The invention relates to a conductive composite
fiber and a preparation method thereof. The conductive composite
fiber comprises a
skin core structure including conductive particles and organic fibers, wherein the
mass percentage composition of the conductive particles is 0.5-10%, and the
mass percentage composition of the organic fibers is 90-99.5%. The preparation method comprises the following steps: (1) pre-treating the organic fibers in pretreatment liquid, and blowing; (2) soaking the fibers into water dispersion liquid of the conductive particles, ultrasonically assisting the conductive particles to outer
layers of the fibers in
ice water bath, soaking,
drying, and soaking, cleaning and
drying through
hydrochloric acid solution to obtain the conductive composite
fiber. According to the invention, the conductive composite fiber has the advantages of no
organic solvent in preparation, greenness and environmental friendliness, simple process, low cost, continuous large-scale production,
high conductivity of a product, difficulty in falling conductive components, durable conductive performance, soft hand feel and capability of being knitted; and the conductive composite fiber is used as an antistatic and electromagnetic shield material and an
energy storage electrode material.