Process method for preparing lithium battery diaphragm by using 3D printing technology

A lithium battery diaphragm, 3D printing technology, applied in the field of lithium-ion batteries, can solve the problems of easy peeling off of the coating, complicated process, and uneven pores

Pending Publication Date: 2020-07-24
ZHEJIANG KEATON NEW MATERIAL TECH CO LTD
View PDF27 Cites 4 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, due to the limitation of technology and materials, there are some problems to be solved in the existing separators: 1) The pore formation of the base film is not uniform, and local defects are inevitable; 2) The inorganic material ceramic separator, PVDF or PMMA coating film coating The thickness is uneven, the coating process is complicated, and the coating is easy to fall off; 3) The thin-layer diaphragm has a large heat shrinkage; 4) The coating process is prone to produce inorganic waste residue, organic solvent discharge and other environmental problems; 5) The thickness of the diaphragm is difficult to control; 6 ) The process is complex and the processing cost is high
Its shortcomings are: 1) The process is

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Process method for preparing lithium battery diaphragm by using 3D printing technology
  • Process method for preparing lithium battery diaphragm by using 3D printing technology
  • Process method for preparing lithium battery diaphragm by using 3D printing technology

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] Step 1, mix the PP diaphragm base material, ultrafine alumina powder, and PVDF in the mixer according to the ratio of 7:2:1, transfer the evenly mixed material to the drum dry grinder, and grind to Mixed material powder with a particle size of 30 μm.

[0042] Step 2, transfer the mixed material powder obtained in step 1 to a heater with stirring, heat to 180°C to melt the material, then add NMP to adjust the viscosity of the material to 80000mPa.s, so that the material has a certain fluidity, and fully stir for 3 hours . Get the materials to be printed.

[0043] Step 3, transfer the melted material to be printed to the material injector of the 3D printer, and the nozzle arrangement width of the 3D printer is 1.5m.

[0044] The thickness of the diaphragm, the shape and diameter of the channel, the diameter of the membrane line, and the printing speed are set through the computer of the printer. After starting the printing, push the plunger of the syringe so that the mate

Embodiment 2

[0046] Step 1, mix the PE diaphragm base material, ultrafine alumina powder, and PVDF in the mixer according to the ratio of 7:2:1, transfer the evenly mixed material to the drum dry grinder, and grind to Mixed material powder with a particle size of 30 μm.

[0047] Step 2, transfer the mixed material powder obtained in step 1 to a heater with stirring, heat to 175°C to melt the material, then add NMP to adjust the viscosity of the material to 80000mPa.s, so that the material has a certain fluidity, and fully stir for 3 hours . Get the materials to be printed.

[0048] Step 3, transfer the melted material to be printed to the material injector of the 3D printer, and the nozzle arrangement width of the 3D printer is 1.5m.

[0049] The thickness of the diaphragm, the shape and diameter of the channel, the diameter of the membrane line, and the printing speed are set through the computer of the printer. After starting the printing, push the plunger of the syringe so that the mate

Embodiment 3

[0051] Step 1. Mix polypropylene non-woven diaphragm base material, ultrafine alumina powder, and PVDF in a mixer in a ratio of 7:2:1, and transfer the evenly mixed material to a drum-type dry grinder , grind to a mixed material powder with a particle size of 30 μm.

[0052] Step 2, transfer the mixed material powder obtained in step 1 to a heater with stirring, heat to 175°C to melt the material, then add NMP to adjust the viscosity of the material to 80000mPa.s, so that the material has a certain fluidity, and fully stir for 3 hours . Get the materials to be printed.

[0053] Step 3, transfer the melted material to be printed to the material injector of the 3D printer, and the nozzle arrangement width of the 3D printer is 1.5m.

[0054] The thickness of the diaphragm, the shape and diameter of the channel, the diameter of the membrane line, and the printing speed are set through the computer of the printer. After starting the printing, push the plunger of the syringe so that

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
Granularityaaaaaaaaaa
Thicknessaaaaaaaaaa
Apertureaaaaaaaaaa
Login to view more

Abstract

The invention relates to a process method for preparing a lithium battery diaphragm by using a 3D printing technology. The method comprises the following steps: A) uniformly mixing a diaphragm base material, an ultrafine ceramic powder and one of PVDF and PMMA in a blender mixer according to a required ratio, transferring into a grinding machine, and grinding to obtain a mixed material with required granularity; B) transferring the obtained mixed material into a heater with a stirring function, heating to melt the material, adding an organic solvent to adjust viscosity of the material, and stirring for 2-5 hours; and C) transferring the molten material into a material injector of a 3D printer, pushing a piston of the injector to enable the material to be sprayed on a substrate in a certainshape and thickness through a spray head of the 3D printer, peeling off the material from the substrate after complete cooling, curing and molding, and rolling to obtain the multifunctional compositediaphragm embedded with the ultrafine nano ceramic powder. The method has the beneficial effect that the thickness-controllable multifunctional composite diaphragm embedded with the ultrafine nano ceramic powder is obtained by applying the 3D printing technology.

Description

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Owner ZHEJIANG KEATON NEW MATERIAL TECH CO LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products