The present invention discloses a corrosion-resistant and aging-resistant building brick, which comprises the following raw materials in weight part: 20-30 parts of cement, 5-15 parts of meerschaum, 5-15 parts of fly ash, 1-4 parts of magnesium oxide, 5-12 parts of calcium hydrate, 1-6 parts of barite, 15-25 parts of attapulgite, 1-4 parts of wollastonite, 5-12 parts of construction wastes, 5-12 parts of modified montmorillonite, 1-2 parts of cyclodextrin, 0.2-0.8 part of ethylene-vinyl acetate copolymer, and 0.1-0.5 part of polysiloxanes powder. The preparation process of the modified montmorillonite comprises the steps of adding montmorillonite powders and sodium dihydrogen phosphate into an oxalic acid solution, stirring the solution, standing the solution, extracting an upper layer of suspending liquid, adding sodium hydroxide into the suspending liquid, stirring, adding oxalic acid, stirring, adding potassium dihydrogen phosphate, stirring, adding ethylene diamine tetraacetic acid, stirring, centrifuging, drying, crushing, then adding a silane coupling agent and water to adjust the pH value of the system, stirring, filtering, washing, adding a glutaraldehyde aqueous solution, stirring, filtering, and drying to obtain the modified montmorillonite.