Thin film all-solid-state battery

A solid-state thin-film battery, all-solid-state technology, applied in the field of electrochemistry

Pending Publication Date: 2022-05-24
FUDAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This technical improvement will have a better effect on regular, low-frequency pressure extrusion, but it still cannot fundamentally avoid the risk of short circuit

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] Example 1, cyclic type

[0032]The positive electrode slurry composed of lithium iron phosphate (LiFeP04), lithium germanium phosphorus sulfur solid electrolyte (Li10GeP2S12), carbon black conductive additive, and binder is coated on the electrode aluminum foil, dried and cut into a certain size of positive electrode diaphragm. The negative electrode slurry composed of graphite, lithium germanium phosphorus sulfur solid electrolyte (Li10GeP2S12) is coated on the electrode copper foil, dried and cut into a certain size of negative diaphragm. The positive and negative diaphragms are pressed in parallel by roller pressing method on the same side of the package film A. The marking method is used to remove part of the electrode material on the positive and negative diaphragms to form a dense grid. The width of the engraving line is 10~100μm. The lithium germanium phosphorus sulfur solid electrolyte and binder with organic solvent dispersion and mixing uniformly to form an electr...

Embodiment 2

[0033] Example 2, the rate type

[0034] Lithium cobalt oxide (LCO) and lithium phosphorus oxychloride solid electrolyte (LPON) are sintered and pressed into a film under high temperature and pressure and pressed on the electrode aluminum foil, and cut into a certain size of positive electrode diaphragm. The LiIn alloy is pressed onto the electrode copper foil and cut into a negative diaphragm of a certain size. The marking method is used to remove part of the electrode material on the positive and negative diaphragms to form a dense grid. The width of the notch line is 10-100 μm. The lithium phosphorus sulfur chloride solid electrolyte (Li5.5PS4.5C11.5) and the binder with an organic solvent dispersed and mixed evenly to form an electrolyte slurry, the above diaphragm award is coated with the positive and negative diaphragms and the gap between the two, and the positive and negative diaphragms are located on the same side and connected to the positive and negative diaphragms. The...

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PUM

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Abstract

The invention belongs to the technical field of electrochemistry, and particularly relates to an all-solid-state thin film battery. The all-solid-state thin film battery comprises a positive electrode layer, a negative electrode layer, an all-solid-state diaphragm layer and a flexible battery polar plate, wherein the positive electrode layer and the negative electrode layer are positioned in the same plane; a gap is formed between the positive electrode layer and the negative electrode layer; the positive electrode layer is formed by mixing a positive electrode active material, a solid electrolyte, a conductive additive and a binder according to a certain process; the negative electrode layer is formed by compounding graphite and a solid electrolyte, or consists of lithium metal and Li-Al, Li-In and Li-Sn alloy; the all-solid-state diaphragm layer is composed of a solid electrolyte with ultrahigh ionic conductivity; the flexible battery pole plates are respectively composed of ultrathin aluminum foils and copper foils; and the contact sides of the solid electrolyte layer and the positive electrode and the negative electrode adopt latticed extension structures. According to the invention, the risk of contact short circuit caused by the stacking structure of the positive electrode layer and the negative electrode layer is fundamentally avoided, and the ionic conductivity is greatly improved.

Description

Technical field [0001] The present invention belongs to the field of electrochemical technology, specifically relates to an all-solid-state thin-film battery. Background [0002] The all-solid-state thin-film battery replaces the traditional liquid electrolyte with a non-liquid electrolyte, which effectively avoids the leakage problem after the battery is damaged, and greatly broadens the effective working temperature range of the battery (the working range of the thin-film battery that usually uses the traditional liquid electrolyte is -10~60 °C, and the working range of the all-solid-state thin-film battery is extended to -30~150 °C). However, the current all-solid-state thin-film battery structure still has obvious safety risks. At present, the structure of traditional solid-state thin-film batteries is stacked and packaged by the positive electrode layer, diaphragm and negative electrode layer, and there are inevitably battery short-circuit failures and safety risks in high-p...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M10/0562H01M10/0525H01M10/058H01M4/139
CPCH01M10/0562H01M10/0525H01M10/058H01M4/139Y02P70/50
Inventor 梁世硕孙雪迎杨东胡建华
Owner FUDAN UNIV
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