The invention provides an alloying component and a preparation method thereof. The alloying component takes high-entropy alloy as a matrix, and uses a carbon nano tube and rare earth nano particles asreinforcements, wherein the expression of the atomic percent of the high-entropy alloy is LxMyNz(Fe2/3Nb1/6Ta1/6)100-x-y-z; L comprises at least one of B, Mg, Al, Si, Sr, Ga, Ge, Sn, Sb and Bi; M comprises at least one of Cu, Co, Cr, Ni, Mn, Ag, Zn, V, Ti, Zr, Mo, Hf and W; N comprises at least one of Er, Y, Sc, Nd, Dy, Tm and Gd; and x is larger than or equal to 0 and smaller than 100, y is larger than or equal to 0 and smaller than 45, z is larger than or equal to 0 and smaller than 10, and the sum of x+y+z is larger than or equal to 0 and smaller than 100. The invention can provide the alloying component which refines grains to enables material compositions to be distributed more uniformly, and improves the grain boundary performance and the grain boundary corrosion resistance and thepreparation method of the alloying component.