Surface-treated steel plate, fuel pipe, cell can

一种表面处理钢板、电池壳的技术,应用在电池组零部件、电池盒/外套、电池箱/套材料等方向,能够解决不具有耐腐蚀性、针孔点蚀、环境安全性不理想等问题

Active Publication Date: 2014-03-19
TOYO KOHAN CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, since the Sn-Pb alloy has no corrosion resistance to water, and the potential of the Sn-Pb alloy is higher than that of Fe, the following problems occur: pinholes (Japanese: ピンホール) are generated during hot-dip plating, Under the action of corrosive substances such as moisture inevitably contained in gasoline fuel, pitting corrosion occurs due to the pinholes
[0006] However, as a result of studies by the present inventors, it has been found that the effect of suppressing pitting corrosion of the plated steel sheet disclosed in Patent Document 1 is not necessarily sufficient.
In addition, in the above-mentioned Patent Document 1, since fluorine compound particles are used, it is not preferable from the viewpoint of environmental safety.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0057] As a base, a steel sheet obtained by annealing a cold-rolled sheet (0.25 mm in thickness) of low-carbon aluminum-killed steel having the chemical composition shown below was prepared.

[0058] C: 0.045% by weight, Mn: 0.23% by weight, Si: 0.02% by weight, P: 0.012% by weight, S: 0.009% by weight, Al: 0.063% by weight, N: 0.0036% by weight, remainder: Fe and unavoidable Impurities

[0059] Then, the prepared steel sheet was subjected to alkaline electrolytic degreasing and acid pickling by immersion in sulfuric acid, and then nickel plating was performed under the following conditions to form a nickel plating layer with a thickness of 0.5 μm.

[0060] Bath composition: nickel sulfate 250g / L, nickel chloride 45g / L, boric acid 30g / L

[0061] pH: 3~4.8

[0062] Bath temperature: 60°C

[0063] Current density: 10A / dm 2

[0064] Next, heat-treat the steel plate with the nickel coating for two hours at a temperature of 650°C and a non-oxidizing atmosphere (vacuum annealin...

Embodiment 2

[0066] A surface-treated steel sheet was produced in the same manner as in Example 1 except that the heat treatment time was changed to 4 hours and evaluated in the same manner. The results are shown in Table 1.

Embodiment 3

[0068] A surface-treated steel sheet was produced in the same manner as in Example 2 except that the thickness of the nickel plating layer was 1 μm, and was evaluated in the same manner. The results are shown in Table 1.

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PUM

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Abstract

Provided is a surface-treated steel plate obtained by forming an iron-nickel alloy layer on the topmost surface, the surface-treated steel plate being characterized in that the Fe / Ni value obtained by Auger electron spectroscopy on the surface of the iron / nickel alloy layer is in the range of 0.3-2.0. In accordance with the present invention, there is provided a surface-treated steel plate having excellent corrosion resistance and in which the occurrence of pitting is effectively reduced when the surface-treated steel plate is exposed to various fuels such as automotive fuel oil.

Description

technical field [0001] The invention relates to a surface-treated steel plate, and a fuel pipe and a battery case made by using the surface-treated steel plate. Background technique [0002] Conventionally, as fuel pipe materials for automobiles and the like, Sn—Pb alloy-plated steel sheets, nickel-plated and Sn—Pb alloy-plated multilayer plated steel sheets have been mainly used. [0003] However, since the Sn-Pb alloy has no corrosion resistance to water, and the potential of the Sn-Pb alloy is higher than that of Fe, the following problems occur: pinholes (Japanese: ピンホール) are generated during hot-dip plating, Pitting corrosion occurs due to the pinholes under the action of corrosive substances such as water inevitably contained in gasoline fuel. [0004] On the other hand, for example, Patent Document 1 discloses a plated steel sheet obtained by electroplating on the surface of the steel sheet to form a composite coating in which fluorine compound particles are disperse...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C10/28B60K15/04C25D5/50F16L9/02F16L58/08H01M2/02H01M50/119H01M50/124H01M50/145
CPCY02E60/12F16L58/08C23C30/00C23C26/00C23C10/30H01M2/0292C25D5/50H01M2/0262C25D3/12F16L9/165F16L9/02H01M50/124H01M50/1245H01M50/145H01M50/119Y02E60/10
Inventor 友森龙夫吉冈兴
Owner TOYO KOHAN CO LTD
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