Hydrogen-peroxide high-efficiency utilization method and apparatus for desulphurization and denitration of low-temperature flue gas

一种脱硫脱硝、低温烟气的技术,应用在分离方法、化学仪器和方法、空气质量改善等方向,能够解决双氧水与烟气混合不均匀、双氧水利用率低、脱除率低等问题,达到有益效果显著、适于应用推广、提高利用率的效果

Inactive Publication Date: 2017-06-16
UNIV OF JINAN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In this method, hydrogen peroxide is sprayed into the catalyst in liquid form, and a large amount of liquid hydrogen peroxide injected is mixed unevenly with the flue gas, and the utilization rate of hydrogen peroxide is low, which leads to NO in the flue gas x Low removal rate

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Such as figure 1 As shown, a schematic structural view of the first embodiment of the present invention is provided, which is composed of a hydrogen peroxide storage tank 1, a slurry pump 2, a vaporizer 3, a flue 4, and an absorption tower 5. In the shown hydrogen peroxide storage tank 1 Liquid hydrogen peroxide is stored, and the feed pump 2 pumps the hydrogen peroxide in the hydrogen peroxide storage tank 1 into the vaporizer 3 . The liquid hydrogen peroxide is vaporized in the vaporizer 3 and converted into gaseous hydrogen peroxide. The vaporization temperature of the vaporizer 3 is 60-130° C., and the vaporizer 3 forms a feeding device for directly heating and vaporizing the liquid hydrogen peroxide. The vaporized hydrogen peroxide is passed into the flue 4, and the gaseous hydrogen peroxide contains more hydroxyl radicals, which enter the airway to participate in the denitrification reaction, which can significantly increase the NO x , SO 2 The removal rate, b...

Embodiment 2

[0030] Such as figure 2 As shown, the structural representation of the second embodiment of the present invention is provided, which consists of a hydrogen peroxide storage tank 1, a feed pump 2, a bubbling chamber 9, a carrier gas tank 6, an air intake pump 7, a preheater 8, a drum The bubble chamber 9, the flue 4 and the absorption tower 5 are composed, and the carrier gas tank 6, the intake pump 7, the preheater 8 and the bubble chamber 9 form a hot carrier gas bubbling feeding device in hydrogen peroxide. The feed pump 2 pumps the liquid hydrogen peroxide in the hydrogen peroxide storage tank 1 into the bubbling chamber 9, the carrier gas stored in the carrier gas tank 6 is air or an inert gas, and the intake pump 7 pumps the carrier gas in the carrier gas tank 6 to Heating is carried out in the preheater 8 , the heating temperature is 80-150° C., and the heated carrier gas is passed into the bubbling chamber 9 . After the carrier gas enters the bubbling chamber 9, it ca...

Embodiment 3

[0032] Such as image 3As shown, the structural representation of the third embodiment of the present invention is provided. Compared with Embodiment 2, the present embodiment adopts a carrier gas tank 6, an intake pump 7, a preheater 8, a vaporizer 3 and a mixing chamber. The hot carrier gas carrying hydrogen peroxide steam feeding device composed of 10 is used to replace the hot carrier gas bubbling feeding device in hydrogen peroxide in Example 2, except that the rest of the structure is the same. In this embodiment, the feed pump 2 pumps the liquid hydrogen peroxide in the hydrogen peroxide storage tank 1 into the vaporizer 3 to be vaporized to generate gaseous hydrogen peroxide, and the gaseous hydrogen peroxide is passed into the mixing chamber 10 . The intake pump 7 pumps the carrier gas in the carrier gas tank 6 into the preheater 8 for heating, and the heated carrier gas passes into the mixing chamber 10 and enters the flue 4 with gaseous hydrogen peroxide. Gaseous h...

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PUM

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Abstract

The invention provides a hydrogen-peroxide high-efficiency utilization method and apparatus for desulphurization and denitration of low-temperature flue gas. According to the method, hydrogen peroxide is fed in the form of gas in the process of desulphurization and denitration of low-temperature flue gas via hydrogen peroxide. The apparatus comprises a hydrogen peroxide storage tank, a feed pump, a flue and an absorbing tower. The apparatus is characterized in that hydrogen peroxide is converted to a gaseous state after treatment by a device for feeding liquid hydrogen peroxide after direct heating and vaporization of liquid hydrogen peroxide, or a device for feeding hydrogen peroxide after bubbling of hot carrying gas in hydrogen peroxide, or a device for feeding hydrogen peroxide carried by hot carrying gas or a device for feeding atomized hydrogen peroxide carried by hot carrying gas; the gaseous hydrogen peroxide then enters the flue; and the gaseous hydrogen peroxide and hydroxyl radicals therein are used for desulphurization and denitration reactions. The method and apparatus provided by the invention changes a conventional liquid-gas mixed reaction into a gas-gas mixed reaction. Compared with liquid hydrogen peroxide, more hydroxyl radicals can be produced through decomposition in the process of vaporization of hydrogen peroxide, so the utilization rate of hydrogen peroxide and the removal rate of NOx are improved, and the usage amount of hydrogen peroxide is reduced.

Description

technical field [0001] The present invention relates to a high-efficiency hydrogen peroxide utilization method and device for desulfurization and denitrification of low-temperature flue gas, more specifically, to a hydrogen peroxide that uses gasified hydrogen peroxide to contain more hydroxyl radicals to achieve desulfurization and denitrification of flue gas Efficient utilization method and device. Background technique [0002] In recent years, severe smog has frequently occurred in large areas of my country, which has seriously affected economic and social development and the lives and health of the people. The reason is that the nitrogen oxides emitted by coal-fired coal from power plants, coking plants, sintering machines, kilns and various small and medium-sized boilers is one of the important reasons for the formation of haze weather. Therefore, the control and elimination of nitrogen oxides and sulfur oxides Emissions are an urgent real need. [0003] Currently, we...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/76B01D53/60
CPCB01D53/60B01D53/76B01D2251/106Y02A50/20
Inventor 张昭良蔡连国李壮壮辛颖李倩
Owner UNIV OF JINAN
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