Method for separating organic matters in reverse osmosis concentrated water

A reverse osmosis concentrated water and separation method technology, which is applied in the field of separation of organic matter in reverse osmosis concentrated water, can solve problems such as inability to classify and track DOM, change difficult pollutant components, etc., and achieve small system errors, high reliability, Simple operation effect

Active Publication Date: 2014-12-24
PETROCHINA CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] At present, some studies have shown that the organic matter in reverse osmosis concentrated water can be characterized and analyzed by methods such as ultraviolet spectroscopy, Fourier infrared spectroscopy, and fluorescence spectroscopy, but these methods are only for research on total dissolved organic matter (DOM) in reverse osmosis concentrated water , but it is impossible to classify and characterize DOM more carefully, and it is also difficult to track the changes of pollutant components in DOM during the treatment process
[0006] At present, for the separation method of organic matter in reverse osmosis concentrated water, there are no literature and patent technical reports at home and abroad.

Method used

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Embodiment

[0025] This embodiment provides a method for separating organic matter in reverse osmosis concentrated water, which includes the following specific steps:

[0026] (1) After filtering 1L of reverse osmosis concentrated water through a glass fiber filter membrane with a pore diameter of 0.45 μm, first pass through a peristaltic pump at a flow rate of 1.5mL / min through an XAD-8 non-ionic macroporous resin column, and then use Wash with ultrapure water twice the volume of XAD-8 non-ionic macroporous resin, and mix with reverse osmosis concentrated water after passing through the XAD-8 non-ionic macroporous resin column to obtain mixed effluent;

[0027] (2) Backwash the XAD-8 non-ionic macroporous resin column with 0.1mol / L hydrochloric acid solution 0.3 times the volume of the resin, and then backwash the XAD-8 with pure water 1.5 times the volume of the XAD-8 non-ionic macroporous resin Non-ionic macroporous resin column, the effluent component is hydrophobic basic organic matt...

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Abstract

The invention relates to a method for separating organic matters in reverse osmosis concentrated water. The method comprises the following steps: filtering reverse osmosis concentrated water via a glass fiber filter membrane, passing the reverse osmosis concentrated water through an XAD-8 resin column, washing the XAD-8 resin column by ultrapure water, and mixing the washing liquid and effluent to obtain mixed effluent; backwashing the XAD-8 resin column by hydrochloric acid, and backwashing the XAD-8 resin column by pure water, wherein the effluent component is a hydrophobic alkaline organic matter; regulating the pH value of the mixed effluent to be 2 by hydrochloric acid, and passing the mixed effluent through serially connected XAD-8 resin column and XAD-4 resin column, wherein the effluent is a hydrophilic organic matter; backwashing the XAD-8 resin column by sodium hydroxide, and backwashing the XAD-8 resin column by pure water, wherein the effluent component is a hydrophobic acidic organic matter; backwashing the XAD-4 resin column by the sodium hydroxide, and backwashing the XAD-4 resin column by pure water, wherein the effluent is a weakly hydrophobic acidic organic mater; carrying out Soxhlet extraction on the dried XAD-8 resin by methanol, carrying out rotary vaporization on the prepared extracting solution until the extracting solution is dry, and dissolving by pure water to obtain the hydrophobic neutral organic matters. According to the separation method provided by the invention, organic matters in the reverse osmosis concentrated water can be effectively separated.

Description

technical field [0001] The invention relates to a method for separating organic matter in reverse osmosis concentrated water, belonging to the technical field of sewage treatment. Background technique [0002] At present, membrane treatment technology has gradually developed into a water treatment technology widely used in industry and daily life. Among them, reverse osmosis technology has the characteristics of good effluent quality and high recovery rate, and has been successfully applied to industrial sewage reuse. After the industrial wastewater is treated, it enters the reverse osmosis process device, and the hardness ions and organic matter are removed to a large extent, and the effluent can be directly reused in the boiler. However, due to the limitation of influent water quality and treatment cost and other factors, the actual water collection rate of reverse osmosis membrane was 43% on average in 2004, and the researchers predict that it can only reach 61% by 2015,...

Claims

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Application Information

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IPC IPC(8): C02F9/10
Inventor 张华吴百春张晓飞邓皓刘光全罗臻李婷刘译阳王毅霖杨雪莹
Owner PETROCHINA CO LTD
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