The invention provides a preparation method for heptatridecafluorooctylpropyl polyhedral oligomeric
silsesquioxane and functionalized derivates thereof. The preparation method comprises the steps as follows: adding tridecafluorooctylpropyl trimethoxy
silane into an
organic solvent, adding de-ionized water and NaOH, heating, stirring, reacting under
reflux condition, washing by a washing
solvent, and
drying to obtain trisilanol
sodium salt of heptatridecafluorooctylpropyl polyhedral oligomeric
silsesquioxane; and adding trisilanol
sodium salt into an organic
reagent, dropwise adding
hydrochloric acid,
triethylamine and a
silane coupling agent, stirring a mixture at normal temperature for reaction, removing generated deposit, carrying out rotary
evaporation, removing the
solvent, obtaining white crystals, dissolving the crystals in
methanol, filtering for collecting insoluble parts, and carrying out
vacuum drying to obtain a T8-type monofunctional tridecafluorooctylpropyl POSS (polyhedral oligomeric
silsesquioxane)
monomer. The preparation method can obtain long
branch chain type active
fluorine-containing POSS, is simple and easy in process, low in cost, high in yield and higher in product purity, and is suitable for large-scale industrial production.