ZrO2 ceramic surface electric conduction method

一种陶瓷表面、导电化的技术,应用在ZrO2陶瓷领域,能够解决增加能耗、提高烧结成本等问题

Active Publication Date: 2021-06-22
DONGGUAN XINBO STRUCTURAL CERAMICS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Excessive sintering temperature will increase energy consumption, thereby increasing sintering cost

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] a ZrO 2 A ceramic surface conduction method, the steps comprising:

[0022] (1) ZrO 2 A number of grooves with a certain shape are processed on the surface of the finished ceramic product;

[0023] (2) 35 parts of glaze powder, 20 parts of conductive ceramic powder and 45 parts of varnish are added to a ball mill jar and ball milled to obtain conductive paste, wherein the glaze powder includes 10 parts of Al 2 o 3 , 60 parts of SiO 2 , 8 parts of Na 2 O, the conductive ceramic powder is titanium nitride, and the varnish includes 59 parts of acrylic resin, 1 part of 1-hydroxycyclohexyl phenyl ketone, and 40 parts of xylene;

[0024] (3) Screen-print the conductive paste on ZrO 2 The groove of the finished ceramic product is dried in an oven at 90°C, and the silk screen printing process is carried out several times in a row to obtain a zirconia green body;

[0025] (4) The zirconia biscuit is placed in a vacuum atmosphere for sintering, the sintering temperature is...

Embodiment 2

[0027] a ZrO 2 A ceramic surface conduction method, the steps comprising:

[0028] (1) ZrO 2 A number of grooves with a certain shape are processed on the surface of the finished ceramic product;

[0029] (2) 40 parts of glaze powder, 15 parts of conductive ceramic powder and 45 parts of varnish are added to a ball mill jar and ball milled to obtain a conductive paste, wherein the glaze powder includes 8 parts of Al 2 o 3 , 50 parts of SiO 2 , 5 parts of Na 2 O, 5 parts of K 2 O, 5 parts of CaO, 5 parts of MgO, 3 parts of B 2 o 3 , 5 parts of ZnO, the conductive ceramic powder is zirconium carbide and titanium carbide, and the varnish includes 45 parts of acrylic resin, 3 parts of 1-hydroxycyclohexyl phenyl ketone, and 52 parts of xylene;

[0030] (3) Screen-print the conductive paste on ZrO 2 The groove of the ceramic product is dried in an oven at 120°C, and the silk screen printing process is carried out several times in a row to obtain a zirconia green body;

[0...

Embodiment 3

[0033] a ZrO 2 A ceramic surface conduction method, the steps comprising:

[0034] (1) ZrO 2 A number of grooves with a certain shape are processed on the surface of the finished ceramic product;

[0035] (2) 35 parts of glaze powder, 15 parts of conductive ceramic powder and 55 parts of varnish are added to a ball mill jar and ball milled to obtain conductive paste, wherein the glaze powder includes 5 parts of Al 2 o 3 , 40 parts of SiO 2 , 5 parts of Na 2 O, 8 parts of K 2 O, 8 parts of CaO, 5 parts of MgO, 3 parts of B 2 o 3 , 5 parts of ZnO, the conductive ceramic powder is boron carbide and titanium carbide, and the varnish includes 55.5 parts of acrylic resin, 0.5 parts of 1-hydroxycyclohexyl phenyl ketone, and 44 parts of xylene;

[0036](3) Screen-print the conductive paste on ZrO 2 The groove of the ceramic product is dried in an oven at 180°C, and the silk screen printing process is carried out several times in a row to obtain a zirconia green body;

[0037...

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Abstract

The invention provides a ZrO2 ceramic surface electric conduction method. The ZrO2 ceramic surface electric conduction method comprises the steps: (1) processing a plurality of grooves in the surface of a ZrO2 ceramic finished product; (2) ball-milling glaze powder, electrically conductive ceramic powder and gloss oil to obtain electric conductive slurry, wherein the glaze powder comprises Al2O3 and SiO2 and further comprises at least one of Na2O, K2O, CaO, MgO, B2O3 and ZnO; (3) carrying out silk-screen printing on the electric conductive slurry at the grooves of the ZrO2 ceramic finished product, and drying to obtain a zirconium oxide blank; and (4) carrying out sintering treatment on the zirconium oxide blank at the sintering temperature of 600 DEG C-1200 DEG C, and then carrying out polishing treatment to prepare the zirconium oxide ceramic with the electrically conductive surface. According to the method, the surface electrically conductive zirconium oxide ceramic is obtained at a relatively low sintering temperature and is resistant to acid and alkali corrosion; and moreover, good electrical conductivity is achieved, a metalized layer is firmly combined with a zirconia ceramic matrix, is not easy to crack and fall off, has a mirror surface effect and does not have macroscopic pores.

Description

technical field [0001] The present invention relates to ZrO 2 Ceramic technical field, specifically relate to a kind of ZrO 2 Method for making ceramic surface conductive. Background technique [0002] The ceramic surface conduction method is commonly used in the ceramic surface metallization method, and the ceramic metallization method is often used in the field of cermet sealing welding. Ceramics using ceramic metallization methods generally include alumina, boron nitride, silicon nitride, beryllium oxide, etc., and are mostly used in the manufacture of electronic devices such as electron tubes and vacuum switch tubes, so few scholars have paid attention to ZrO 2 Research on electrical conductivity of ceramic surfaces. [0003] The sintered metal method is often used to realize the metal conductivity of the ceramic surface. At present, the sintered metal method realizes the conductivity of the ceramic surface, and the sintering temperature is generally high. For exampl...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B41/87C04B41/90C03C8/00
CPCC04B41/009C04B41/5068C04B41/5057C04B41/52C04B41/87C04B41/90C03C8/00C04B35/48C04B41/5022C04B41/4857C04B41/4811C04B41/46C04B41/53C04B41/522C04B41/51
Inventor 袁云波刘锋吴国亮纪文义何岳平彭朝阳
Owner DONGGUAN XINBO STRUCTURAL CERAMICS CO LTD
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