturing propping agent by utilizing gold ore tailings and zirconium oxide. The method comprises the steps of mixing the gold ore tailings, alumina powders and high-temperature zirconium oxide chopped fibers, then adding gum water solution, mixing uniformly, conducting wet grinding and then pelleting; putting particles into alumina crucible and arranging into a silicon carbide rod resistor furnace, heating to 1230 DEG C from the room temperature at the heating speed being 5 DEG C / min-10 DEG C / min, keeping the temperature for 0.5h-1h, heating to 1350 DEG C-1400 DEG C at the heating speed being 5 DEG C / min-7 DEG C / min, keeping the temperature for 2h-3h; and cooling the particles in the furnace and then taking out the particles, and screening the particles by a 20-40 meshes sieve so as to obtain the composite type fracturing propping agent. According to the method, fibers (crystal whiskers) necessary for enhancing the strength and toughness is provided by integrating the concept of composite materials integrated with a non-compact ceramic propping agent and adopting the high-temperature reaction self generation mode, and the composite type fracturing propping agent with high strength, high toughness, low density and low damage rate is prepared by two measures, namely fiber reinforcement and particle reinforcement.

Description

technical field [0001] The invention relates to a method for preparing ceramic composite materials by using waste materials, in particular to a method for preparing composite fracturing proppants by using gold mine tailings and zirconia fibers. Background technique [0002] As a new industry, fracturing proppant has not been developed for a long time in my country, its product structure and varieties are still far from perfect, and the processing scale and level of the industry are in the initial stage of development. Most oil and gas fields are of medium depth, requiring fracturing proppants to have high strength and low fragmentation rate to withstand the huge pressure of the rock formation and various corrosions in the formation environment. In the world, sintered corundum products are often used as fracturing proppants in medium and deep oil and gas fields. Although this product can meet the requirements in terms of physical and chemical properties, the source of raw mat...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/622C04B35/80C04B35/78C09K8/80B09B3/00
Inventor 陈平
Owner SHAANXI UNIV OF SCI & TECH
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