39 results about "Phenols" patented technology

The invention refers to a kind of plant fibre liquefied and the manufacturing method, and the usage. It is made up by mixing 100 shares of polyatomic alcohol, 0-12 shares of phenol, 1-15 acid and heating them to 110-160deg.C, then adds in dried and crushed plant fibre material about 5-40 shares, reacts for 20-150 minutes, then cools them with ice. The product can be used to produce polyurethane foaming material. The plant fibre liquefied material not only can be lumber fibre material, but also can use other plant fibre material, it upgrades the use of material other than lumber resources, it reduces the consumption of chemical agent, the other hand, it can improve the flexibility of high polyurethane.

The invention discloses a phenol ortho-methylation catalyst and a preparation method thereof. The catalyst is an alkaline Fe/Mg compound oxide, wherein, the mol ratio of Fe to Mg is 1: (0.1-2). The preparation method comprises the following steps: mixing and dissolving soluble malysite and soluble magnesium salts into alcohols solvent according to a required proportion to prepare a solution A; adding polyethyleneglycol (PEG) into strong aqua ammonia to prepare a solution B; slowly mixing the solution A and the solution B in a cocurrent flow mode under the condition of normal temperature and ultrasound, and then going on with the ultrasound for 30 minutes; filtering, washing, drying and baking the obtained precipitation; porphyrizing the baked solid and repulverizing the solid into 10-20 mesh finely ground particles after tabletting; the finely ground particles are the catalyst. The catalyst has the advantages of high activity at low temperature, simple preparation, innocuity, good stability, high selectivity of ortho position, particularly high selectivity of orthocresol and few by-products.

Provided are a rubber composition for a tire cord topping, a breaker edge strip, a breaker cushion, or a strip adjacent to cords, which achieves a balanced improvement in handling stability, fuel economy, durability, ride quality, and adhesion; and pneumatic tires including the same. The rubber composition includes: an isoprene-based rubber; a phenol resin and/or an alkylphenol resin; and a partial condensate of HMMM and/or a partial condensate of HMMPME, wherein an amount of the isoprene-based rubber is 60% by mass or higher per 100% by mass of the rubber component; and a combined amount of the phenol resin and the alkylphenol resin is 2-3.9 parts by mass, a combined amount of the partial condensate of HMMM and the partial condensate of HMMPME is 0.5-5 parts by mass, and an amount of silica is at most 15 parts by mass, each per 100 parts by mass of the rubber component.

The invention discloses a method for removing phenol in phenol contained wastewater by using a hollow fiber membrane. The method comprises the following steps of: mixing a carrier and a diluent to prepare an extractant, wherein the adopted extractant carrier is tributyl phosphate, and the adopted diluent is coal oil or benzene; stirring and fully mixing the extractant and a stripping agent to prepare treating fluid; removing the phenol out of the phenol contained wastewater by using a hollow fiber membrane device; and after pretreating the hollow fiber membrane device, injecting the treating fluid into a tube pass of a membrane component, and injecting the phenol contained wastewater into a shell pass of the hollow fiber membrane component, wherein the wastewater can be treated through the same membrane component or a plurality of serial membrane components in a circular manner for many times; after the wastewater is subjected to two-stage treatment, the phenol concentration is less than 100mg/L; and after the wastewater is subjected to five-stage treatment, the phenol concentration is less than 5mg/L, the removal rate reaches up to 99.8 percent, and the wastewater reaches the national emission standard.

The invention provides a method for removing phenol-based substances from water by using an iron-sulfur supported multi-walled carbon nano-tube reinforced persulfate, and relates to a water treatment method. A purpose of the present invention is to solve the technical defects of high cost, poor removal effect and the like of the existing method for removing phenol-based substances from water. The method comprises: 1, mixing a persulfate and pre-treated water; 2, preparing iron-sulfur supported dual-phase composite multi-walled carbon nano-tubes; 3, pouring the iron-sulfur supported dual-phase composite multi-walled carbon nano-tubes; and 4, filtering the treated water so as to complete the method. With the method of the present invention, the removal rate of the phenol-based substances in the water can achieve 87-98%, and the residual phenol-based substance in the water can be removed.

The invention discloses a fiber-enhanced epoxy resin composition for quickly forming an automobile part and a preparation method thereof. The fiber-enhanced epoxy resin composition for quickly forming the automobile part comprises a component A and a component B. The component A comprises bisphenol A epoxy resin 127, a three-functional group glycidyl ether diluent XY636 and alicyclic epoxy resin TTA21; and the component B comprises diethylenetriamine DETA, isophorone diamine IPDA, methyl cyclohexanediamine HTDA, 1,3-bis(aminomethyl)-cyclohexan BAC and 2,4,6-tri(dimethylamino methyl) phenol DMP-30. The epoxy resin composition can be quickly cured and is suitable for a quick curing forming process of a fiber-enhanced composite material by means of a high pressure pouring process (HP-RTM) or a wet process molding process (WCM) and the like. The fiber-enhanced composite material prepared by the epoxy resin composition has excellent mechanical properties. The preparation method of the epoxy composition has the advantages of being simple in process and convenient to operate.

A modified dimethylnaphthalene formaldehyde resin is disclosed, which is excellent in heat resistance and useful for thermosetting resins which are used for an electrical insulating material, a resin for resist, a semiconductor sealing resin, an adhesive for printed wiring board, a matrix resin for electrical laminate or prepreg to be mounted in electrical instruments, electronic instruments, industrial instruments, etc., a buildup laminate material, a resin for fiber-reinforced plastic, a sealing resin for liquid crystal display panel, a paint, a variety of coating agents, an adhesive, a laminate for electrical or electronic parts, a molded article, a coating material, a sealing material and the like, the modified dimethylnaphthalene formaldehyde resin being obtained by modifying a polyfunctional dimethylnaphthalene formaldehyde resin having a constituent unit represented by the following general formula [1] in a molecule thereof with at least one member selected from the group consisting of a phenol represented by the following general formula [2], a naphthol represented by the following general formula [3] and a naphthol represented by the following general formula [4] (provided that at least any of the naphthol represented by the general formula [3] or the naphthol represented by the general formula [4] must be included).

The invention discloses metal paint remover and a method for making the same. The metal paint remover comprises the following compositions and mixture ratio: 10 to 40 portions of methylene dichloride, 8 to 35 portions of dutch liquid, 10 to 25 portions of phenol, 5 to 15 portions of methanoic acid, 0.2 to 2 portions of octylphenol polyoxyethylene ether; the mixture ratio is in weight portion. The preparation method comprises the following steps that: firstly, methylene dichloride and dutch liquid are evenly mixed and stirred; secondly, phenol, methanoic acid and octylphenol polyoxyethylene ether are added in turn and evenly stirred to obtain a finished product. The prepared paint remover is suitable for removing various paints and has rapid paint removing speed, full removing, safe use, small toxicity, does not erode workpieces and hurt hands and can be used repeatedly and reduce environmental pollution.

The invention provides a method for detecting polar phenol type chlorinated/brominated disinfection by-products in water. The method comprises steps as follows: 1) standard working solutions of 13 polar phenol type chlorinated/brominated disinfection by-products required to be detected are prepared; 2) a to-be-detected water sample is acidized, salted out, subjected to continuous liquid-liquid extraction, separated, concentrated, filtered and pretreated in other modes; 3) analysis is performed by means of a UPLC/ESI-tqMS (ultra-high performance liquid chromatography/electrospray ionization-triple quadrupole mass spectrometer): mass spectrum parameters, liquid chromatography parameters and gradient elution process parameters of the UPLC/ESI-tqMS are established; 4) a calibration curve is drawn and the concentration is calculated after a chromatographic peak of a chromatogram sample is preliminarily determined to be identical to that of a known standard substance and the chromatogram sample and the known standard substance are the same substance. The detection method is high in sensitivity, precision and accuracy, can achieve the purpose of rapidly and efficiently measuring the 13 polar phenol type chlorinated/brominated disinfection by-products in the water, particularly can rapidly and efficiently detect a trace quantity of polar phenol type chlorinated/brominated disinfection by-products in the water, and has relatively high practical value.

The invention discloses an extraction method of plant genome DNA rich in polysaccharides. The method comprises the following steps: grinding through liquid nitrogen; adding precooled CATB-free bufferand mercaptoethanol, and sufficiently and uniformly vibrating; laying the materials on ice, controlling the temperature to be 4 DEC C, performing centrifugation, and abandoning supernatant; washing according through PBS according to viscosity, adding an SDS solution and mercaptoethanol, and uniformly mixing; then performing water bath, and performing reversing and mixing during water bath; addingequivoluminal phenol and chloroform after the materials are cooled, and reversing and mixing; performing centrifugation, taking supernatant, adding RNase A, performing reversing and mixing, and layingthe materials at a room temperature; adding isopropanol, reversing and mixing, laying the materials at a room temperature or a low temperature, performing centrifugation, abandoning supernatant, washing through 75 percent ethanol, and adding an appropriate volume of sterile water for dissolving. The method has a better extraction effect on plant gene rich in polysaccharides, and compared with conventional methods, the method has the advantages that the gene integrity and subsequent purity are better.

The invention relates to a catalyst for synthesizing diphenyl carbonate in phenol oxidative carbonylation as well as a preparation method and an application method of the catalyst. The catalyst comprises carrier rod-shaped nanometer CeO3 and an active component Pd compound, wherein the Pd compound is based on Pd, the weight ratio of the Pd to the CeO2 is 0.1: (10:100). The catalyst is used for synthesizing the diphenyl carbonate in the phenol oxidative carbonylation, solving the separation problem of a homogeneous Pd catalyst and overcoming the shortcomings that a conventional heterogeneous catalyst system is low in reaction rate and long in reaction time, and the like; meanwhile, by using the catalyst, the using amount of additives is reduced in the phenol oxidative carbonylation, only one additive is used, and the defects such as large using amount of the additives, multiple varieties, high difficulty in aftertreatment and high cost of a conventional reaction system are overcome. In addition, according to the method, the catalyst has relatively high activity all the time in the reaction process and can be repeatedly used.

A process for producing a phosphonitrilic acid ester. The process comprises using a specific compound as a catalyst to react phosphonitrile dichloride with at least one member selected among phenol compounds and/or alcohol compounds in the presence of a reaction solvent. Alternatively, the process comprises reacting a liquid reaction mixture obtained in a first stage with at least one member selected among phenol compounds and/or alcohol compounds without isolating phosphonitrile dichloride from the mixture.

The invention discloses a preparation method of composite acrylate emulsion. The preparation method comprises the following steps: adding polyoxyethylene octyl phenol ether-10, lauryl sodium sulfate and ammonium persulfate into an emulsifying kettle; adding deionized water, stirring and dissolving, sequentially adding butyl acrylate, methyl methacrylate and methacrylic acid into a pre-emulsifyingkettle, stirring and emulsifying to obtain pre-emulsion of the monomer; sequentially adding sodium bicarbonate and deionized water into a polymerizing pot, starting stirring to dissolve, and placing in a 50 DEG C water bath; filling in a constant pressure dropping funnel, weighing 5 parts of the prepared monomer pre-emulsion, adding into the polymerizing pot, adding a modified nano-hydroxyapatitematerial, weighing ammonium persulfate and dissolving into water, slowly adding into the polymerizing pot, regulating the temperature of the water bath to 82 DEG C, slowly raising the temperature to 82 DEG C, slowly dropwise adding the monomer pre-emulsion, washing the pre-emulsifying kettle, dropwise adding into the polymerizing pot, and regulating the pH value to 8 with ammonium hydroxide, thereby obtaining the composite nano acrylate emulsion.

The invention discloses an anticorrosive coating material for reinforced concrete, a preparation method and applications thereof, and belongs to the technical field of anticorrosive coating materials,wherein the anticorrosive coating material comprises, by mass, 8-30% of a phenol formaldehyde epoxy resin, 4-20 % of Ethylene glycol diglycidyl ether, 4-20 % of butanol, 1-5 % of a xylene-type unsaturated polyester resin, 7-32 % of a modified amine epoxy resin curing agent, 0.8-4 % of toluene-2,6-diisocyanate and/or modified toluene-2,6-diisocyanate, 5-25 % of mica flakes, and 2-3 % of ultrafinesilica. According to the present invention, the anticorrosive coating material has advantages of good sulfate and chlorine ion barrier performance, low film thickness, low surface energy, strong climate adaptability, good mechanical property, simple coating and the like, can meet the use requirements of high-sulfate and high-chlorine-ion composite salty soil environments, and can ensure the safetyand the long-term stability of the reinforced concrete infrastructure in the high-sulfate and high-chlorine-ion composite salty soil environment.

The invention discloses an avermectin.triazophos emulsifiable concentrate, which comprises the components of, by mass: 0.1% to 0.3% of avermectin, 18.7% to 20.9% of triazophos, 2% to 6% of calcium dodecylbenzene sulfonate, 4% to 8% of styryl phenol polyoxyethylene ether, and 65% to 75% of xylene. Effective components of the product provided by the invention are avermectin and triazophos. Avermectin, triazophos and filing materials are prepared into an avermectin.triazophos complex-formulated pesticide according to certain proportions. With the pesticide, drug resistance of the crops is delayed, pest controlling effect of the pesticide is improved, merits of various medicaments are represented, cost is reduced, labor is substantially saved, and economic benefits are improved.

The invention discloses a preparation method of an L-carnitine amino acid deep eutectic solvent and application thereof in polyphenol extraction. The preparation process of the deep eutectic solvent includes: weighing a certain mass of L-carnitine and performing dissolving in water, also weighing another part of amino acid and performing dissolving in a solvent, conducting stirring dissolving, andtransferring the product into a dropping funnel, adding the amino acid solution into the L-carnitine aqueous solution dropwise under a stirring state, then performing stirring at 25-60DEG C for 12h,and conducting rotary evaporation to remove the solvent, thereby obtaining the L-carnitine amino acid deep eutectic solvent. According to the method, the influence of the deep eutectic solvent content, the extraction time and the extraction temperature on the extracted polyphenol content is explored, and an optimal extraction condition is determined. Researches show that: the L-carnitine amino acid deep eutectic solvent has extraction efficiency far higher than that of water, and is greener, more environmentally friendly, and free of pollution.

The invention relates to the field of synthetic fibers for biological carriers and particularly relates to a preparation method of a polyester fiber with a rough surface. The polyester fiber comprises swelling agent master batches. The method is characterized by comprising the following steps of (1) drying fine particles of any one of sodium carbonate and sodium ortho phenyl phenol; (2) grinding the dried fine particles and processing to prepare the swelling agent master batches; (3) blending 5-20wt% of prepared swelling agent master batches and a polyester chip; (4) preparing an extruded fiber; and (5) hydrolyzing the prepared extruded fiber under the action of a cation surfactant at a high temperature of 90-100 DEG C and obtaining the polyester fiber with the rough surface. Compared with the prior art, a microbial material can be quickly fixed, and the polyester fiber has better biocompatibility; the removal effect of a biological membrane on the carrier surface on ammonia nitrogen in activated sludge is superior to that of an ordinary high polymer material; the polyester fiber with the rough surface is beneficial to promotion of growth of microorganisms in the activated sludge and improvement of the ammonia nitrogen removal rate.

The invention discloses a preparation method and application of an efficient agricultural water suspension and dispersion agent. The efficient agricultural water suspension and dispersion agent is prepared from the following components in percentage by weight: 90 to 10 weight percent of a substance A and 10 to 90 weight percent of a substance B, wherein the substance A is a water-soluble macromolecular polycarboxylate compounded with a comb type structure, which is formed by copolymerizing saturated carboxylic acid, unsaturated carboxylic acid and hydroxyl-containing fatty alcohol or phenol polyoxyethylene polypropylene oxide ether ester compound and a third functional monomer under the action of an initiator through solution copolymerization and alkali neutralization; the substance B comprises modified aryl phenol polyoxyethylene ether sulfonate, modified aryl phenol polyoxyethylene ether phosphate or modified aryl phenol polyoxyethylene ether carboxylate. The dispersant disclosed bythe invention is applicable to high-content, especially ether urea type and triazole type insecticidal bactericide pesticide water suspension agents, and provides good wetting and dispersion effects.The preparation method has the advantages of low production cost, practical and feasible technology, environment protection and no pollution and good application performance.

The invention relates to a synthetic method of methylene ether urushiol hydroxamic acid derivatives with (histone deacetylase) HDAC inhibitory activity. Unsaturated urushiol is taken as a raw material, and oxidative polymerization of the urushiol is blocked through an etherification reaction; hydroxamic acid groups are introduced to tail parts of side chains of the urushiol thorugh a Diels-Alder reaction, a hydrolysis reactions, a hydroxylation reaction and the like; and in addition, different pharmacological groups such as nitro groups, hydroxyl groups and the like are introduced into benzene rings or alkyl chains, so that three methylene ether urushiol hydroxamic acid derivatives are synthesized. The three compounds can be well combined with active pockets of HDAC, can form stable hydrogen bonds with residual groups of the HDAC for interaction, and can be stably chelated with Zn<2+> at the bottom of the active pockets, so that good HDAC inhibitory activity is achieved. The median inhibitory concentrations (IC50) of the three compounds on HDAC 2 and HDAC 8 are equivalent to the IC50 value of an HDAC inhibitor SAHA approved by the Food and Drug Administration (FDA). The three compounds can be applied to clinical antitumor drugs and have extremely high additional values, and the synthetic method can be a novel technology for clinically developing novel phenol-based HDAC inhibitors.

The invention provides a TiO2 single-crystal hollow square nanocone material and a preparation method and application thereof. The preparation method includes: mixing 1, 6-hexamethylene diamine and cyclohexane, and then adding Ti(OC4H9)4; adding deionized water, and stirring and mixing to obtain suspension; sealing the obtained suspension, performing heating reaction, cooling, centrifuging, precipitating and washing, and drying to obtain the TiO2 single-crystal hollow square nanocone material. Compared with the prior art, the preparation method has the advantages that the anatase TiO2 single-crystal hollow square nanocone material prepared by the method has a large amount of exposed {101} faces and large specific surface area; the TiO2 single-crystal hollow square nanocone material has excellent photocatalytic activity on organic dye rhodamine B, methyl orange and colorless organic small-molecular phenol and is high in degrading efficiency, good in stability, environmentally friendly, simple in preparation process and low in cost.

The invention provides a preparation method for rosolic acid, wherein the preparation method comprises the following specific preparation steps: (1) heating phenol to melt into a liquid, then adding an aluminum trichloride powder, intensely stirring to make the solid evenly dispersed in phenol, heating the system to 100 DEG C, then adding carbon tetrachloride, carrying out a reaction for 8 hours and then stopping heating; and (2) cooling to room temperature by allowing to stand, washing with water for three times, finally washing with diethyl ether to obtain a red solid product, collecting thesolid product, and drying at the temperature of 60 DEG C, to obtain the rosolic acid. The preparation method adopts aluminum trichloride as a catalyst and phenol and carbon tetrachloride as the raw materials to synthesize the rosolic acid, and has the advantages of high operability and short reaction time; the yield can be increased to 75% or more, and the product has high sensitivity and is suitable for needs of large-scale industrialized production.

The invention relates to a rapid-sterilizing tableware disinfectant. The rapid-sterilizing tableware disinfectant is prepared from the following raw materials in parts by weight: 6-14 parts of quaternary ammonium salt of chitosan, 7-11 parts of alkyl dimethyl benzyl ammonium chloride, 6-10 parts of nonylphenol polyoxyethylene ether sodium sulfate, 3-5 parts of cordate houttuynia, 1-5 parts of lonicera japonica, 4-9 parts of lavandula angustifolia, 3-8 parts of myristic aldehyde, 3-6 parts of herba schizonepetae, 1-5 parts of magnolia bark, 5-9 parts of four kings, 2-8 parts of honeysuckle flowers, 2.5-6 parts of sorbitol, 7-9 parts of hypericum perforatum, 7-11 parts of greasy hypericum monogynum extract, 1-3 parts of sodium sulfate and 6-11 parts of fruit of negundo chastetree fruits. The rapid-sterilizing tableware disinfectant has the beneficial effects that a variety of traditional Chinese medicine ingredients are added, so that the tableware disinfectant disclosed by the invention is environment-friendly and is high in sterilizing speed; and meanwhile, the tableware disinfectant is easy to clean and is free of residue.

The invention relates to a fructus schizandrae extract containing antiseptic disinfectant for a pure cotton fabric. The antiseptic disinfectant contains the following ingredients in parts by mass: 8-18 parts of fructus schizandrae extract, 8-18 parts of hydrogen peroxide, 0.8-1.6 parts of phenol, 0.1-0.3 part of emulsifier, 8-18 parts of vegetable flavoring essence, 1-1.88 parts of potassium permanganate, 0.2-0.3 part of formaldehyde and 24-58 parts of water. According to the fructus schizandrae extract containing antiseptic disinfectant for the pure cotton fabric, provided by the invention, the added purely-natural fructus schizandrae extract is environmentally friendly and can be used for protecting fibers of the pure cotton fabric from damage; and the antiseptic disinfectant has good detergency, is good in bactericidal and antibacterial effect, can be used for killing bacteria hidden in the fibers and enables the pure cotton fabric to have an antibacterial action.

The invention discloses a preparation method of a hindered phenol antioxidant 1019. The method comprises the following steps: dissolving 3-(3, 5-dibutyl-4-hydroxyphenyl) propionyl chloride into an organic solvent; adding the solution obtained from the former step into a mixed solution prepared from propane diamine, inorganic base and water by an agitating manner; controlling the temperature of the reaction system under adding to 0 to 50 DEG C; further reacting at the temperature of 0 to 50 DEG C after adding until reaching the end of reaction; heating to reach the temperature of 50 to 80 DEG C after reaction; separating out a lower water phase; washing an organic phase at two to three times through water until the pH of the washing water is 6 to 7; cooling; crystallizing; filtering; drying to obtain the target product, namely, N, N'-bi-(3-(3,5-di-butyl-4-hydroxyphenyl) propionyl) propane diamine. Compared with the existing synthesis method, the preparation method has the advantages that the yield is high, conditions of reaction are mild, the operation is simple, the product is easily separated and purified, and the quality is high; the preparation method is suitable for industrial production.