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4 results about "Hydroxyl radical" patented technology

The hydroxyl radical, •OH, is the neutral form of the hydroxide ion (OH⁻). Hydroxyl radicals are highly reactive (easily becoming hydroxyl groups) and consequently short-lived; however, they form an important part of radical chemistry. Most notably hydroxyl radicals are produced from the decomposition of hydroperoxides (ROOH) or, in atmospheric chemistry, by the reaction of excited atomic oxygen with water. It is also an important radical formed in radiation chemistry, since it leads to the formation of hydrogen peroxide and oxygen, which can enhance corrosion and SCC in coolant systems subjected to radioactive environments. Hydroxyl radicals are also produced during UV-light dissociation of H₂O₂ (suggested in 1879) and likely in Fenton chemistry, where trace amounts of reduced transition metals catalyze peroxide-mediated oxidations of organic compounds.

Visible-light-driven photocatalyst for degrading dye in wastewater, and preparation and application thereof

The invention relates to the field of photocatalysis, and particularly relates to a visible-light-driven photocatalyst for degrading dye in wastewater, and preparation and application thereof. The visible-light-driven photocatalyst for degrading dye in wastewater is characterized in that mesoporous silicon dioxide of which the framework contains Ti atoms is used as a carrier, the mesoporous silicon dioxide carrier carries graphitic carbon nitride, and bivalent Cu ions are doped on the graphitic carbon nitride, wherein the graphitic carbon nitride with the doped cupric ions serves as a main catalyst, and the element Ti serves as a cocatalyst. The Ti atoms contained in the framework of the mesoporous silicon dioxide directly react with H2O2 in a photo-Fenton-like system to produce hydroxyl free radicals, thereby obviously improving the photo-Fenton-like reaction activity. The photocatalyst provided by the invention catalyzes degradation of methyl orange and/or rhodamine B in wastewater, and degradation can be performed at room temperature under the irradiation of visible light, thereby enabling the photocatalyst to have the advantages of mild reaction conditions, low cost and easy implementation; and the photocatalyst can be easily regenerated, and still has excellent photocatalytic performance after being regenerated many times.
Owner:BINZHOU UNIV

Hydrogen-peroxide high-efficiency utilization method and apparatus for desulphurization and denitration of low-temperature flue gas

The invention provides a hydrogen-peroxide high-efficiency utilization method and apparatus for desulphurization and denitration of low-temperature flue gas. According to the method, hydrogen peroxide is fed in the form of gas in the process of desulphurization and denitration of low-temperature flue gas via hydrogen peroxide. The apparatus comprises a hydrogen peroxide storage tank, a feed pump, a flue and an absorbing tower. The apparatus is characterized in that hydrogen peroxide is converted to a gaseous state after treatment by a device for feeding liquid hydrogen peroxide after direct heating and vaporization of liquid hydrogen peroxide, or a device for feeding hydrogen peroxide after bubbling of hot carrying gas in hydrogen peroxide, or a device for feeding hydrogen peroxide carried by hot carrying gas or a device for feeding atomized hydrogen peroxide carried by hot carrying gas; the gaseous hydrogen peroxide then enters the flue; and the gaseous hydrogen peroxide and hydroxyl radicals therein are used for desulphurization and denitration reactions. The method and apparatus provided by the invention changes a conventional liquid-gas mixed reaction into a gas-gas mixed reaction. Compared with liquid hydrogen peroxide, more hydroxyl radicals can be produced through decomposition in the process of vaporization of hydrogen peroxide, so the utilization rate of hydrogen peroxide and the removal rate of NOx are improved, and the usage amount of hydrogen peroxide is reduced.
Owner:UNIV OF JINAN
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