13 results about "Alkane" patented technology

The invention relates to super-hydrophobic film materials and provides a super-hydrophobic polypropylene film and a preparation method thereof. The super-hydrophobic polypropylene film is characterized in that an isotactic polypropylene-b-polyethylene glycol diblock copolymer serves as a surface modifier to construct a micronano composite structure on the surface of the polypropylene film. The preparation method includes steps: dissolving the isotactic polypropylene-b-polyethylene glycol diblock copolymer in an alkane solvent to obtain a polymer solution, coating to the surface of the polypropylene film by spin coating, putting the polypropylene film subjected to surface modification into a vacuum drying oven, and performing vacuum drying to obtain the super-hydrophobic polypropylene film. The super-hydrophobic polypropylene film and the preparation method thereof have advantages that simplicity in operation is achieved, complex chemical treatment is avoided, and expensive equipment is not needed; the preparation method is high in efficiency, feasible, environment friendly, low in cost and easy for industrialization; the prepared super-hydrophobic polypropylene film has excellent surface structural stability.

The invention provides a method for separating aromatic hydrocarbon from alkane by ionic liquid and membrane process coupling technology. The method includes that a hollow fiber membrane component is used as an extraction and separation device, ionic liquid is filled in pores of a hollow fiber membrane to form extract, aromatic hydrocarbon and alkane mixed liquor and a back-extraction phase respectively flow in a tube pass and a shell pass of the hollow fiber membrane in parallel or reversely, aromatic hydrocarbon is preferentially transferred to the back-extraction phase via the extract owing to the difference between the solubility of the aromatic hydrocarbon and the solubility of alkane in the ionic liquid, and the purpose of separating the aromatic hydrocarbon from the alkane is achieved. The method has the advantages of good selectivity, high mass transfer efficiency, low dosage of extracting solvent, simplicity in technological process, high stability and the like.

The invention discloses a room-temperature preparation method of a metal-organic framework material preferentially adsorbing ethane. The preparation method comprises the following steps: dispersing zinc oxide and copper tetrafluoroborate hexahydrate in water and ethanol; dispersing quinoline-5-carboxylic acid in N,N-dimethylformamide; mixing the former solutions, and stirring an obtained mixed solution at room temperature; filtering the stirred solution to obtain a solid product, purifying, drying and performing vacuum activation to obtain the metal-organic framework material preferentially adsorbing the ethane. By the room-temperature preparation method, the metal-organic framework material with good alkane selectivity is prepared at room temperature, the synthesizing energy consumption of the material is reduced, and the prepared material has good adsorptive separation performance for ethylene-ethane gas at normal temperature and pressure. The material can preferentially adsorb the ethane from the ethylene-ethane mixed gas; in addition, the material has good water vapor stability, and still has a good crystal structure after 40-day direct exposure to air.

The invention discloses a method for preparing deuterated aromatic compounds, in particular to a method for preparing complex deuterated aromatic compounds through a "one-pot method". The reduction reaction of palladium-catalyzed carbon-halogen bonds with the participation of deuterium anions, and bromide Participate in palladium-catalyzed coupling reactions, with halogenated aromatic hydrocarbons and brominated alkanes as starting materials, sodium deuteroformate as deuterated reagent, N,N-dimethylformamide as solvent, and metal palladium complex as catalyst , organic phosphine as a ligand, fully reacted at 30-100 degrees Celsius under the protection of an inert gas, and synthesized the target compound. Compared with the traditional deuterium method, this method has the following advantages: mild conditions, starting from simple and easy-to-obtain raw materials, and directly obtaining complex deuterated compounds in one step, avoiding the traditional multi-step synthesis method; avoiding the use of expensive The deuterated reagent is used as a solvent, which reduces the production cost; the deuterated rate of the target product deuterated aromatic compound reaches more than 98%.

The invention provides a preparation method of aryl borate, which mainly comprises the following steps: in the presence of a water-soluble free radical initiator, reacting by using water as a solventand aryl sulfonyl chloride and bis(pinacolato)borate as raw materials, extracting the reaction product by using an organic solvent after the reaction is completed, collecting the extract an organic phase, and carrying out reduced pressure distillation to obtain the product aryl borate. By using the water-soluble free radical initiator, water can be used as a reaction solvent; compared with the prior art that acetonitrile, halogenated alkane, ethyl acetate and other organic solvents are used, water is used as a solvent, environmental pollution is reduced, toxicity is reduced, and raw material sources are more economical; in addition, the method has the advantages of mild reaction, simple post-treatment, high yield, high purity and the like, and is very suitable for industrial production.