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5 results about "Emulsion polymerization" patented technology

Emulsion polymerization is a type of radical polymerization that usually starts with an emulsion incorporating water, monomer, and surfactant. The most common type of emulsion polymerization is an oil-in-water emulsion, in which droplets of monomer (the oil) are emulsified (with surfactants) in a continuous phase of water. Water-soluble polymers, such as certain polyvinyl alcohols or hydroxyethyl celluloses, can also be used to act as emulsifiers/stabilizers. The name "emulsion polymerization" is a misnomer that arises from a historical misconception. Rather than occurring in emulsion droplets, polymerization takes place in the latex/colloid particles that form spontaneously in the first few minutes of the process. These latex particles are typically 100 nm in size, and are made of many individual polymer chains. The particles are prevented from coagulating with each other because each particle is surrounded by the surfactant ('soap'); the charge on the surfactant repels other particles electrostatically. When water-soluble polymers are used as stabilizers instead of soap, the repulsion between particles arises because these water-soluble polymers form a 'hairy layer' around a particle that repels other particles, because pushing particles together would involve compressing these chains.

Vinyl acetate-ethylene copolymer emulsion as electrostatic spinning adhesive and synthesis method thereof

ActiveCN102030857AGood adhesionImprove water resistanceMonocarboxylic acid ester polymer adhesivesLiquid surface applicatorsCross-linkPolymer science
The invention relates to a vinyl acetate-ethylene copolymer emulsion as an electrostatic spinning adhesive and a synthesis method thereof. Organic peroxides and zinc formaldehyde sulfate are taken as an initiator; vinyl acetate, ethylene, acrylic ester monomers and cross-linking monomer N-hydroxymethyl acrylamide are taken as comonomers; a nonionic emulsifier, and the synthetic emulsion and the protective colloid of an amphoteric emulsifier are matched to be taken as an emulsification system; and the copolymer emulsion is prepared through emulsion polymerization. Compared with the VAE (vinyl acetate-ethylene) emulsion prepared by the conventional preparation method, the product in the invention has the advantages of good water resistance, strong adhesion on low-surface-energy materials (polyethylene, polypropylene and the like), fine grain and the like. The vinyl acetate-ethylene copolymer emulsion is suitable for being as the adhesive to be applied to the field of the electrostatic spinning in textile industry and the fields of waterproofing and packaging.
Owner:CHINA PETROCHEMICAL CORP +1

Polymer composite material filled with industrial lignin as well as preparation method and application thereof

InactiveCN103351491AReduce shipping costsConducive to pollution controlPolymer scienceBlack liquor
The invention relates to a polymer composite material filled with industrial lignin as well as a preparation method and an application thereof. The polymer composite material is characterized in that substances forming the polymer composite material comprise rubber A, lignin and a third constituent, wherein the ratio of the oven dry parts by weight of the substances in the polymer composite material is 100:(10-300):(0-100); the rubber A is natural rubber or synthetic rubber produced by an emulsion polymerization method; the lignin is hydroxymethylation modified lignin produced from alkali lignin or black liquor; in a technical scheme in which the oven dry part by weight of the third constituent is greater than 0, the third constituent is one or the combination of more than two of other rubbers or plastics except the rubber A, or a plasticizer or operating oil, or argil, montmorillonoid, kaolin, kieselguhr or calcium carbonate, or papermaking pulp taking calcium carbonate as a main ingredient, or alkali-preparing waste, namely, white clay; the polymer composite material filled with the industrial lignin is of a block form or a powder form. According to the polymer composite material filled with the industrial lignin as well as the preparation method and the application thereof disclosed by the invention, the manufacturing cost is further decreased, and wastewater generated during the production process is further reduced.
Owner:张仲伦

Preparation method of waterborne modified acrylic resin type hyperdispersant

InactiveCN109181402ALower requirementsEasy to addInksAcrylic resinEmulsion polymerization
The invention discloses a preparation method of a waterborne modified acrylic resin type hyperdispersant. The preparation method comprises the following two steps: (1) synthesizing high molecular acrylic resin liquid through emulsion polymerization; and (2) adding a surfactant for compounding, so as to obtain a target product of the patent. The hyperdispersant is mainly applied to the fields of waterborne printing ink, waterborne coatings, waterborne ink and the like, belongs to the waterborne modified acrylic resin type hyperdispersant, can be used for dispersing various types of inorganic and organic pigments and effectively and stably dispersing pigments into water for a long time, and the dispersion particle size can reach a nanometer level, so that the powerful guarantee is provided for the coloring of the waterborne coatings, the waterborne printing ink and the waterborne ink, and the preparation method is a waterborne core technique for coatings and the printing ink; the invention relates to application testing of the product of the patent in the waterborne printing ink field in the application field, the printing ink will be developed in the truly environment-friendly VOC-free waterborne printing ink in future, and relatively environment-friendly packaging printing ink can meet the current market development trend.
Owner:广东天龙油墨有限公司
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