26 results about "Phenol" patented technology

The invention refers to a kind of plant fibre liquefied and the manufacturing method, and the usage. It is made up by mixing 100 shares of polyatomic alcohol, 0-12 shares of phenol, 1-15 acid and heating them to 110-160deg.C, then adds in dried and crushed plant fibre material about 5-40 shares, reacts for 20-150 minutes, then cools them with ice. The product can be used to produce polyurethane foaming material. The plant fibre liquefied material not only can be lumber fibre material, but also can use other plant fibre material, it upgrades the use of material other than lumber resources, it reduces the consumption of chemical agent, the other hand, it can improve the flexibility of high polyurethane.

The invention discloses a method for removing phenol in phenol contained wastewater by using a hollow fiber membrane. The method comprises the following steps of: mixing a carrier and a diluent to prepare an extractant, wherein the adopted extractant carrier is tributyl phosphate, and the adopted diluent is coal oil or benzene; stirring and fully mixing the extractant and a stripping agent to prepare treating fluid; removing the phenol out of the phenol contained wastewater by using a hollow fiber membrane device; and after pretreating the hollow fiber membrane device, injecting the treating fluid into a tube pass of a membrane component, and injecting the phenol contained wastewater into a shell pass of the hollow fiber membrane component, wherein the wastewater can be treated through the same membrane component or a plurality of serial membrane components in a circular manner for many times; after the wastewater is subjected to two-stage treatment, the phenol concentration is less than 100mg/L; and after the wastewater is subjected to five-stage treatment, the phenol concentration is less than 5mg/L, the removal rate reaches up to 99.8 percent, and the wastewater reaches the national emission standard.

The invention provides a method for removing phenol-based substances from water by using an iron-sulfur supported multi-walled carbon nano-tube reinforced persulfate, and relates to a water treatment method. A purpose of the present invention is to solve the technical defects of high cost, poor removal effect and the like of the existing method for removing phenol-based substances from water. The method comprises: 1, mixing a persulfate and pre-treated water; 2, preparing iron-sulfur supported dual-phase composite multi-walled carbon nano-tubes; 3, pouring the iron-sulfur supported dual-phase composite multi-walled carbon nano-tubes; and 4, filtering the treated water so as to complete the method. With the method of the present invention, the removal rate of the phenol-based substances in the water can achieve 87-98%, and the residual phenol-based substance in the water can be removed.

The invention discloses a fiber-enhanced epoxy resin composition for quickly forming an automobile part and a preparation method thereof. The fiber-enhanced epoxy resin composition for quickly forming the automobile part comprises a component A and a component B. The component A comprises bisphenol A epoxy resin 127, a three-functional group glycidyl ether diluent XY636 and alicyclic epoxy resin TTA21; and the component B comprises diethylenetriamine DETA, isophorone diamine IPDA, methyl cyclohexanediamine HTDA, 1,3-bis(aminomethyl)-cyclohexan BAC and 2,4,6-tri(dimethylamino methyl) phenol DMP-30. The epoxy resin composition can be quickly cured and is suitable for a quick curing forming process of a fiber-enhanced composite material by means of a high pressure pouring process (HP-RTM) or a wet process molding process (WCM) and the like. The fiber-enhanced composite material prepared by the epoxy resin composition has excellent mechanical properties. The preparation method of the epoxy composition has the advantages of being simple in process and convenient to operate.

The invention discloses metal paint remover and a method for making the same. The metal paint remover comprises the following compositions and mixture ratio: 10 to 40 portions of methylene dichloride, 8 to 35 portions of dutch liquid, 10 to 25 portions of phenol, 5 to 15 portions of methanoic acid, 0.2 to 2 portions of octylphenol polyoxyethylene ether; the mixture ratio is in weight portion. The preparation method comprises the following steps that: firstly, methylene dichloride and dutch liquid are evenly mixed and stirred; secondly, phenol, methanoic acid and octylphenol polyoxyethylene ether are added in turn and evenly stirred to obtain a finished product. The prepared paint remover is suitable for removing various paints and has rapid paint removing speed, full removing, safe use, small toxicity, does not erode workpieces and hurt hands and can be used repeatedly and reduce environmental pollution.

The invention provides a method for detecting polar phenol type chlorinated/brominated disinfection by-products in water. The method comprises steps as follows: 1) standard working solutions of 13 polar phenol type chlorinated/brominated disinfection by-products required to be detected are prepared; 2) a to-be-detected water sample is acidized, salted out, subjected to continuous liquid-liquid extraction, separated, concentrated, filtered and pretreated in other modes; 3) analysis is performed by means of a UPLC/ESI-tqMS (ultra-high performance liquid chromatography/electrospray ionization-triple quadrupole mass spectrometer): mass spectrum parameters, liquid chromatography parameters and gradient elution process parameters of the UPLC/ESI-tqMS are established; 4) a calibration curve is drawn and the concentration is calculated after a chromatographic peak of a chromatogram sample is preliminarily determined to be identical to that of a known standard substance and the chromatogram sample and the known standard substance are the same substance. The detection method is high in sensitivity, precision and accuracy, can achieve the purpose of rapidly and efficiently measuring the 13 polar phenol type chlorinated/brominated disinfection by-products in the water, particularly can rapidly and efficiently detect a trace quantity of polar phenol type chlorinated/brominated disinfection by-products in the water, and has relatively high practical value.

The invention discloses a preparation method of composite acrylate emulsion. The preparation method comprises the following steps: adding polyoxyethylene octyl phenol ether-10, lauryl sodium sulfate and ammonium persulfate into an emulsifying kettle; adding deionized water, stirring and dissolving, sequentially adding butyl acrylate, methyl methacrylate and methacrylic acid into a pre-emulsifyingkettle, stirring and emulsifying to obtain pre-emulsion of the monomer; sequentially adding sodium bicarbonate and deionized water into a polymerizing pot, starting stirring to dissolve, and placing in a 50 DEG C water bath; filling in a constant pressure dropping funnel, weighing 5 parts of the prepared monomer pre-emulsion, adding into the polymerizing pot, adding a modified nano-hydroxyapatitematerial, weighing ammonium persulfate and dissolving into water, slowly adding into the polymerizing pot, regulating the temperature of the water bath to 82 DEG C, slowly raising the temperature to 82 DEG C, slowly dropwise adding the monomer pre-emulsion, washing the pre-emulsifying kettle, dropwise adding into the polymerizing pot, and regulating the pH value to 8 with ammonium hydroxide, thereby obtaining the composite nano acrylate emulsion.

The invention discloses an anticorrosive coating material for reinforced concrete, a preparation method and applications thereof, and belongs to the technical field of anticorrosive coating materials,wherein the anticorrosive coating material comprises, by mass, 8-30% of a phenol formaldehyde epoxy resin, 4-20 % of Ethylene glycol diglycidyl ether, 4-20 % of butanol, 1-5 % of a xylene-type unsaturated polyester resin, 7-32 % of a modified amine epoxy resin curing agent, 0.8-4 % of toluene-2,6-diisocyanate and/or modified toluene-2,6-diisocyanate, 5-25 % of mica flakes, and 2-3 % of ultrafinesilica. According to the present invention, the anticorrosive coating material has advantages of good sulfate and chlorine ion barrier performance, low film thickness, low surface energy, strong climate adaptability, good mechanical property, simple coating and the like, can meet the use requirements of high-sulfate and high-chlorine-ion composite salty soil environments, and can ensure the safetyand the long-term stability of the reinforced concrete infrastructure in the high-sulfate and high-chlorine-ion composite salty soil environment.

The invention discloses an avermectin.triazophos emulsifiable concentrate, which comprises the components of, by mass: 0.1% to 0.3% of avermectin, 18.7% to 20.9% of triazophos, 2% to 6% of calcium dodecylbenzene sulfonate, 4% to 8% of styryl phenol polyoxyethylene ether, and 65% to 75% of xylene. Effective components of the product provided by the invention are avermectin and triazophos. Avermectin, triazophos and filing materials are prepared into an avermectin.triazophos complex-formulated pesticide according to certain proportions. With the pesticide, drug resistance of the crops is delayed, pest controlling effect of the pesticide is improved, merits of various medicaments are represented, cost is reduced, labor is substantially saved, and economic benefits are improved.

The invention relates to the field of synthetic fibers for biological carriers and particularly relates to a preparation method of a polyester fiber with a rough surface. The polyester fiber comprises swelling agent master batches. The method is characterized by comprising the following steps of (1) drying fine particles of any one of sodium carbonate and sodium ortho phenyl phenol; (2) grinding the dried fine particles and processing to prepare the swelling agent master batches; (3) blending 5-20wt% of prepared swelling agent master batches and a polyester chip; (4) preparing an extruded fiber; and (5) hydrolyzing the prepared extruded fiber under the action of a cation surfactant at a high temperature of 90-100 DEG C and obtaining the polyester fiber with the rough surface. Compared with the prior art, a microbial material can be quickly fixed, and the polyester fiber has better biocompatibility; the removal effect of a biological membrane on the carrier surface on ammonia nitrogen in activated sludge is superior to that of an ordinary high polymer material; the polyester fiber with the rough surface is beneficial to promotion of growth of microorganisms in the activated sludge and improvement of the ammonia nitrogen removal rate.

The invention discloses a preparation method and application of an efficient agricultural water suspension and dispersion agent. The efficient agricultural water suspension and dispersion agent is prepared from the following components in percentage by weight: 90 to 10 weight percent of a substance A and 10 to 90 weight percent of a substance B, wherein the substance A is a water-soluble macromolecular polycarboxylate compounded with a comb type structure, which is formed by copolymerizing saturated carboxylic acid, unsaturated carboxylic acid and hydroxyl-containing fatty alcohol or phenol polyoxyethylene polypropylene oxide ether ester compound and a third functional monomer under the action of an initiator through solution copolymerization and alkali neutralization; the substance B comprises modified aryl phenol polyoxyethylene ether sulfonate, modified aryl phenol polyoxyethylene ether phosphate or modified aryl phenol polyoxyethylene ether carboxylate. The dispersant disclosed bythe invention is applicable to high-content, especially ether urea type and triazole type insecticidal bactericide pesticide water suspension agents, and provides good wetting and dispersion effects.The preparation method has the advantages of low production cost, practical and feasible technology, environment protection and no pollution and good application performance.

The invention discloses a modification treatment method for coal ash for concrete. The modification treatment method comprises the steps: adding coal ash into a ball mill for grinding, and carrying out sieving to obtain fine powder of the coal ash; then, adding a sodium phosphate solution to soak the fine powder, carrying out cleaning, and airing the fine powder of the coal ash; and finally, adding the aired fine powder of the coal ash into a mixer, carrying out heating, adding a mixed modifier composed of maleic rosin-octyl phenol polyoxyethylene ether diester carboxylate sodium and fatty alcohol polyoxyethylene ether methylsilane under high-speed stirring, and carrying out stirring, discharging and airing to finish the modification of the coal ash. The coal ash obtained by modification ahs the advantages such as improved dispersibility, good stability, remarkably-reduced water absorption rate, improved early strength, good compatibility with a concrete base material and good stability. If the coal ash modified by using the method is applied to concrete, the compressive strength, splitting tensile strength and impermeability of the concrete are remarkably improved.

The invention provides a TiO2 single-crystal hollow square nanocone material and a preparation method and application thereof. The preparation method includes: mixing 1, 6-hexamethylene diamine and cyclohexane, and then adding Ti(OC4H9)4; adding deionized water, and stirring and mixing to obtain suspension; sealing the obtained suspension, performing heating reaction, cooling, centrifuging, precipitating and washing, and drying to obtain the TiO2 single-crystal hollow square nanocone material. Compared with the prior art, the preparation method has the advantages that the anatase TiO2 single-crystal hollow square nanocone material prepared by the method has a large amount of exposed {101} faces and large specific surface area; the TiO2 single-crystal hollow square nanocone material has excellent photocatalytic activity on organic dye rhodamine B, methyl orange and colorless organic small-molecular phenol and is high in degrading efficiency, good in stability, environmentally friendly, simple in preparation process and low in cost.

The invention provides a preparation method for rosolic acid, wherein the preparation method comprises the following specific preparation steps: (1) heating phenol to melt into a liquid, then adding an aluminum trichloride powder, intensely stirring to make the solid evenly dispersed in phenol, heating the system to 100 DEG C, then adding carbon tetrachloride, carrying out a reaction for 8 hours and then stopping heating; and (2) cooling to room temperature by allowing to stand, washing with water for three times, finally washing with diethyl ether to obtain a red solid product, collecting thesolid product, and drying at the temperature of 60 DEG C, to obtain the rosolic acid. The preparation method adopts aluminum trichloride as a catalyst and phenol and carbon tetrachloride as the raw materials to synthesize the rosolic acid, and has the advantages of high operability and short reaction time; the yield can be increased to 75% or more, and the product has high sensitivity and is suitable for needs of large-scale industrialized production.

A method for increasing the presentation of ETEC CS6 antigen on cell surface, comprising the step of contacting cells expressing said antigen with an aqueous solution comprising 0.6-2.2 percent phenol by weight, such that the presentation of said antigen is increased by at least 100%. A method for the manufacture of a killed whole cell vaccine for immunization against CS6-expressing ETEC. Cells and vaccines obtainable by the above methods.

The invention relates to a fructus schizandrae extract containing antiseptic disinfectant for a pure cotton fabric. The antiseptic disinfectant contains the following ingredients in parts by mass: 8-18 parts of fructus schizandrae extract, 8-18 parts of hydrogen peroxide, 0.8-1.6 parts of phenol, 0.1-0.3 part of emulsifier, 8-18 parts of vegetable flavoring essence, 1-1.88 parts of potassium permanganate, 0.2-0.3 part of formaldehyde and 24-58 parts of water. According to the fructus schizandrae extract containing antiseptic disinfectant for the pure cotton fabric, provided by the invention, the added purely-natural fructus schizandrae extract is environmentally friendly and can be used for protecting fibers of the pure cotton fabric from damage; and the antiseptic disinfectant has good detergency, is good in bactericidal and antibacterial effect, can be used for killing bacteria hidden in the fibers and enables the pure cotton fabric to have an antibacterial action.

The invention discloses a heat-conducting POM (polyformaldehyde) material and a preparation method thereof. The heat-conducting POM material is prepared from the following components in parts by weight: 60-75 parts of POM, 8-15 parts of silicon carbide, 6-10 parts of polyethylene glycol, 1-3 parts of melamine, 1-3 parts of di(dioctylpyrophosphato) oxyacetate titanate, 0.5-2 parts of 2,6-di-tert-butyl-4-methylphenol and 0-1 part of sodium carbonate. The preparation method comprises the following steps: fully mixing the raw materials, adding the mixture to a twin screw extruder, extruding and granulating so as to obtain the heat-conducting POM material. The heat-conducting POM material prepared by the method has good compatibility, mechanical property and heat-conducting property.

The invention discloses a preparation method of a hindered phenol antioxidant 1019. The method comprises the following steps: dissolving 3-(3, 5-dibutyl-4-hydroxyphenyl) propionyl chloride into an organic solvent; adding the solution obtained from the former step into a mixed solution prepared from propane diamine, inorganic base and water by an agitating manner; controlling the temperature of the reaction system under adding to 0 to 50 DEG C; further reacting at the temperature of 0 to 50 DEG C after adding until reaching the end of reaction; heating to reach the temperature of 50 to 80 DEG C after reaction; separating out a lower water phase; washing an organic phase at two to three times through water until the pH of the washing water is 6 to 7; cooling; crystallizing; filtering; drying to obtain the target product, namely, N, N'-bi-(3-(3,5-di-butyl-4-hydroxyphenyl) propionyl) propane diamine. Compared with the existing synthesis method, the preparation method has the advantages that the yield is high, conditions of reaction are mild, the operation is simple, the product is easily separated and purified, and the quality is high; the preparation method is suitable for industrial production.

The invention discloses an amino phosphate water-soluble corrosion inhibitor and a preparation method thereof. The corrosion inhibitor contains, by weight, 30-45 parts of amino phosphate mixed solutions, 4-6 parts of N-methyl thiourea, 5-10 parts of ethylene glycol monomethyl ether, 5-8 parts of formamide, 5-9 parts of p-hydroxybenzoic acid, 1-5 parts of nonylphenol polyoxyethylene ether, 1-2 parts of octyl phenol polyoxyethylene ether, 6-23.5 parts of water, 8-15 parts of vinyl ethylene glycol ether, 0.5-2.5 parts of3-methyl-2-pentene-4-alkynol and 2-6.5 parts of acetaldehyde methyl hexyl acetal. The amino phosphate corrosion inhibitor has good anti-corrosion effects on an oil and gas field collecting and conveying system with high CO2 (partial pressure of 0-5 MPa) and H2S coexistence (the partial pressure of 0-1 MPa).

The invention discloses a graphene adsorbent for crude oil desulfurization. The graphene adsorbent for the crude oil desulfurization is prepared from the following raw materials in parts by weight: 2.4 to 3.2 parts of diethanolamine, 10 to 18 parts of graphene, 1.5 to 2.5 of bismuth oxide, 2 to 4 parts of iron oxide, 2.2 to 3.6 parts of alumina, 0.6 to 1.5 parts of sodium nitrite, 4 to 8 parts ofacetaldehyde, 46 to 63 parts of ethylene glycol, 1.8 to 5 parts of polyacrylamide, 5 to 10 parts of strong alkali solution, 1.6 to 3 parts of surfactant, 2 to 3 parts of phenol and 6.5 to 9 parts of radix isatidis. The graphene adsorbent for the crude oil desulfurization has wide raw material sources, the specific surface area of the graphene is improved by supporting inorganic oxide on the graphene, the graphene is modified by using a strong alkali, sodium nitrite and a surfactant to improve the surface activity of the graphene, and the adsorption to sulfides in crude oil is improved by combining the graphene adsorbent with other components.

The invention provides an acrylic bonding agent and a preparation method thereof. The bonding agent is prepared from the following materials in parts by weight: 10 to 60 parts of phenol, 5 to 20 partsof glacial acetic acid and 1 to 30 parts of dichloromethane. After the acrylic bonding agent is used for bonding acrylic and images, the transparency is good; no bubble exists; image corrosion cannotoccur, so that the acrylic and the images can be perfectly bonded; the color change can be avoided for a long time; bubbles can not be generated; the problems of easy color change, poor transparency,bubble generation on the surface of the existing bonding agents in the market can be well solved.