Flat ceramic membrane formulation carrying nano copper oxide and preparation method thereof

一种纳米氧化铜、陶瓷膜的技术,应用在无机陶瓷膜领域,能够解决原料碳化硅成本高、不具备广泛推广的条件、生产工艺成本大等问题,达到降低材料成本、生产工艺降低、产品质量保证的效果

Inactive Publication Date: 2018-09-14
CHANGZHOU SUNAN WATER ENVIRONMENT RES INST CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the use of aluminum oxide, aluminum hydroxide, silicon oxide, silicon carbide, silicon nitride, etc. as the ceramic membrane of the main material of the ceramic membrane support, the preparation process is relatively strict, and the raw material of the support needs to be prepared in a nitrogen environment. The cost of the production process is too high, and the cost of the raw material silicon carbide is relatively high, and it is not ready for widespread promotion in practical applications.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] The preparation of the flat ceramic membrane loaded with nano-copper oxide, the steps are as follows:

[0028] (1) Preparation of support body: 5% (wt), particle size is 2 μ m of kaolin, basic magnesium carbonate mixed with distilled water and then ground, then mixed with 85% (wt) of alumina and mullite material, After the mixture is completely dry, grind it lightly, pass it through a 1000 mesh sieve, then add 5% cornstarch, a pore-forming agent with a particle size of 2 μm, and 5% binder PVA-1750 solution and mix well, and finally form a support material ; Then, the supporting body ingredients were prepared by extrusion molding method to prepare the ceramic membrane supporting body; after the ceramic membrane supporting body was dried at 105 ° C, it was sintered in an electric furnace with a constant temperature of 1400 ° C for 2 hours, and then naturally cooled to room temperature; the main material of the supporting body The mass ratio of alumina and mullite is 1:2. ...

Embodiment 2

[0033]The preparation of the flat ceramic membrane loaded with nano-copper oxide, the steps are as follows:

[0034] (1) Preparation of the support body: 10% (wt), particle size of 1 μm of kaolin, basic magnesium carbonate and distilled water are mixed and ground, then mixed with 75% (wt) of alumina, dolomite materials, wait After the mixture is completely dry, grind it lightly, pass through an 800-mesh sieve after grinding, add 5% cornstarch, a pore-forming agent with a particle size of 11 μm, and 10% binder PVA-1750 solution and mix well, and finally form a support body ingredient; then Prepare the ceramic membrane support by extruding the ingredients of the support; dry the ceramic membrane support at 105°C, sinter in an electric furnace with a constant temperature of 1100°C for 3 hours, and then cool naturally to room temperature; the main material of the support is alumina The mass ratio to dolomite is 1:1.

[0035] After testing, the average pore diameter of the sintere...

Embodiment 3

[0039] The preparation of the flat ceramic membrane loaded with nano-copper oxide, the steps are as follows:

[0040] (1) Preparation of the support body: 20% (wt) of kaolin with a particle size of 3 μm, basic magnesium carbonate and distilled water are mixed and ground, and then mixed with 70% (wt) of alumina, dolomite and bauxite materials Evenly, after the mixture is completely dry, grind gently, pass through a 150-mesh sieve after grinding, then add 2% corn starch with a particle size of 80 μm, 8% binder PVA-1750 solution and mix well, and finally form a support Body ingredients; then the support body ingredients were prepared by extrusion molding method to balance the ceramic membrane support body; after the ceramic membrane support body was dried at 105°C, it was sintered in an electric furnace with a constant temperature of 1300°C for 1.5h, and then naturally cooled to room temperature; the support The mass ratio of main material dolomite and bauxite is 1:2.

[0041] A...

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Abstract

The invention a flat ceramic membrane formulation carrying nano copper oxide and a preparation method thereof. The flat ceramic membrane comprises a carrier and a separation membrane layer; the carrier incudes a main materials and auxiliary materials; the main materials of the carrier include one or more of alumina, mullite, dolomite, and bauxite; the auxiliary materials of the carrier include a sintering aid, a plasticizer, a pore-forming agent and a binder; the separation membrane layer is made with adhesive, nano copper oxide particles, a dispersing agent and a plasticizer. The flat ceramicmembrane carrying nano copper oxide has the advantages that the materials of the carrier are simple and easily accessible, the materials have antibacterial and catalytic functions, the pore size is flexibly controllable, and the materials have good features, such as excellent mechanical properties and low thermal expansion coefficient.

Description

technical field [0001] The invention relates to the field of inorganic ceramic membranes, in particular to a formulation of a flat ceramic membrane loaded with nano-copper oxide and a preparation method thereof. Background technique [0002] Inorganic ceramic membrane is an inorganic or polymer material with a special selective separation function. It can separate the fluid into two parts that are not connected, so that one or several substances can pass through and separate other substances. come out. Due to the technical advantages of high temperature resistance, acid and alkali resistance, good regeneration performance and long service life, inorganic ceramic membranes have been widely used in medicine, water treatment, chemical industry, electronics, food processing and other fields. [0003] In the prior art, aluminum oxide, aluminum hydroxide, silicon oxide, silicon carbide, and silicon nitride are usually used as the main material for preparing ceramic membrane suppo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/06C04B35/10C04B35/185C04B35/622C04B38/06C04B41/85
CPCC04B35/06C04B35/10C04B35/185C04B35/62218C04B38/0645C04B41/009C04B41/5075C04B41/85C04B2235/3206C04B2235/349C04B2235/96C04B41/4592C04B41/4539C04B41/4857C04B41/4803
Inventor 陆一冯苹沈敏蒋建锋
Owner CHANGZHOU SUNAN WATER ENVIRONMENT RES INST CO LTD
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