8 results about "Hydroxymethyl" patented technology

The invention discloses a (S)-1-(3-hydroxy-1-phenylpropyl)thiourea unilateral-modified Fe-Anderson-type heteropoly acid catalyst, a preparation method and an application thereof. According to the invention, ammonium molybdate and ferric sulfate are reacted under acidic condition to generate Fe-Anderson-type heteropoly acid parent; then heteropoly acid parent and tris(hydroxymethyl)aminomethane are reacted under backflow condition to obtain amino unilateral-modified Fe-Anderson-type polyoxometallate; (S)-1-(3-hydroxy-1-phenylpropyl)isorhodanate is synthesized; and finally, polyoxometallate and (S)-1-(3-hydroxy-1-phenylpropyl)isorhodanate are subjected to the reaction to obtain the target product. The preparation method has the advantages of simple process, high yield, mild reaction condition, and environment friendlessness; the catalyst can be used for a self-oxidation coupling reaction of a aryl methylamine compound, and has the advantages of environment pollution and high efficiency, high corresponding selectivity, and easy recovery and utilization.

The invention discloses environment-friendly impermeable composite bentonite, and belongs to the field of green chemistry and environmental protection. The composite bentonite is prepared from the following components in parts by mass: 1000-1200 parts of bentonite, 90-120 parts of sodium carbonate, 300-500 parts of a biodegradable polyester material, 50-100 parts of a cross-linking agent, 30-50 parts of a drying agent and 30-50 parts of a preservative; wherein the bentonite is granular bentonite; the biodegradable polyester material is one of poly (trimethylene carbonate), polycaprolactone andpolyvalerolactone; the cross-linking agent is N-hydroxymethyl acrylamide; the drying agent is at least one of bamboo charcoal and quartz sand; and the preservative is copper sulfate. By adding the biodegradable material and the cross-linking agent, the composite bentonite has good anti-seepage performance, can be biologically degraded, and has a wind indicator effect on the development of green chemistry.

The invention provides a weak gelling agent, a preparation method of the weak gelling agent, a cement paste suspension stabilizer and application of the cement paste suspension stabilizer. The weak gelling agent is obtained by initiating reaction of raw materials through an initiator, and the raw materials comprise sodium p-styrenesulfonate, itaconic acid, acrylic acid, N, N '-dimethylacrylamide, N-isopropylacrylamide or N-hydroxymethyl acrylamide and N-vinyl pyrrolidone. The weak gelling agent can relieve the phenomena of dilution and viscosity reduction generated in well cementation construction. The invention further provides a cement paste suspension stabilizer which comprises a tackifying and shear strength improving agent and the weak gelling agent. The invention further provides application of the cement paste suspension stabilizer in well cementation construction at the temperature of 200 DEG C or above. The cement paste suspension stabilizer can ensure the safety of cementing and well cementation construction under high-temperature and ultrahigh-temperature working conditions, and can improve the packing effect and well cementation quality of a deep stratum.

The invention relates to a synthesis method of 2-chloro-1-(2, 2-dimethyl-4H-benzo [1, 3] dioxin-6-yl) ethanone, the method comprises the following steps: (1) carrying out hydroxymethylation on methyl 4-hydroxybenzoate to obtain methyl 4-hydroxy-3-(hydroxymethyl) benzoate; (2) carrying out acetonylidene protection on ortho-dihydroxyl of the 4-hydroxy-3-(hydroxymethyl) methyl benzoate, so as to obtain 2, 2-dimethyl-4H-benzo [d] [1, 3] dioxin-6-carboxylic acid methyl ester; and (3) carrying out chloromethylation on the 2, 2-dimethyl-4H-benzo [d] [1, 3] dioxin-6-carboxylic acid methyl ester, so as to obtain the 2-chloro-1-(2, 2-dimethyl-4H-benzo [d] [1, 3] dioxin-6-yl) ethanone. The synthesis route does not involve a Friedel-Crafts acylation reaction, liquid bromine does not need to be used, the initial raw materials belong to bulk chemicals, the synthesis route is short, the synthesis route is safer and more environmentally friendly, and mass production of the 2-chloro-1-(2, 2-dimethyl-4H-benzo [1, 3] dioxin-6-yl) ethanone is easy to achieve.

The invention discloses a preparation method of a 4-hydroxymethyl coumarin compound, which comprises the following steps: (1) dispersing the 4-hydroxymethyl coumarin compound into an organic solvent, sequentially adding an oxidant and a pro-oxidant, heating and refluxing, cooling to room temperature after the reaction is finished, and filtering and washing to obtain an intermediate; (2) dispersing the intermediate into a water solution, adding a reducing agent, stirring at room temperature, and filtering after reaction to obtain a solid material and a water phase; and (3) dispersing the solid material in the step (2) into ethyl acetate, carrying out heating reflux, cooling to room temperature, aging for a period of time, filtering, and drying the solid material to obtain the 4-hydroxymethyl coumarin compound. The preparation method of the 4-hydroxymethyl coumarin compound adopting the structure is simple in technological process, low in cost, high in yield and suitable for industrial production.