The invention relates to a
silicon-
calcium-
barium-
magnesium desoxidant for
steelmaking and / or electroslag. The desoxidant is composed of the following chemical components in
mass percent: 20-50% of Si, 10-40% of Ca, 5-20% of Ba, 2-10% of Mg, 0-10% of RE, not larger than 0.030% of P, not larger than 0.040% of S, 0-2% of C and the balance of Fe. The preparation method comprises the following steps: firstly
smelting iron and
silicon in a
melting furnace to an intermediate
alloy, adding
barium,
calcium,
magnesium and / or
rare earth, melting and
casting to an
alloy block, and controlling the
specific gravity of the
silicon-
calcium-
barium-
magnesium desoxidant to 3-5 g / cm<3>. When in use, the silicon-calcium-barium-magnesium desoxidant is directly thrown into a steel furnace and / or an electroslag remelting crystallizer
slag bath, the
specific gravity of the desoxidant is increased, the
vapor pressure is reduced, the desoxidant is deposited at a
slag-steel interface to generate a CaO-BaO-SiO2 type
impurity, and the CaO-BaO-SiO2 type
impurity is larger in granule, lower in
melting point, easy to be captured by the
slag and easy to float to be removed, so that the cleanness of
molten steel is improved.