Biochemical-photocatalytic advanced water treatment method for PBBC wastewater

A photocatalytic and water treatment technology, applied in water/sewage treatment, multi-stage water/sewage treatment, biological water/sewage treatment, etc., to reduce load, improve treatment effect, and increase ratio

Active Publication Date: 2015-05-20
山东默锐环境产业股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The technical problem to be solved by the present invention is to provide a biochemical-photocatalytic deep water treatment method for PBBC ​​wastewater, which can completely degrade the PBBC ​​wastewater with high concentration, high toxicity and high salt. , no secondary pollution, low operating cost, to make up for the defects in the above-mentioned background technology

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0027] Example 1

[0028] The basic situation of the raw water to be treated is: PBBC ​​wastewater. The wastewater mainly contains phenol, tetrabromobisphenol A (TBBA) and a very small amount of dichloromethane and triethylamine. Wastewater pH is 6.5~7.5, COD value is 2500mg / L, BOD 5 / CODcr is 0.26, and the chloride ion content is higher, at 4000mg / L, which belongs to high toxicity, high salt and refractory wastewater.

[0029] The PBBC ​​wastewater is filtered to remove suspended solid particles in the water, while also removing part of the organic matter. At room temperature, the pretreated PBBC ​​wastewater is reacted under the catalysis of ultraviolet rays, and a nickel mesh loaded with titanium dioxide is used as a photocatalyst. The wavelength of the ultraviolet rays is 254 nm. The PBBC ​​wastewater flows through the nickel mesh and In the photocatalytic reactor of the ultraviolet lamp tube, the photocatalytic reaction time flowing through is 1.5 hours, and the pH value o

Example Embodiment

[0034] Example 2

[0035] The basic situation of the raw water to be treated is: PBBC ​​wastewater. The wastewater mainly contains phenol, tetrabromobisphenol A (TBBA) and a very small amount of dichloromethane and triethylamine. Wastewater pH is 6.5~7.5, COD value is 2500mg / L, BOD 5 / CODcr is 0.26, and the chloride ion content is higher, at 4000mg / L, which belongs to high toxicity, high salt and refractory wastewater.

[0036] The PBBC ​​wastewater is filtered to remove suspended solid particles in the water, while also removing part of the organic matter. At room temperature, the pretreated PBBC ​​wastewater is reacted under the catalysis of ultraviolet rays, and a nickel mesh loaded with titanium dioxide is used as a photocatalyst. The wavelength of the ultraviolet rays is 254 nm. The PBBC ​​wastewater flows through the nickel mesh and The photocatalytic reactor of the ultraviolet lamp tube, the flow velocity of the PBBC ​​wastewater is 2.5m 3 / h, the photocatalytic reacti

Example Embodiment

[0041] Example 3

[0042] The basic situation of the raw water to be treated is: PBBC ​​wastewater. The wastewater mainly contains phenol, tetrabromobisphenol A (TBBA) and a very small amount of dichloromethane and triethylamine. Wastewater pH is 6.5~7.5, COD value is 2500mg / L, BOD 5 / CODcr is 0.26, and the chloride ion content is higher, at 4000mg / L, which belongs to high toxicity, high salt and refractory wastewater.

[0043] The PBBC ​​wastewater is filtered to remove suspended solid particles in the water, while also removing part of the organic matter. At room temperature, the pretreated PBBC ​​wastewater is reacted under the catalysis of ultraviolet rays, and a nickel mesh loaded with titanium dioxide is used as a photocatalyst. The wavelength of the ultraviolet rays is 254 nm. The PBBC ​​wastewater flows through the nickel mesh and The photocatalytic reactor of the ultraviolet lamp tube, the flow velocity of the PBBC ​​wastewater is 3.5m 3 / h, the photocatalytic reacti

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Abstract

The invention discloses a biochemical-photocatalytic advanced water treatment method for PBBC wastewater. The method comprises the following steps: (1) filtering the PBBC wastewater; (2) taking a nickel net loaded with titanium dioxide as a photocatalyst, wherein the wave length of the ultraviolet is 254 nm, the light-catalyzed reaction time is 1.5-3 hours; (3) reacting the wastewater in an ABR reaction pool for 20-40 hours, raising the temperature to 28-32 degrees centigrade and continuously performing aeration reaction for 12-24 hours; (4) reacting the wastewater under a catalytic action of the ultraviolet, taking the nickel net loaded with titanium dioxide as a photocatalyst, wherein the wave length of the ultraviolet is 254 nm, the light-catalyzed reaction time is 2-3 hours; (5) performing ion exchange on the wastewater through an ion exchange resin to desalt. By means of combining the biochemical process with the photocatalytic process, through the photocatalytic pretreatment, the method is capable of increasing the biodegradability of the wastewater to have complementary advantages and achieving the aim of advanced degradation of the wastewater.

Description

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Claims

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Application Information

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Owner 山东默锐环境产业股份有限公司
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