The invention discloses a method for preparing pure-phase monodisperse ZnS nanocrystalline by using
diethylene glycol serving as a
solvent. The method comprises steps of dissolving Zn (NO3)2.6H2O in the
diethylene glycol, regarding the Zn (NO3)2.6H2O which is dissolved in the
diethylene glycol as a
zinc source precursor solution, dissolving thiacetamide and
Polyvinylpyrrolidone (PVP) in the diethylene glycol, regarding the thiacetamide and the PVP which are dissolved in the diethylene glycol as a sulphur source precursor solution, pouring the sulphur source precursor solution into a flask with three necks which is provided with a condenser tube, feeding a
nitrogen flow, heating, injecting the
zinc source precursor solution of which the mol ratio of Zn and S is 1:1, conducting
reflux for 10 minutes at the temperature from 180 DEG C to 200 DEG C, cooling to the
room temperature by using water, cleaning centrifugally by using absolute ethyl
alcohol, dispersing
zinc oxide nanocrystalline in
alcohol and sealing and storing the zinc
oxide nanocrystalline. The zinc blende ZnS nanocrystalline which does not have any impure phases and is good in dispersibility is synthesized, the process is free from
pollution, the device is simple, the preparation cost is low and the scale industrial production can be applied.