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6 results about "Nickel salt" patented technology

Preparation method of radial structure spherical NCM811 type ternary positive electrode material

ActiveCN110330060AReduced anisotropic volume changeHigh tap densityCell electrodesSecondary cellsNickel saltFiltration
The invention provides a preparation method of a radial structure spherical NCM811 type ternary positive electrode material. The preparation method comprises the following steps: preparing a nickel salt, cobalt salt and manganese salt solution used as a solution 1, wherein a molar ratio of Ni:Co:Mn is 8:1:1; taking a precipitant, and preparing a solution 2; taking a complexing agent, and preparinga solution 3; adding the complexing agent solution into a reaction kettle as a base solution; adding the solution 1, the solution 2, and the solution 3 into the reaction kettle, introducing an inertgas to carry out protection, controlling the total ammonia concentration of the reaction system to be 0.5-1.5 mol/L, and performing aging under a pH value of 11.3-11.7 at a temperature of 45-55 DEG Cfor 5-15 h; washing the obtained reaction product, performing suction filtration, and drying the reaction product to prepare a precursor; grinding and uniformly mixing the precursor and a lithium saltwhich are used as raw materials; placing and sintering the obtained mixture in a muffle furnace in an oxygen atmosphere, wherein the sintering process comprises sintering at 400-500 DEG C for 4-8 h,and sintering at 700-780 DEG C for 10-15 h; and cooling the sintered mixture to room temperature to prepare the positive electrode material. The material obtained by the invention has the advantages of stable structure, excellent electrochemical performances, and reduction of the industrialization cost.
Owner:HAINAN UNIVERSITY

Selective hydrogenation catalyst

ActiveCN103566942AEasy to prepareShort preparation cycleMetal/metal-oxides/metal-hydroxide catalystsRefining by selective hydrogenationNickel saltAlloy catalyst
The invention provides a selective hydrogenation catalyst. The selective hydrogenation catalyst is prepared by a method comprising the following steps: firstly, evenly mixing a soluble nickel salt solution with the mixed sol of an aluminum compound and a titanium compound to obtain a mixed solution; secondly, dropwise adding a metal boron hydride to the mixed solution in an inert atmosphere at a temperature ranging from 0 to 30 DEG C, stirring, and finally, obtaining an amorphous alloy catalyst with the composite sol as the carrier. The catalyst provided by the invention is characterized in that the preparation method of the catalyst is simple, the step of preparing a solid carrier is omitted, the preparation period is short and the cost is low, and the catalyst can be reused; and moreover, the catalyst is high in catalyst activity and good in selectivity, and has a good application prospect.
Owner:CHINA PETROLEUM & CHEM CORP +1

Method for synthesizing 3-(methylthio) dibenzenamine by light/nickel concerted catalysis

ActiveCN108409618AMild reaction conditionsHigh coupling efficiencySulfide preparationNickel saltBenzene
The invention discloses a method for synthesizing 3-(methylthio) dibenzenamine by light / nickel concerted catalysis. According to the method, cheap 3-(methylthio) benzenamine and halogeno benzene are used as raw materials, a light / nickel concerted catalysis strategy is used for constructing C-N bonds for the first time, and pyridazines drug key intermediate 3-(methylthio) dibenzenamine is synthesized. The method has the advantages that 1) the use amount of a photocatalyst is low, and is 0.01-0.02% of the molar weight of the halogeno benzene; 2) nickel salt is directly used as a metal catalyst such as nickel bromide, and an external ligand is not required; 3) reaction conditions are gentle, and can be effectively carried out at the temperature of 40-50 DEG C; and 4) the product can be directly obtained by reduced pressure distillation and is easily separated. By the remarkable advantages, the method has good industrial application prospect.
Owner:SHAANXI NORMAL UNIV

Preparation method of special-morphology micro nano structural lithium-rich manganese-based cathode material

ActiveCN110143619AAchieving controllable equipmentRealize controllable preparation of special morphologyMaterial nanotechnologyPositive electrodesNickel saltHigh energy
The invention discloses a preparation method of a special-morphology micro nano structural lithium-rich manganese-based cathode material, and belongs to the technical field of novel energy material energy storage material preparation processes. The method comprises the following steps: dissolving a manganese salt and a nickel salt into distilled water according to a ratio to obtain an A liquid; dissolving a homogeneous precipitant weighed according to a ratio into distilled water to obtain a B liquid, introducing a certain ratio of an ionic liquid into the B liquid, performing full stirring, and performing uniform mixing; mixing the A liquid and the mixed B liquid, and performing full stirring; transferring the mixed liquid to a hydrothermal reaction kettle, performing a hydrothermal reaction, performing cooling to room temperature, performing centrifugal separation, performing washing, and performing drying to obtain a manganese-based precursor material; and finally grinding the precursor and a certain ratio of lithium carbonate, performing uniform mixing, performing pre-sintering, and performing calcination to obtain the lithium-rich manganese-based cathode material. The method provided by the invention solves the problems of high energy consumption, long consumed time and difficulty in control of product topography characteristics in the preparation process in the prior art.
Owner:JISHOU UNIVERSITY
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